#------------------------------------------------------------------------------
#$Date: 2019-11-17 09:37:18 +0100 (Sun 17 de Nov de 2019) $
#$Revision: 229380 $
#$URL: svn://www.crystallography.net/cod/cif/7/04/50/7045010.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7045010
loop_
_publ_author_name
'Krebs, K. M.'
'Freitag, S.'
'Maudrich, J.-J.'
'Schubert, H.'
'Sirsch, P.'
'Wesemann, L.'
_publ_section_title
;
 Coordination chemistry of stannylene-based Lewis pairs - insertion into
 M-Cl and M-C bonds. From base stabilized stannylenes to bidentate
 ligands.
;
_journal_issue                   1
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              83
_journal_page_last               95
_journal_paper_doi               10.1039/c7dt04044j
_journal_volume                  47
_journal_year                    2017
_chemical_formula_sum            'C127 H151 P2 Pt Sn2'
_chemical_formula_weight         2171.89
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_update_record
;
2017-09-20 deposited with the CCDC.
2017-12-01 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 113.2410(10)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   28.0389(11)
_cell_length_b                   17.6143(7)
_cell_length_c                   23.7299(10)
_cell_measurement_reflns_used    1416
_cell_measurement_temperature    100.(2)
_cell_measurement_theta_max      27.4199
_cell_measurement_theta_min      3.6975
_cell_volume                     10768.8(8)
_computing_cell_refinement       'APEX2 v2011.8-0 (Bruker AXS)'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'SAINT V7.68A (Bruker AXS, 2009)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      100.(2)
_diffrn_detector_area_resol_mean 8.3333
_diffrn_measured_fraction_theta_full 0.984
_diffrn_measured_fraction_theta_max 0.984
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0732
_diffrn_reflns_av_sigmaI/netI    0.0730
_diffrn_reflns_limit_h_max       35
_diffrn_reflns_limit_h_min       -36
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       30
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            128147
_diffrn_reflns_theta_full        27.52
_diffrn_reflns_theta_max         27.52
_diffrn_reflns_theta_min         1.40
_diffrn_source_type              'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    1.835
_exptl_absorpt_correction_T_max  0.84
_exptl_absorpt_correction_T_min  0.75
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'SADABS V2008/1 (Bruker AXS)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.340
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             4484
_exptl_crystal_size_max          0.170
_exptl_crystal_size_mid          0.150
_exptl_crystal_size_min          0.120
_refine_diff_density_max         2.220
_refine_diff_density_min         -2.713
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.035
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1216
_refine_ls_number_reflns         24382
_refine_ls_number_restraints     84
_refine_ls_restrained_S_all      1.037
_refine_ls_R_factor_all          0.0843
_refine_ls_R_factor_gt           0.0436
_refine_ls_shift/su_max          0.003
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0178P)²+14.9706P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0609
_refine_ls_wR_factor_ref         0.0699
_reflns_number_gt                17843
_reflns_number_total             24382
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c7dt04044j2.cif
_cod_data_source_block           I
_cod_depositor_comments
'Adding full bibliography for 7045009--7045016.cif.'
_cod_database_code               7045010
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
Sn Sn2 0.269273(9) 0.630794(14) 0.491873(11) 0.01155(6) Uani d . 1
Pt Pt2 0.258243(5) 0.506474(8) 0.422125(6) 0.01092(4) Uani d . 1
Sn Sn1 0.248163(9) 0.374005(14) 0.473386(11) 0.01153(6) Uani d . 1
C C200 0.14632(13) 0.7219(2) 0.45767(16) 0.0141(8) Uani d . 1
P P1 0.25495(4) 0.61157(5) 0.36254(4) 0.0136(2) Uani d . 1
P P2 0.26410(4) 0.40863(6) 0.36017(4) 0.0142(2) Uani d . 1
C C505 0.4227(3) 0.0442(5) 0.3770(4) 0.112(3) Uani d U 1
H H505 0.3881 0.0479 0.3746 0.134 Uiso calc R 1
C C504 0.4356(3) 0.0847(6) 0.3358(4) 0.112(3) Uani d U 1
H H504 0.4088 0.1132 0.3057 0.135 Uiso calc R 1
C C1 0.20545(13) 0.6138(2) 0.28358(16) 0.0149(8) Uani d . 1
C C2 0.15453(14) 0.6342(2) 0.27294(17) 0.0205(9) Uani d . 1
H H2 0.146 0.6488 0.3064 0.025 Uiso calc R 1
C C3 0.11617(15) 0.6335(2) 0.21381(19) 0.0270(10) Uani d . 1
H H3 0.0817 0.6481 0.207 0.032 Uiso calc R 1
C C4 0.12793(15) 0.6118(2) 0.16506(18) 0.0269(10) Uani d . 1
H H4 0.1017 0.6111 0.1247 0.032 Uiso calc R 1
C C5 0.17787(16) 0.5911(2) 0.17510(18) 0.0278(10) Uani d . 1
H H5 0.186 0.5758 0.1415 0.033 Uiso calc R 1
C C6 0.21668(15) 0.5923(2) 0.23403(17) 0.0209(9) Uani d . 1
H H6 0.2511 0.5783 0.2403 0.025 Uiso calc R 1
C C7 0.31428(13) 0.6332(2) 0.35215(16) 0.0154(8) Uani d . 1
C C8 0.35929(14) 0.5925(2) 0.38458(18) 0.0216(9) Uani d . 1
H H8 0.3589 0.5533 0.4119 0.026 Uiso calc R 1
C C9 0.40476(15) 0.6093(2) 0.3769(2) 0.0294(10) Uani d . 1
H H9 0.4355 0.5812 0.3988 0.035 Uiso calc R 1
C C10 0.40557(16) 0.6666(3) 0.3376(2) 0.0318(11) Uani d . 1
H H10 0.4367 0.6774 0.3322 0.038 Uiso calc R 1
C C11 0.36124(16) 0.7083(2) 0.30608(18) 0.0250(9) Uani d . 1
H H11 0.362 0.7482 0.2796 0.03 Uiso calc R 1
C C12 0.31592(15) 0.6915(2) 0.31335(17) 0.0193(9) Uani d . 1
H H12 0.2854 0.7201 0.2916 0.023 Uiso calc R 1
C C13 0.24244(14) 0.6932(2) 0.40246(16) 0.0152(8) Uani d . 1
H H13 0.2038 0.6957 0.388 0.018 Uiso calc R 1
C C14 0.25845(14) 0.7706(2) 0.39026(16) 0.0166(8) Uani d . 1
C C15 0.30864(15) 0.7989(2) 0.42283(17) 0.0206(9) Uani d . 1
H H15 0.3338 0.7675 0.4522 0.025 Uiso calc R 1
C C16 0.32196(15) 0.8712(2) 0.41301(18) 0.0267(10) Uani d . 1
H H16 0.3562 0.8892 0.4357 0.032 Uiso calc R 1
C C17 0.28609(16) 0.9182(2) 0.37045(19) 0.0267(10) Uani d . 1
H H17 0.2952 0.9687 0.3648 0.032 Uiso calc R 1
C C18 0.23662(16) 0.8909(2) 0.33613(18) 0.0263(10) Uani d . 1
H H18 0.212 0.9221 0.3059 0.032 Uiso calc R 1
C C19 0.22340(15) 0.8175(2) 0.34632(17) 0.0207(9) Uani d . 1
H H19 0.1895 0.7991 0.3226 0.025 Uiso calc R 1
C C20 0.28173(14) 0.3246(2) 0.41004(16) 0.0160(8) Uani d . 1
H H20 0.3202 0.328 0.433 0.019 Uiso calc R 1
C C21 0.27253(13) 0.2488(2) 0.37875(15) 0.0143(8) Uani d . 1
C C22 0.22665(15) 0.2091(2) 0.36599(18) 0.0229(9) Uani d . 1
H H22 0.2017 0.2288 0.3799 0.027 Uiso calc R 1
C C23 0.21634(16) 0.1418(2) 0.33366(19) 0.0279(10) Uani d . 1
H H23 0.1848 0.1156 0.3258 0.034 Uiso calc R 1
C C24 0.25193(16) 0.1130(2) 0.31286(19) 0.0296(10) Uani d . 1
H H24 0.2448 0.067 0.2901 0.036 Uiso calc R 1
C C25 0.29806(17) 0.1507(2) 0.3251(2) 0.0314(11) Uani d . 1
H H25 0.3227 0.1305 0.3107 0.038 Uiso calc R 1
C C26 0.30875(15) 0.2183(2) 0.35838(18) 0.0245(9) Uani d . 1
H H26 0.3408 0.2437 0.3672 0.029 Uiso calc R 1
C C27 0.20452(13) 0.3873(2) 0.29369(16) 0.0166(8) Uani d . 1
C C28 0.16106(14) 0.4314(2) 0.28180(16) 0.0167(8) Uani d . 1
H H28 0.1618 0.4704 0.3098 0.02 Uiso calc R 1
C C29 0.11617(14) 0.4200(2) 0.22967(18) 0.0228(9) Uani d . 1
H H29 0.0866 0.451 0.2222 0.027 Uiso calc R 1
C C30 0.11466(15) 0.3632(2) 0.18856(18) 0.0250(9) Uani d . 1
H H30 0.0841 0.3553 0.1527 0.03 Uiso calc R 1
C C31 0.15781(15) 0.3180(2) 0.19984(18) 0.0236(9) Uani d . 1
H H31 0.1568 0.279 0.1717 0.028 Uiso calc R 1
C C32 0.20235(15) 0.3295(2) 0.25183(17) 0.0203(9) Uani d . 1
H H32 0.2318 0.298 0.2594 0.024 Uiso calc R 1
C C33 0.31163(14) 0.4169(2) 0.32544(17) 0.0164(8) Uani d . 1
C C34 0.36444(15) 0.4080(2) 0.3610(2) 0.0265(10) Uani d . 1
H H34 0.3757 0.3934 0.4028 0.032 Uiso calc R 1
C C35 0.40079(16) 0.4206(3) 0.3354(2) 0.0343(11) Uani d . 1
H H35 0.4368 0.4145 0.3598 0.041 Uiso calc R 1
C C36 0.38460(19) 0.4417(3) 0.2750(2) 0.0374(12) Uani d . 1
H H36 0.4096 0.451 0.258 0.045 Uiso calc R 1
C C37 0.33327(18) 0.4497(2) 0.2393(2) 0.0321(11) Uani d . 1
H H37 0.3225 0.4638 0.1975 0.039 Uiso calc R 1
C C38 0.29667(16) 0.4370(2) 0.26399(18) 0.0223(9) Uani d . 1
H H38 0.2608 0.4422 0.2387 0.027 Uiso calc R 1
C C39 0.28215(13) 0.3151(2) 0.56314(16) 0.0131(8) Uani d . 1
C C40 0.25247(13) 0.3050(2) 0.59921(16) 0.0131(8) Uani d . 1
C C41 0.27737(13) 0.2882(2) 0.66201(16) 0.0161(8) Uani d . 1
H H41 0.2573 0.2837 0.6861 0.019 Uiso calc R 1
C C42 0.33033(14) 0.2783(2) 0.68936(17) 0.0197(9) Uani d . 1
H H42 0.347 0.2705 0.7324 0.024 Uiso calc R 1
C C43 0.35873(13) 0.2797(2) 0.65339(17) 0.0179(9) Uani d . 1
H H43 0.3949 0.2694 0.6717 0.021 Uiso calc R 1
C C44 0.33558(13) 0.2960(2) 0.59051(16) 0.0148(8) Uani d . 1
C C45 0.37009(13) 0.2802(2) 0.55597(16) 0.0154(8) Uani d . 1
C C46 0.37059(13) 0.2065(2) 0.53352(17) 0.0179(8) Uani d . 1
C C47 0.40635(13) 0.1889(2) 0.50812(17) 0.0208(9) Uani d . 1
H H47 0.4056 0.1394 0.4918 0.025 Uiso calc R 1
C C48 0.44282(14) 0.2400(2) 0.50563(17) 0.0212(9) Uani d . 1
C C49 0.48215(15) 0.2162(3) 0.47933(19) 0.0279(10) Uani d . 1
H H49 0.4708 0.1657 0.4592 0.033 Uiso calc R 1
C C50 0.4840(3) 0.2692(4) 0.4315(3) 0.092(3) Uani d . 1
H H50A 0.4488 0.2769 0.4005 0.138 Uiso calc R 1
H H50B 0.506 0.2477 0.4121 0.138 Uiso calc R 1
H H50C 0.4984 0.318 0.4505 0.138 Uiso calc R 1
C C51 0.53562(18) 0.2058(3) 0.5283(2) 0.0555(16) Uani d . 1
H H51A 0.5583 0.1834 0.5102 0.083 Uiso calc R 1
H H51B 0.5339 0.1719 0.5602 0.083 Uiso calc R 1
H H51C 0.5495 0.2551 0.5464 0.083 Uiso calc R 1
C C52 0.44211(14) 0.3119(2) 0.52889(17) 0.0212(9) Uani d . 1
H H52 0.4669 0.3481 0.5279 0.025 Uiso calc R 1
C C53 0.40657(13) 0.3337(2) 0.55363(17) 0.0174(8) Uani d . 1
C C54 0.40973(14) 0.4127(2) 0.58019(19) 0.0233(9) Uani d . 1
H H54 0.3774 0.4209 0.5877 0.028 Uiso calc R 1
C C55 0.45584(16) 0.4200(3) 0.6420(2) 0.0356(11) Uani d . 1
H H55A 0.4535 0.3807 0.6701 0.053 Uiso calc R 1
H H55B 0.4553 0.4702 0.6595 0.053 Uiso calc R 1
H H55C 0.4883 0.4137 0.6361 0.053 Uiso calc R 1
C C56 0.41176(19) 0.4747(2) 0.5362(2) 0.0422(13) Uani d . 1
H H56A 0.4417 0.466 0.5254 0.063 Uiso calc R 1
H H56B 0.4151 0.5243 0.556 0.063 Uiso calc R 1
H H56C 0.3798 0.4734 0.4989 0.063 Uiso calc R 1
C C57 0.33541(15) 0.1431(2) 0.5390(2) 0.0284(10) Uani d . 1
H H57 0.3035 0.1676 0.5399 0.034 Uiso calc R 1
C C58 0.31788(17) 0.0864(2) 0.4862(2) 0.0354(12) Uani d . 1
H H58A 0.3032 0.1138 0.4472 0.053 Uiso calc R 1
H H58B 0.2915 0.0526 0.49 0.053 Uiso calc R 1
H H58C 0.3477 0.0563 0.4876 0.053 Uiso calc R 1
C C59 0.3616(2) 0.0997(3) 0.5993(2) 0.0472(14) Uani d . 1
H H59A 0.3948 0.0791 0.6016 0.071 Uiso calc R 1
H H59B 0.339 0.058 0.601 0.071 Uiso calc R 1
H H59C 0.3677 0.1342 0.6339 0.071 Uiso calc R 1
C C60 0.19351(13) 0.3027(2) 0.57430(16) 0.0128(8) Uani d . 1
C C61 0.16799(13) 0.2362(2) 0.54424(16) 0.0151(8) Uani d . 1
C C62 0.11413(13) 0.2313(2) 0.52446(17) 0.0169(8) Uani d . 1
H H62 0.0972 0.186 0.505 0.02 Uiso calc R 1
C C63 0.08447(13) 0.2902(2) 0.53216(17) 0.0172(8) Uani d . 1
C C64 0.02551(13) 0.2857(2) 0.50874(17) 0.0207(9) Uani d . 1
H H64 0.0125 0.3385 0.5092 0.025 Uiso calc R 1
C C65 0.00081(15) 0.2573(3) 0.44268(19) 0.0391(13) Uani d . 1
H H65A 0.013 0.2884 0.4167 0.059 Uiso calc R 1
H H65B -0.037 0.2611 0.4279 0.059 Uiso calc R 1
H H65C 0.0107 0.2043 0.441 0.059 Uiso calc R 1
C C66 0.00832(14) 0.2376(2) 0.5507(2) 0.0280(10) Uani d . 1
H H66A 0.0189 0.1848 0.5497 0.042 Uiso calc R 1
H H66B -0.0295 0.2402 0.5368 0.042 Uiso calc R 1
H H66C 0.0245 0.257 0.5928 0.042 Uiso calc R 1
C C67 0.11072(13) 0.3539(2) 0.56286(17) 0.0191(9) Uani d . 1
H H67 0.0911 0.3946 0.5691 0.023 Uiso calc R 1
C C68 0.16458(13) 0.3614(2) 0.58515(16) 0.0161(8) Uani d . 1
C C69 0.18891(14) 0.4351(2) 0.61695(17) 0.0184(9) Uani d . 1
H H69 0.2271 0.4269 0.6389 0.022 Uiso calc R 1
C C70 0.16730(16) 0.4606(3) 0.66401(19) 0.0298(10) Uani d . 1
H H70A 0.1313 0.4774 0.6426 0.045 Uiso calc R 1
H H70B 0.1883 0.5027 0.6884 0.045 Uiso calc R 1
H H70C 0.1685 0.4181 0.6912 0.045 Uiso calc R 1
C C71 0.18034(16) 0.4969(2) 0.56951(18) 0.0280(9) Uani d . 1
H H71A 0.1993 0.4843 0.5438 0.042 Uiso calc R 1
H H71B 0.193 0.5454 0.5903 0.042 Uiso calc R 1
H H71C 0.1432 0.5011 0.5438 0.042 Uiso calc R 1
C C72 0.19809(14) 0.1688(2) 0.53442(18) 0.0210(9) Uani d . 1
H H72 0.2301 0.1895 0.531 0.025 Uiso calc R 1
C C73 0.21582(17) 0.1158(2) 0.58979(19) 0.0356(12) Uani d . 1
H H73A 0.2371 0.1442 0.6267 0.053 Uiso calc R 1
H H73B 0.2364 0.0743 0.5833 0.053 Uiso calc R 1
H H73C 0.1854 0.0949 0.595 0.053 Uiso calc R 1
C C74 0.16901(15) 0.1232(2) 0.47615(18) 0.0242(9) Uani d . 1
H H74A 0.1412 0.094 0.4811 0.036 Uiso calc R 1
H H74B 0.1932 0.0885 0.4686 0.036 Uiso calc R 1
H H74C 0.154 0.158 0.4413 0.036 Uiso calc R 1
C C75 0.23036(13) 0.6814(2) 0.54800(16) 0.0133(8) Uani d . 1
C C76 0.25757(14) 0.6870(2) 0.61246(17) 0.0157(8) Uani d . 1
C C77 0.23050(14) 0.6988(2) 0.65016(17) 0.0182(8) Uani d . 1
H H77 0.2491 0.7014 0.6933 0.022 Uiso calc R 1
C C78 0.17739(14) 0.7066(2) 0.62579(18) 0.0209(9) Uani d . 1
H H78 0.159 0.7098 0.6519 0.025 Uiso calc R 1
C C79 0.15116(14) 0.7098(2) 0.56297(17) 0.0183(8) Uani d . 1
H H79 0.1149 0.7193 0.546 0.022 Uiso calc R 1
C C80 0.17704(14) 0.6993(2) 0.52370(16) 0.0150(8) Uani d . 1
C C81 0.14758(13) 0.7993(2) 0.44257(17) 0.0167(8) Uani d . 1
C C82 0.17635(14) 0.8589(2) 0.49027(17) 0.0179(8) Uani d . 1
H H82 0.1984 0.8318 0.5288 0.022 Uiso calc R 1
C C83 0.21190(15) 0.9095(2) 0.47156(18) 0.0238(9) Uani d . 1
H H83A 0.2379 0.8781 0.4647 0.036 Uiso calc R 1
H H83B 0.2293 0.9462 0.5043 0.036 Uiso calc R 1
H H83C 0.1912 0.9367 0.4337 0.036 Uiso calc R 1
C C84 0.13697(15) 0.9072(2) 0.50410(18) 0.0256(10) Uani d . 1
H H84A 0.1138 0.9325 0.4665 0.038 Uiso calc R 1
H H84B 0.1553 0.9454 0.5351 0.038 Uiso calc R 1
H H84C 0.1165 0.8745 0.5196 0.038 Uiso calc R 1
C C85 0.11688(13) 0.8230(2) 0.38329(17) 0.0181(8) Uani d . 1
H H85 0.1186 0.8746 0.3727 0.022 Uiso calc R 1
C C86 0.08403(13) 0.7744(2) 0.33923(17) 0.0171(8) Uani d . 1
C C87 0.08205(13) 0.6993(2) 0.35560(17) 0.0172(8) Uani d . 1
H H87 0.0589 0.6656 0.3263 0.021 Uiso calc R 1
C C88 0.11294(13) 0.6718(2) 0.41359(17) 0.0161(8) Uani d . 1
C C89 0.10784(14) 0.5896(2) 0.42955(17) 0.0181(8) Uani d . 1
H H89 0.1387 0.5777 0.4679 0.022 Uiso calc R 1
C C90 0.10809(16) 0.5338(2) 0.38070(19) 0.0275(10) Uani d . 1
H H90A 0.0798 0.5463 0.3415 0.041 Uiso calc R 1
H H90B 0.1033 0.4822 0.3929 0.041 Uiso calc R 1
H H90C 0.1413 0.5372 0.3763 0.041 Uiso calc R 1
C C91 0.05960(15) 0.5784(2) 0.4438(2) 0.0310(10) Uani d . 1
H H91A 0.0626 0.6095 0.4793 0.047 Uiso calc R 1
H H91B 0.0566 0.5248 0.453 0.047 Uiso calc R 1
H H91C 0.0286 0.5938 0.4083 0.047 Uiso calc R 1
C C92 0.04898(14) 0.8034(2) 0.27579(18) 0.0234(9) Uani d . 1
H H92 0.0309 0.7585 0.2507 0.028 Uiso calc R 1
C C93 0.00737(15) 0.8559(2) 0.2803(2) 0.0336(11) Uani d . 1
H H93A -0.0119 0.8293 0.3009 0.05 Uiso calc R 1
H H93B -0.0165 0.8709 0.239 0.05 Uiso calc R 1
H H93C 0.0238 0.9012 0.3039 0.05 Uiso calc R 1
C C94 0.07901(16) 0.8428(3) 0.24211(19) 0.0328(11) Uani d . 1
H H94A 0.098 0.8865 0.2662 0.049 Uiso calc R 1
H H94B 0.0546 0.8603 0.2018 0.049 Uiso calc R 1
H H94C 0.1036 0.807 0.2368 0.049 Uiso calc R 1
C C95 0.31601(14) 0.6875(2) 0.64502(16) 0.0151(8) Uani d . 1
C C96 0.34421(14) 0.7538(2) 0.64455(16) 0.0179(8) Uani d . 1
C C97 0.39686(15) 0.7560(2) 0.68052(17) 0.0238(9) Uani d . 1
H H97 0.4158 0.8007 0.6805 0.029 Uiso calc R 1
C C98 0.42288(14) 0.6953(2) 0.71654(17) 0.0247(10) Uani d . 1
C C99 0.48059(16) 0.7014(3) 0.7561(2) 0.0379(12) Uani d . 1
H H99 0.4874 0.7573 0.7589 0.045 Uiso calc R 1
C C100 0.49582(18) 0.6780(4) 0.8201(2) 0.0592(17) Uani d . 1
H H10A 0.4957 0.6225 0.8225 0.089 Uiso calc R 1
H H10B 0.4712 0.6988 0.8361 0.089 Uiso calc R 1
H H10C 0.5307 0.6971 0.8447 0.089 Uiso calc R 1
C C101 0.51177(17) 0.6725(4) 0.7235(2) 0.071(2) Uani d . 1
H H10D 0.5487 0.6766 0.7501 0.106 Uiso calc R 1
H H10E 0.5045 0.7026 0.6863 0.106 Uiso calc R 1
H H10F 0.5029 0.6193 0.7124 0.106 Uiso calc R 1
C C102 0.39499(14) 0.6302(2) 0.71594(17) 0.0228(9) Uani d . 1
H H102 0.4124 0.5879 0.7402 0.027 Uiso calc R 1
C C103 0.34175(13) 0.6254(2) 0.68030(16) 0.0172(8) Uani d . 1
C C104 0.31332(14) 0.5524(2) 0.68094(17) 0.0186(9) Uani d . 1
H H104 0.2762 0.5596 0.6527 0.022 Uiso calc R 1
C C105 0.33414(16) 0.4864(2) 0.6565(2) 0.0325(11) Uani d . 1
H H10N 0.33 0.4973 0.6143 0.049 Uiso calc R 1
H H10O 0.3149 0.4402 0.657 0.049 Uiso calc R 1
H H10P 0.371 0.4791 0.6822 0.049 Uiso calc R 1
C C106 0.3145(2) 0.5360(3) 0.7446(2) 0.0468(14) Uani d . 1
H H10S 0.3505 0.5306 0.7738 0.07 Uiso calc R 1
H H10Q 0.2955 0.4889 0.7434 0.07 Uiso calc R 1
H H10R 0.2981 0.578 0.7573 0.07 Uiso calc R 1
C C107 0.31778(15) 0.8235(2) 0.60708(18) 0.0215(9) Uani d . 1
H H107 0.2889 0.8053 0.5689 0.026 Uiso calc R 1
C C108 0.35332(16) 0.8727(2) 0.58767(19) 0.0303(10) Uani d . 1
H H10G 0.3326 0.9111 0.5583 0.045 Uiso calc R 1
H H10H 0.3713 0.8408 0.5685 0.045 Uiso calc R 1
H H10I 0.3789 0.8979 0.6238 0.045 Uiso calc R 1
C C109 0.29363(17) 0.8718(2) 0.6429(2) 0.0317(10) Uani d . 1
H H10J 0.2689 0.8409 0.6528 0.048 Uiso calc R 1
H H10K 0.2755 0.9153 0.6178 0.048 Uiso calc R 1
H H10L 0.3211 0.89 0.6809 0.048 Uiso calc R 1
C C110 0.35192(13) 0.6539(2) 0.53542(16) 0.0172(8) Uani d . 1
H H11A 0.3574 0.708 0.5454 0.026 Uiso calc R 1
H H11B 0.3685 0.6402 0.5074 0.026 Uiso calc R 1
H H11C 0.3672 0.6239 0.5731 0.026 Uiso calc R 1
C C111 -0.01787(16) 0.5003(3) 0.93675(19) 0.0307(10) Uani d . 1
H H111 -0.0301 0.501 0.8933 0.037 Uiso calc R 1
C C112 0.04913(16) 0.4731(2) 1.0346(2) 0.0352(12) Uani d . 1
H H112 0.0831 0.455 1.0585 0.042 Uiso calc R 1
C C113 0.03103(16) 0.4730(2) 0.9715(2) 0.0301(10) Uani d . 1
H H113 0.0523 0.454 0.9519 0.036 Uiso calc R 1
C C114 0.03992(19) 0.1335(3) 0.3247(3) 0.0528(15) Uani d . 1
H H114 0.0268 0.1263 0.3556 0.063 Uiso calc R 1
C C115 0.0314(2) 0.0792(3) 0.2806(4) 0.073(2) Uani d . 1
H H115 0.0125 0.0344 0.2806 0.088 Uiso calc R 1
C C116 0.0513(3) 0.0913(4) 0.2347(3) 0.078(2) Uani d . 1
H H116 0.0465 0.0545 0.2036 0.093 Uiso calc R 1
C C117 0.0780(2) 0.1584(4) 0.2367(3) 0.0572(16) Uani d . 1
H H117 0.091 0.1683 0.206 0.069 Uiso calc R 1
C C118 0.08555(17) 0.2094(3) 0.2814(3) 0.0474(14) Uani d . 1
H H118 0.1043 0.2546 0.2824 0.057 Uiso calc R 1
C C119 0.06680(17) 0.1972(3) 0.3249(2) 0.0430(13) Uani d . 1
H H119 0.0726 0.234 0.3562 0.052 Uiso calc R 1
C C501 0.4569(3) -0.0014(4) 0.4218(6) 0.146(4) Uani d U 1
H H501 0.448 -0.029 0.4507 0.176 Uiso calc R 1
C C502 0.5034(3) -0.0027(5) 0.4204(7) 0.199(5) Uani d U 1
H H502 0.5276 -0.0371 0.4477 0.239 Uiso calc R 1
C C507 0.5205(4) 0.0386(6) 0.3851(8) 0.215(6) Uani d U 1
H H507 0.5561 0.0377 0.3914 0.258 Uiso calc R 1
C C503 0.4817(4) 0.0874(6) 0.3342(6) 0.156(4) Uani d U 1
H H503 0.49 0.1159 0.3053 0.187 Uiso calc R 1
C C508 0.16611(13) 0.3460(2) 0.43204(16) 0.0159(8) Uani d . 1
H H50D 0.1617 0.2911 0.4348 0.024 Uiso calc R 1
H H50E 0.1518 0.3614 0.3889 0.024 Uiso calc R 1
H H50F 0.1478 0.3728 0.4538 0.024 Uiso calc R 1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sn Sn -0.6537 1.4246 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
C110 Sn2 C75 . . 108.95(13)
C110 Sn2 C13 . . 104.80(14)
C75 Sn2 C13 . . 108.14(13)
C110 Sn2 Pt2 . . 106.72(10)
C75 Sn2 Pt2 . . 137.20(9)
C13 Sn2 Pt2 . . 84.39(9)
C110 Sn2 P1 . . 101.42(10)
C75 Sn2 P1 . . 140.70(9)
C13 Sn2 P1 . . 38.24(9)
Pt2 Sn2 P1 . . 48.038(19)
P1 Pt2 P2 . . 101.76(4)
P1 Pt2 Sn2 . . 72.00(2)
P2 Pt2 Sn2 . . 168.13(3)
P1 Pt2 Sn1 . . 169.65(2)
P2 Pt2 Sn1 . . 71.84(3)
Sn2 Pt2 Sn1 . . 115.728(9)
C508 Sn1 C39 . . 107.74(13)
C508 Sn1 C20 . . 105.02(13)
C39 Sn1 C20 . . 109.12(13)
C508 Sn1 Pt2 . . 105.88(10)
C39 Sn1 Pt2 . . 139.10(9)
C20 Sn1 Pt2 . . 83.51(9)
C508 Sn1 P2 . . 98.59(10)
C39 Sn1 P2 . . 143.86(9)
C20 Sn1 P2 . . 38.38(9)
Pt2 Sn1 P2 . . 48.03(2)
C88 C200 C81 . . 119.5(3)
C88 C200 C80 . . 123.1(3)
C81 C200 C80 . . 117.0(3)
C7 P1 C13 . . 106.16(17)
C7 P1 C1 . . 102.73(17)
C13 P1 C1 . . 106.77(16)
C7 P1 Pt2 . . 115.74(12)
C13 P1 Pt2 . . 106.38(12)
C1 P1 Pt2 . . 118.20(12)
C7 P1 Sn2 . . 111.15(11)
C13 P1 Sn2 . . 49.24(11)
C1 P1 Sn2 . . 142.58(13)
Pt2 P1 Sn2 . . 59.96(2)
C27 P2 C33 . . 101.99(17)
C27 P2 C20 . . 108.21(17)
C33 P2 C20 . . 107.20(17)
C27 P2 Pt2 . . 115.58(13)
C33 P2 Pt2 . . 118.32(12)
C20 P2 Pt2 . . 105.05(12)
C27 P2 Sn1 . . 109.13(12)
C33 P2 Sn1 . . 145.55(12)
C20 P2 Sn1 . . 49.23(12)
Pt2 P2 Sn1 . . 60.13(2)
C504 C505 C501 . . 123.7(9)
C504 C505 H505 . . 118.2
C501 C505 H505 . . 118.2
C503 C504 C505 . . 125.6(11)
C503 C504 H504 . . 117.2
C505 C504 H504 . . 117.2
C6 C1 C2 . . 118.4(3)
C6 C1 P1 . . 121.7(3)
C2 C1 P1 . . 119.8(3)
C3 C2 C1 . . 120.6(4)
C3 C2 H2 . . 119.7
C1 C2 H2 . . 119.7
C4 C3 C2 . . 120.3(4)
C4 C3 H3 . . 119.9
C2 C3 H3 . . 119.9
C5 C4 C3 . . 119.6(4)
C5 C4 H4 . . 120.2
C3 C4 H4 . . 120.2
C4 C5 C6 . . 120.6(4)
C4 C5 H5 . . 119.7
C6 C5 H5 . . 119.7
C1 C6 C5 . . 120.5(4)
C1 C6 H6 . . 119.8
C5 C6 H6 . . 119.8
C8 C7 C12 . . 119.2(3)
C8 C7 P1 . . 119.8(3)
C12 C7 P1 . . 121.1(3)
C9 C8 C7 . . 119.8(4)
C9 C8 H8 . . 120.1
C7 C8 H8 . . 120.1
C10 C9 C8 . . 120.3(4)
C10 C9 H9 . . 119.8
C8 C9 H9 . . 119.8
C9 C10 C11 . . 120.2(4)
C9 C10 H10 . . 119.9
C11 C10 H10 . . 119.9
C12 C11 C10 . . 119.6(4)
C12 C11 H11 . . 120.2
C10 C11 H11 . . 120.2
C11 C12 C7 . . 120.8(4)
C11 C12 H12 . . 119.6
C7 C12 H12 . . 119.6
C14 C13 P1 . . 118.8(3)
C14 C13 Sn2 . . 127.9(2)
P1 C13 Sn2 . . 92.52(15)
C14 C13 H13 . . 105.1
P1 C13 H13 . . 105.1
Sn2 C13 H13 . . 105.1
C19 C14 C15 . . 117.4(4)
C19 C14 C13 . . 120.7(3)
C15 C14 C13 . . 121.9(3)
C16 C15 C14 . . 121.1(4)
C16 C15 H15 . . 119.4
C14 C15 H15 . . 119.4
C15 C16 C17 . . 120.7(4)
C15 C16 H16 . . 119.6
C17 C16 H16 . . 119.6
C16 C17 C18 . . 119.5(4)
C16 C17 H17 . . 120.3
C18 C17 H17 . . 120.3
C17 C18 C19 . . 119.5(4)
C17 C18 H18 . . 120.3
C19 C18 H18 . . 120.3
C14 C19 C18 . . 121.7(4)
C14 C19 H19 . . 119.1
C18 C19 H19 . . 119.1
C21 C20 P2 . . 116.6(2)
C21 C20 Sn1 . . 130.0(3)
P2 C20 Sn1 . . 92.38(15)
C21 C20 H20 . . 105.1
P2 C20 H20 . . 105.1
Sn1 C20 H20 . . 105.1
C22 C21 C26 . . 118.0(4)
C22 C21 C20 . . 121.3(3)
C26 C21 C20 . . 120.6(3)
C23 C22 C21 . . 121.8(4)
C23 C22 H22 . . 119.1
C21 C22 H22 . . 119.1
C24 C23 C22 . . 119.7(4)
C24 C23 H23 . . 120.1
C22 C23 H23 . . 120.1
C23 C24 C25 . . 120.0(4)
C23 C24 H24 . . 120.0
C25 C24 H24 . . 120.0
C24 C25 C26 . . 120.3(4)
C24 C25 H25 . . 119.9
C26 C25 H25 . . 119.9
C21 C26 C25 . . 120.2(4)
C21 C26 H26 . . 119.9
C25 C26 H26 . . 119.9
C28 C27 C32 . . 118.4(3)
C28 C27 P2 . . 119.6(3)
C32 C27 P2 . . 121.9(3)
C27 C28 C29 . . 121.3(4)
C27 C28 H28 . . 119.4
C29 C28 H28 . . 119.4
C30 C29 C28 . . 119.8(4)
C30 C29 H29 . . 120.1
C28 C29 H29 . . 120.1
C31 C30 C29 . . 119.8(3)
C31 C30 H30 . . 120.1
C29 C30 H30 . . 120.1
C32 C31 C30 . . 120.2(4)
C32 C31 H31 . . 119.9
C30 C31 H31 . . 119.9
C31 C32 C27 . . 120.5(4)
C31 C32 H32 . . 119.7
C27 C32 H32 . . 119.7
C34 C33 C38 . . 118.1(4)
C34 C33 P2 . . 120.5(3)
C38 C33 P2 . . 121.3(3)
C33 C34 C35 . . 120.2(4)
C33 C34 H34 . . 119.9
C35 C34 H34 . . 119.9
C36 C35 C34 . . 120.0(4)
C36 C35 H35 . . 120.0
C34 C35 H35 . . 120.0
C37 C36 C35 . . 120.8(4)
C37 C36 H36 . . 119.6
C35 C36 H36 . . 119.6
C36 C37 C38 . . 119.9(4)
C36 C37 H37 . . 120.1
C38 C37 H37 . . 120.1
C37 C38 C33 . . 121.0(4)
C37 C38 H38 . . 119.5
C33 C38 H38 . . 119.5
C44 C39 C40 . . 117.2(3)
C44 C39 Sn1 . . 121.8(3)
C40 C39 Sn1 . . 120.4(2)
C41 C40 C39 . . 120.1(3)
C41 C40 C60 . . 114.6(3)
C39 C40 C60 . . 125.1(3)
C42 C41 C40 . . 121.2(3)
C42 C41 H41 . . 119.4
C40 C41 H41 . . 119.4
C41 C42 C43 . . 119.0(3)
C41 C42 H42 . . 120.5
C43 C42 H42 . . 120.5
C42 C43 C44 . . 121.7(3)
C42 C43 H43 . . 119.2
C44 C43 H43 . . 119.2
C43 C44 C39 . . 119.9(3)
C43 C44 C45 . . 114.2(3)
C39 C44 C45 . . 125.3(3)
C46 C45 C53 . . 119.1(3)
C46 C45 C44 . . 118.5(3)
C53 C45 C44 . . 121.8(3)
C47 C46 C45 . . 119.1(3)
C47 C46 C57 . . 118.3(3)
C45 C46 C57 . . 122.6(3)
C48 C47 C46 . . 123.0(4)
C48 C47 H47 . . 118.5
C46 C47 H47 . . 118.5
C47 C48 C52 . . 116.9(4)
C47 C48 C49 . . 120.4(4)
C52 C48 C49 . . 122.8(4)
C50 C49 C51 . . 110.0(5)
C50 C49 C48 . . 112.8(4)
C51 C49 C48 . . 112.3(3)
C50 C49 H49 . . 107.1
C51 C49 H49 . . 107.1
C48 C49 H49 . . 107.1
C49 C50 H50A . . 109.5
C49 C50 H50B . . 109.5
H50A C50 H50B . . 109.5
C49 C50 H50C . . 109.5
H50A C50 H50C . . 109.5
H50B C50 H50C . . 109.5
C49 C51 H51A . . 109.5
C49 C51 H51B . . 109.5
H51A C51 H51B . . 109.5
C49 C51 H51C . . 109.5
H51A C51 H51C . . 109.5
H51B C51 H51C . . 109.5
C48 C52 C53 . . 122.9(4)
C48 C52 H52 . . 118.5
C53 C52 H52 . . 118.5
C52 C53 C45 . . 118.9(4)
C52 C53 C54 . . 119.5(3)
C45 C53 C54 . . 121.5(3)
C53 C54 C56 . . 112.6(3)
C53 C54 C55 . . 111.4(3)
C56 C54 C55 . . 110.4(4)
C53 C54 H54 . . 107.4
C56 C54 H54 . . 107.4
C55 C54 H54 . . 107.4
C54 C55 H55A . . 109.5
C54 C55 H55B . . 109.5
H55A C55 H55B . . 109.5
C54 C55 H55C . . 109.5
H55A C55 H55C . . 109.5
H55B C55 H55C . . 109.5
C54 C56 H56A . . 109.5
C54 C56 H56B . . 109.5
H56A C56 H56B . . 109.5
C54 C56 H56C . . 109.5
H56A C56 H56C . . 109.5
H56B C56 H56C . . 109.5
C58 C57 C46 . . 114.7(4)
C58 C57 C59 . . 108.7(3)
C46 C57 C59 . . 110.9(3)
C58 C57 H57 . . 107.4
C46 C57 H57 . . 107.4
C59 C57 H57 . . 107.4
C57 C58 H58A . . 109.5
C57 C58 H58B . . 109.5
H58A C58 H58B . . 109.5
C57 C58 H58C . . 109.5
H58A C58 H58C . . 109.5
H58B C58 H58C . . 109.5
C57 C59 H59A . . 109.5
C57 C59 H59B . . 109.5
H59A C59 H59B . . 109.5
C57 C59 H59C . . 109.5
H59A C59 H59C . . 109.5
H59B C59 H59C . . 109.5
C68 C60 C61 . . 119.5(3)
C68 C60 C40 . . 122.0(3)
C61 C60 C40 . . 118.3(3)
C62 C61 C60 . . 119.1(3)
C62 C61 C72 . . 119.4(3)
C60 C61 C72 . . 121.5(3)
C63 C62 C61 . . 122.4(3)
C63 C62 H62 . . 118.8
C61 C62 H62 . . 118.8
C67 C63 C62 . . 117.1(3)
C67 C63 C64 . . 120.7(3)
C62 C63 C64 . . 122.3(3)
C66 C64 C63 . . 111.6(3)
C66 C64 C65 . . 110.9(3)
C63 C64 C65 . . 112.2(3)
C66 C64 H64 . . 107.3
C63 C64 H64 . . 107.3
C65 C64 H64 . . 107.3
C64 C65 H65A . . 109.5
C64 C65 H65B . . 109.5
H65A C65 H65B . . 109.5
C64 C65 H65C . . 109.5
H65A C65 H65C . . 109.5
H65B C65 H65C . . 109.5
C64 C66 H66A . . 109.5
C64 C66 H66B . . 109.5
H66A C66 H66B . . 109.5
C64 C66 H66C . . 109.5
H66A C66 H66C . . 109.5
H66B C66 H66C . . 109.5
C63 C67 C68 . . 123.3(4)
C63 C67 H67 . . 118.4
C68 C67 H67 . . 118.4
C67 C68 C60 . . 118.6(3)
C67 C68 C69 . . 118.4(3)
C60 C68 C69 . . 122.9(3)
C71 C69 C68 . . 109.6(3)
C71 C69 C70 . . 109.7(3)
C68 C69 C70 . . 112.5(3)
C71 C69 H69 . . 108.3
C68 C69 H69 . . 108.3
C70 C69 H69 . . 108.3
C69 C70 H70A . . 109.5
C69 C70 H70B . . 109.5
H70A C70 H70B . . 109.5
C69 C70 H70C . . 109.5
H70A C70 H70C . . 109.5
H70B C70 H70C . . 109.5
C69 C71 H71A . . 109.5
C69 C71 H71B . . 109.5
H71A C71 H71B . . 109.5
C69 C71 H71C . . 109.5
H71A C71 H71C . . 109.5
H71B C71 H71C . . 109.5
C73 C72 C74 . . 109.6(3)
C73 C72 C61 . . 110.9(3)
C74 C72 C61 . . 114.7(3)
C73 C72 H72 . . 107.1
C74 C72 H72 . . 107.1
C61 C72 H72 . . 107.1
C72 C73 H73A . . 109.5
C72 C73 H73B . . 109.5
H73A C73 H73B . . 109.5
C72 C73 H73C . . 109.5
H73A C73 H73C . . 109.5
H73B C73 H73C . . 109.5
C72 C74 H74A . . 109.5
C72 C74 H74B . . 109.5
H74A C74 H74B . . 109.5
C72 C74 H74C . . 109.5
H74A C74 H74C . . 109.5
H74B C74 H74C . . 109.5
C80 C75 C76 . . 117.2(3)
C80 C75 Sn2 . . 122.6(3)
C76 C75 Sn2 . . 119.6(2)
C77 C76 C75 . . 120.2(3)
C77 C76 C95 . . 115.1(3)
C75 C76 C95 . . 124.4(3)
C78 C77 C76 . . 121.1(3)
C78 C77 H77 . . 119.4
C76 C77 H77 . . 119.4
C77 C78 C79 . . 119.1(4)
C77 C78 H78 . . 120.5
C79 C78 H78 . . 120.5
C78 C79 C80 . . 121.2(3)
C78 C79 H79 . . 119.4
C80 C79 H79 . . 119.4
C79 C80 C75 . . 120.1(3)
C79 C80 C200 . . 114.9(3)
C75 C80 C200 . . 124.1(3)
C85 C81 C200 . . 118.6(3)
C85 C81 C82 . . 118.7(3)
C200 C81 C82 . . 122.4(3)
C81 C82 C83 . . 113.7(3)
C81 C82 C84 . . 109.1(3)
C83 C82 C84 . . 110.3(3)
C81 C82 H82 . . 107.8
C83 C82 H82 . . 107.8
C84 C82 H82 . . 107.8
C82 C83 H83A . . 109.5
C82 C83 H83B . . 109.5
H83A C83 H83B . . 109.5
C82 C83 H83C . . 109.5
H83A C83 H83C . . 109.5
H83B C83 H83C . . 109.5
C82 C84 H84A . . 109.5
C82 C84 H84B . . 109.5
H84A C84 H84B . . 109.5
C82 C84 H84C . . 109.5
H84A C84 H84C . . 109.5
H84B C84 H84C . . 109.5
C86 C85 C81 . . 122.7(4)
C86 C85 H85 . . 118.7
C81 C85 H85 . . 118.7
C85 C86 C87 . . 117.8(3)
C85 C86 C92 . . 121.1(3)
C87 C86 C92 . . 121.0(3)
C86 C87 C88 . . 122.1(3)
C86 C87 H87 . . 118.9
C88 C87 H87 . . 118.9
C87 C88 C200 . . 119.2(3)
C87 C88 C89 . . 119.8(3)
C200 C88 C89 . . 120.9(3)
C88 C89 C90 . . 113.4(3)
C88 C89 C91 . . 110.9(3)
C90 C89 C91 . . 110.8(3)
C88 C89 H89 . . 107.1
C90 C89 H89 . . 107.1
C91 C89 H89 . . 107.1
C89 C90 H90A . . 109.5
C89 C90 H90B . . 109.5
H90A C90 H90B . . 109.5
C89 C90 H90C . . 109.5
H90A C90 H90C . . 109.5
H90B C90 H90C . . 109.5
C89 C91 H91A . . 109.5
C89 C91 H91B . . 109.5
H91A C91 H91B . . 109.5
C89 C91 H91C . . 109.5
H91A C91 H91C . . 109.5
H91B C91 H91C . . 109.5
C93 C92 C86 . . 110.3(3)
C93 C92 C94 . . 110.7(3)
C86 C92 C94 . . 113.1(3)
C93 C92 H92 . . 107.5
C86 C92 H92 . . 107.5
C94 C92 H92 . . 107.5
C92 C93 H93A . . 109.5
C92 C93 H93B . . 109.5
H93A C93 H93B . . 109.5
C92 C93 H93C . . 109.5
H93A C93 H93C . . 109.5
H93B C93 H93C . . 109.5
C92 C94 H94A . . 109.5
C92 C94 H94B . . 109.5
H94A C94 H94B . . 109.5
C92 C94 H94C . . 109.5
H94A C94 H94C . . 109.5
H94B C94 H94C . . 109.5
C103 C95 C96 . . 119.7(3)
C103 C95 C76 . . 120.2(3)
C96 C95 C76 . . 119.9(3)
C97 C96 C95 . . 118.8(4)
C97 C96 C107 . . 119.4(3)
C95 C96 C107 . . 121.7(3)
C98 C97 C96 . . 122.2(4)
C98 C97 H97 . . 118.9
C96 C97 H97 . . 118.9
C97 C98 C102 . . 118.4(3)
C97 C98 C99 . . 120.0(4)
C102 C98 C99 . . 121.5(4)
C100 C99 C101 . . 117.3(4)
C100 C99 C98 . . 115.1(4)
C101 C99 C98 . . 111.1(4)
C100 C99 H99 . . 103.8
C101 C99 H99 . . 103.8
C98 C99 H99 . . 103.8
C99 C100 H10A . . 109.5
C99 C100 H10B . . 109.5
H10A C100 H10B . . 109.5
C99 C100 H10C . . 109.5
H10A C100 H10C . . 109.5
H10B C100 H10C . . 109.5
C99 C101 H10D . . 109.5
C99 C101 H10E . . 109.5
H10D C101 H10E . . 109.5
C99 C101 H10F . . 109.5
H10D C101 H10F . . 109.5
H10E C101 H10F . . 109.5
C98 C102 C103 . . 121.3(4)
C98 C102 H102 . . 119.3
C103 C102 H102 . . 119.3
C95 C103 C102 . . 119.5(4)
C95 C103 C104 . . 121.5(3)
C102 C103 C104 . . 119.0(3)
C105 C104 C103 . . 111.3(3)
C105 C104 C106 . . 112.0(4)
C103 C104 C106 . . 111.4(3)
C105 C104 H104 . . 107.3
C103 C104 H104 . . 107.3
C106 C104 H104 . . 107.3
C104 C105 H10N . . 109.5
C104 C105 H10O . . 109.5
H10N C105 H10O . . 109.5
C104 C105 H10P . . 109.5
H10N C105 H10P . . 109.5
H10O C105 H10P . . 109.5
C104 C106 H10S . . 109.5
C104 C106 H10Q . . 109.5
H10S C106 H10Q . . 109.5
C104 C106 H10R . . 109.5
H10S C106 H10R . . 109.5
H10Q C106 H10R . . 109.5
C108 C107 C96 . . 114.1(3)
C108 C107 C109 . . 109.7(3)
C96 C107 C109 . . 110.0(3)
C108 C107 H107 . . 107.6
C96 C107 H107 . . 107.6
C109 C107 H107 . . 107.6
C107 C108 H10G . . 109.5
C107 C108 H10H . . 109.5
H10G C108 H10H . . 109.5
C107 C108 H10I . . 109.5
H10G C108 H10I . . 109.5
H10H C108 H10I . . 109.5
C107 C109 H10J . . 109.5
C107 C109 H10K . . 109.5
H10J C109 H10K . . 109.5
C107 C109 H10L . . 109.5
H10J C109 H10L . . 109.5
H10K C109 H10L . . 109.5
Sn2 C110 H11A . . 109.5
Sn2 C110 H11B . . 109.5
H11A C110 H11B . . 109.5
Sn2 C110 H11C . . 109.5
H11A C110 H11C . . 109.5
H11B C110 H11C . . 109.5
C113 C111 C112 . 3_567 119.8(4)
C113 C111 H111 . . 120.1
C112 C111 H111 3_567 . 120.1
C113 C112 C111 . 3_567 120.0(4)
C113 C112 H112 . . 120.0
C111 C112 H112 3_567 . 120.0
C111 C113 C112 . . 120.1(4)
C111 C113 H113 . . 119.9
C112 C113 H113 . . 119.9
C119 C114 C115 . . 120.9(6)
C119 C114 H114 . . 119.6
C115 C114 H114 . . 119.6
C114 C115 C116 . . 118.6(6)
C114 C115 H115 . . 120.7
C116 C115 H115 . . 120.7
C117 C116 C115 . . 118.1(6)
C117 C116 H116 . . 121.0
C115 C116 H116 . . 121.0
C118 C117 C116 . . 120.7(6)
C118 C117 H117 . . 119.7
C116 C117 H117 . . 119.7
C117 C118 C119 . . 120.8(6)
C117 C118 H118 . . 119.6
C119 C118 H118 . . 119.6
C118 C119 C114 . . 121.0(6)
C118 C119 H119 . . 119.5
C114 C119 H119 . . 119.5
C502 C501 C505 . . 112.7(11)
C502 C501 H501 . . 123.7
C505 C501 H501 . . 123.7
C501 C502 C507 . . 127.7(11)
C501 C502 H502 . . 116.1
C507 C502 H502 . . 116.1
C502 C507 C503 . . 118.8(9)
C502 C507 H507 . . 120.6
C503 C507 H507 . . 120.6
C504 C503 C507 . . 111.1(11)
C504 C503 H503 . . 124.4
C507 C503 H503 . . 124.4
Sn1 C508 H50D . . 109.5
Sn1 C508 H50E . . 109.5
H50D C508 H50E . . 109.5
Sn1 C508 H50F . . 109.5
H50D C508 H50F . . 109.5
H50E C508 H50F . . 109.5
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
Sn2 C110 . 2.171(3)
Sn2 C75 . 2.215(4)
Sn2 C13 . 2.239(4)
Sn2 Pt2 . 2.6882(3)
Sn2 P1 . 2.9533(10)
Pt2 P1 . 2.3090(10)
Pt2 P2 . 2.3127(10)
Pt2 Sn1 . 2.6973(3)
Sn1 C508 . 2.172(3)
Sn1 C39 . 2.218(3)
Sn1 C20 . 2.241(4)
Sn1 P2 . 2.9558(10)
C200 C88 . 1.406(5)
C200 C81 . 1.414(5)
C200 C80 . 1.513(5)
P1 C7 . 1.816(4)
P1 C13 . 1.830(4)
P1 C1 . 1.840(3)
P2 C27 . 1.828(4)
P2 C33 . 1.829(4)
P2 C20 . 1.837(4)
C505 C504 . 1.372(11)
C505 C501 . 1.376(11)
C505 H505 . 0.95
C504 C503 . 1.307(11)
C504 H504 . 0.95
C1 C6 . 1.385(5)
C1 C2 . 1.395(5)
C2 C3 . 1.391(5)
C2 H2 . 0.95
C3 C4 . 1.376(6)
C3 H3 . 0.95
C4 C5 . 1.373(6)
C4 H4 . 0.95
C5 C6 . 1.393(5)
C5 H5 . 0.95
C6 H6 . 0.95
C7 C8 . 1.390(5)
C7 C12 . 1.391(5)
C8 C9 . 1.389(5)
C8 H8 . 0.95
C9 C10 . 1.380(6)
C9 H9 . 0.95
C10 C11 . 1.382(6)
C10 H10 . 0.95
C11 C12 . 1.380(5)
C11 H11 . 0.95
C12 H12 . 0.95
C13 C14 . 1.499(5)
C13 H13 . 1.0
C14 C19 . 1.389(5)
C14 C15 . 1.403(5)
C15 C16 . 1.373(6)
C15 H15 . 0.95
C16 C17 . 1.384(6)
C16 H16 . 0.95
C17 C18 . 1.388(6)
C17 H17 . 0.95
C18 C19 . 1.392(6)
C18 H18 . 0.95
C19 H19 . 0.95
C20 C21 . 1.499(5)
C20 H20 . 1.0
C21 C22 . 1.389(5)
C21 C26 . 1.393(5)
C22 C23 . 1.379(5)
C22 H22 . 0.95
C23 C24 . 1.374(6)
C23 H23 . 0.95
C24 C25 . 1.379(6)
C24 H24 . 0.95
C25 C26 . 1.396(6)
C25 H25 . 0.95
C26 H26 . 0.95
C27 C28 . 1.377(5)
C27 C32 . 1.408(5)
C28 C29 . 1.388(5)
C28 H28 . 0.95
C29 C30 . 1.387(5)
C29 H29 . 0.95
C30 C31 . 1.383(5)
C30 H30 . 0.95
C31 C32 . 1.381(5)
C31 H31 . 0.95
C32 H32 . 0.95
C33 C34 . 1.394(5)
C33 C38 . 1.395(5)
C34 C35 . 1.394(6)
C34 H34 . 0.95
C35 C36 . 1.373(6)
C35 H35 . 0.95
C36 C37 . 1.359(6)
C36 H36 . 0.95
C37 C38 . 1.386(6)
C37 H37 . 0.95
C38 H38 . 0.95
C39 C44 . 1.418(5)
C39 C40 . 1.421(5)
C40 C41 . 1.405(5)
C40 C60 . 1.521(5)
C41 C42 . 1.377(5)
C41 H41 . 0.95
C42 C43 . 1.379(5)
C42 H42 . 0.95
C43 C44 . 1.402(5)
C43 H43 . 0.95
C44 C45 . 1.520(5)
C45 C46 . 1.406(5)
C45 C53 . 1.407(5)
C46 C47 . 1.393(5)
C46 C57 . 1.529(5)
C47 C48 . 1.381(5)
C47 H47 . 0.95
C48 C52 . 1.386(6)
C48 C49 . 1.525(5)
C49 C50 . 1.486(7)
C49 C51 . 1.502(6)
C49 H49 . 1.0
C50 H50A . 0.98
C50 H50B . 0.98
C50 H50C . 0.98
C51 H51A . 0.98
C51 H51B . 0.98
C51 H51C . 0.98
C52 C53 . 1.395(5)
C52 H52 . 0.95
C53 C54 . 1.515(5)
C54 C56 . 1.527(6)
C54 C55 . 1.531(6)
C54 H54 . 1.0
C55 H55A . 0.98
C55 H55B . 0.98
C55 H55C . 0.98
C56 H56A . 0.98
C56 H56B . 0.98
C56 H56C . 0.98
C57 C58 . 1.525(6)
C57 C59 . 1.530(6)
C57 H57 . 1.0
C58 H58A . 0.98
C58 H58B . 0.98
C58 H58C . 0.98
C59 H59A . 0.98
C59 H59B . 0.98
C59 H59C . 0.98
C60 C68 . 1.399(5)
C60 C61 . 1.411(5)
C61 C62 . 1.396(5)
C61 C72 . 1.527(5)
C62 C63 . 1.386(5)
C62 H62 . 0.95
C63 C67 . 1.381(5)
C63 C64 . 1.524(5)
C64 C66 . 1.524(5)
C64 C65 . 1.527(6)
C64 H64 . 1.0
C65 H65A . 0.98
C65 H65B . 0.98
C65 H65C . 0.98
C66 H66A . 0.98
C66 H66B . 0.98
C66 H66C . 0.98
C67 C68 . 1.396(5)
C67 H67 . 0.95
C68 C69 . 1.521(5)
C69 C71 . 1.516(5)
C69 C70 . 1.533(5)
C69 H69 . 1.0
C70 H70A . 0.98
C70 H70B . 0.98
C70 H70C . 0.98
C71 H71A . 0.98
C71 H71B . 0.98
C71 H71C . 0.98
C72 C73 . 1.526(6)
C72 C74 . 1.527(5)
C72 H72 . 1.0
C73 H73A . 0.98
C73 H73B . 0.98
C73 H73C . 0.98
C74 H74A . 0.98
C74 H74B . 0.98
C74 H74C . 0.98
C75 C80 . 1.410(5)
C75 C76 . 1.418(5)
C76 C77 . 1.398(5)
C76 C95 . 1.511(5)
C77 C78 . 1.375(5)
C77 H77 . 0.95
C78 C79 . 1.379(5)
C78 H78 . 0.95
C79 C80 . 1.401(5)
C79 H79 . 0.95
C81 C85 . 1.392(5)
C81 C82 . 1.521(5)
C82 C83 . 1.528(5)
C82 C84 . 1.528(5)
C82 H82 . 1.0
C83 H83A . 0.98
C83 H83B . 0.98
C83 H83C . 0.98
C84 H84A . 0.98
C84 H84B . 0.98
C84 H84C . 0.98
C85 C86 . 1.384(5)
C85 H85 . 0.95
C86 C87 . 1.385(5)
C86 C92 . 1.525(5)
C87 C88 . 1.392(5)
C87 H87 . 0.95
C88 C89 . 1.517(5)
C89 C90 . 1.521(5)
C89 C91 . 1.532(5)
C89 H89 . 1.0
C90 H90A . 0.98
C90 H90B . 0.98
C90 H90C . 0.98
C91 H91A . 0.98
C91 H91B . 0.98
C91 H91C . 0.98
C92 C93 . 1.525(5)
C92 C94 . 1.536(6)
C92 H92 . 1.0
C93 H93A . 0.98
C93 H93B . 0.98
C93 H93C . 0.98
C94 H94A . 0.98
C94 H94B . 0.98
C94 H94C . 0.98
C95 C103 . 1.393(5)
C95 C96 . 1.414(5)
C96 C97 . 1.384(5)
C96 C107 . 1.526(5)
C97 C98 . 1.383(6)
C97 H97 . 0.95
C98 C102 . 1.385(6)
C98 C99 . 1.521(5)
C99 C100 . 1.465(6)
C99 C101 . 1.468(6)
C99 H99 . 1.0
C100 H10A . 0.98
C100 H10B . 0.98
C100 H10C . 0.98
C101 H10D . 0.98
C101 H10E . 0.98
C101 H10F . 0.98
C102 C103 . 1.398(5)
C102 H102 . 0.95
C103 C104 . 1.516(5)
C104 C105 . 1.515(5)
C104 C106 . 1.525(6)
C104 H104 . 1.0
C105 H10N . 0.98
C105 H10O . 0.98
C105 H10P . 0.98
C106 H10S . 0.98
C106 H10Q . 0.98
C106 H10R . 0.98
C107 C108 . 1.523(5)
C107 C109 . 1.535(5)
C107 H107 . 1.0
C108 H10G . 0.98
C108 H10H . 0.98
C108 H10I . 0.98
C109 H10J . 0.98
C109 H10K . 0.98
C109 H10L . 0.98
C110 H11A . 0.98
C110 H11B . 0.98
C110 H11C . 0.98
C111 C113 . 1.378(6)
C111 C112 3_567 1.385(6)
C111 H111 . 0.95
C112 C113 . 1.379(6)
C112 C111 3_567 1.385(6)
C112 H112 . 0.95
C113 H113 . 0.95
C114 C119 . 1.351(7)
C114 C115 . 1.366(8)
C114 H114 . 0.95
C115 C116 . 1.422(9)
C115 H115 . 0.95
C116 C117 . 1.391(9)
C116 H116 . 0.95
C117 C118 . 1.342(7)
C117 H117 . 0.95
C118 C119 . 1.347(7)
C118 H118 . 0.95
C119 H119 . 0.95
C501 C502 . 1.318(11)
C501 H501 . 0.95
C502 C507 . 1.332(15)
C502 H502 . 0.95
C507 C503 . 1.531(15)
C507 H507 . 0.95
C503 H503 . 0.95
C508 H50D . 0.98
C508 H50E . 0.98
C508 H50F . 0.98
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion
C110 Sn2 Pt2 P1 . -90.45(11)
C75 Sn2 Pt2 P1 . 124.10(14)
C13 Sn2 Pt2 P1 . 13.34(10)
C110 Sn2 Pt2 P2 . -30.68(16)
C75 Sn2 Pt2 P2 . -176.13(18)
C13 Sn2 Pt2 P2 . 73.12(15)
P1 Sn2 Pt2 P2 . 59.77(12)
C110 Sn2 Pt2 Sn1 . 96.98(10)
C75 Sn2 Pt2 Sn1 . -48.47(14)
C13 Sn2 Pt2 Sn1 . -159.22(9)
P1 Sn2 Pt2 Sn1 . -172.57(3)
P1 Pt2 Sn1 C508 . -34.25(18)
P2 Pt2 Sn1 C508 . -87.31(10)
Sn2 Pt2 Sn1 C508 . 102.56(10)
P1 Pt2 Sn1 C39 . -178.6(2)
P2 Pt2 Sn1 C39 . 128.37(14)
Sn2 Pt2 Sn1 C39 . -41.77(14)
P1 Pt2 Sn1 C20 . 69.56(17)
P2 Pt2 Sn1 C20 . 16.51(9)
Sn2 Pt2 Sn1 C20 . -153.62(9)
P1 Pt2 Sn1 P2 . 53.05(15)
Sn2 Pt2 Sn1 P2 . -170.13(3)
P2 Pt2 P1 C7 . -68.94(13)
Sn2 Pt2 P1 C7 . 100.60(13)
Sn1 Pt2 P1 C7 . -119.81(17)
P2 Pt2 P1 C13 . 173.42(12)
Sn2 Pt2 P1 C13 . -17.04(12)
Sn1 Pt2 P1 C13 . 122.55(17)
P2 Pt2 P1 C1 . 53.49(15)
Sn2 Pt2 P1 C1 . -136.97(14)
Sn1 Pt2 P1 C1 . 2.6(2)
P2 Pt2 P1 Sn2 . -169.54(2)
Sn1 Pt2 P1 Sn2 . 139.59(14)
C110 Sn2 P1 C7 . -6.01(17)
C75 Sn2 P1 C7 . 134.3(2)
C13 Sn2 P1 C7 . 93.5(2)
Pt2 Sn2 P1 C7 . -108.31(13)
C110 Sn2 P1 C13 . -99.48(18)
C75 Sn2 P1 C13 . 40.9(2)
Pt2 Sn2 P1 C13 . 158.22(15)
C110 Sn2 P1 C1 . -159.5(2)
C75 Sn2 P1 C1 . -19.1(3)
C13 Sn2 P1 C1 . -60.0(2)
Pt2 Sn2 P1 C1 . 98.2(2)
C110 Sn2 P1 Pt2 . 102.31(10)
C75 Sn2 P1 Pt2 . -117.34(15)
C13 Sn2 P1 Pt2 . -158.22(15)
P1 Pt2 P2 C27 . -73.28(14)
Sn2 Pt2 P2 C27 . -130.36(16)
Sn1 Pt2 P2 C27 . 98.28(14)
P1 Pt2 P2 C33 . 48.02(14)
Sn2 Pt2 P2 C33 . -9.1(2)
Sn1 Pt2 P2 C33 . -140.41(14)
P1 Pt2 P2 C20 . 167.54(12)
Sn2 Pt2 P2 C20 . 110.47(16)
Sn1 Pt2 P2 C20 . -20.89(12)
P1 Pt2 P2 Sn1 . -171.56(2)
Sn2 Pt2 P2 Sn1 . 131.36(11)
C508 Sn1 P2 C27 . -5.46(17)
C39 Sn1 P2 C27 . 131.4(2)
C20 Sn1 P2 C27 . 97.9(2)
Pt2 Sn1 P2 C27 . -109.13(14)
C508 Sn1 P2 C33 . -158.9(2)
C39 Sn1 P2 C33 . -22.0(3)
C20 Sn1 P2 C33 . -55.5(3)
Pt2 Sn1 P2 C33 . 97.5(2)
C508 Sn1 P2 C20 . -103.38(18)
C39 Sn1 P2 C20 . 33.5(2)
Pt2 Sn1 P2 C20 . 152.95(15)
C508 Sn1 P2 Pt2 . 103.67(10)
C39 Sn1 P2 Pt2 . -119.48(16)
C20 Sn1 P2 Pt2 . -152.95(15)
C501 C505 C504 C503 . -2.1(16)
C7 P1 C1 C6 . 32.3(4)
C13 P1 C1 C6 . 143.8(3)
Pt2 P1 C1 C6 . -96.5(3)
Sn2 P1 C1 C6 . -173.0(2)
C7 P1 C1 C2 . -150.7(3)
C13 P1 C1 C2 . -39.3(3)
Pt2 P1 C1 C2 . 80.5(3)
Sn2 P1 C1 C2 . 4.0(4)
C6 C1 C2 C3 . -0.5(6)
P1 C1 C2 C3 . -177.6(3)
C1 C2 C3 C4 . 0.7(6)
C2 C3 C4 C5 . -0.3(6)
C3 C4 C5 C6 . -0.3(6)
C2 C1 C6 C5 . -0.1(6)
P1 C1 C6 C5 . 176.9(3)
C4 C5 C6 C1 . 0.5(6)
C13 P1 C7 C8 . 110.9(3)
C1 P1 C7 C8 . -137.1(3)
Pt2 P1 C7 C8 . -6.8(3)
Sn2 P1 C7 C8 . 59.0(3)
C13 P1 C7 C12 . -67.3(3)
C1 P1 C7 C12 . 44.6(3)
Pt2 P1 C7 C12 . 174.9(3)
Sn2 P1 C7 C12 . -119.2(3)
C12 C7 C8 C9 . -1.4(6)
P1 C7 C8 C9 . -179.7(3)
C7 C8 C9 C10 . 0.5(6)
C8 C9 C10 C11 . 0.7(7)
C9 C10 C11 C12 . -1.0(6)
C10 C11 C12 C7 . 0.1(6)
C8 C7 C12 C11 . 1.1(6)
P1 C7 C12 C11 . 179.3(3)
C7 P1 C13 C14 . 32.3(3)
C1 P1 C13 C14 . -76.8(3)
Pt2 P1 C13 C14 . 156.1(2)
Sn2 P1 C13 C14 . 136.6(3)
C7 P1 C13 Sn2 . -104.26(16)
C1 P1 C13 Sn2 . 146.66(14)
Pt2 P1 C13 Sn2 . 19.56(13)
C110 Sn2 C13 C14 . -40.4(3)
C75 Sn2 C13 C14 . 75.7(3)
Pt2 Sn2 C13 C14 . -146.3(3)
P1 Sn2 C13 C14 . -130.2(4)
C110 Sn2 C13 P1 . 89.75(16)
C75 Sn2 C13 P1 . -154.14(13)
Pt2 Sn2 C13 P1 . -16.10(11)
P1 C13 C14 C19 . 94.4(4)
Sn2 C13 C14 C19 . -146.2(3)
P1 C13 C14 C15 . -86.5(4)
Sn2 C13 C14 C15 . 32.9(5)
C19 C14 C15 C16 . 2.2(6)
C13 C14 C15 C16 . -177.0(4)
C14 C15 C16 C17 . -0.1(6)
C15 C16 C17 C18 . -1.9(6)
C16 C17 C18 C19 . 1.9(6)
C15 C14 C19 C18 . -2.2(6)
C13 C14 C19 C18 . 177.0(4)
C17 C18 C19 C14 . 0.2(6)
C27 P2 C20 C21 . 37.8(3)
C33 P2 C20 C21 . -71.5(3)
Pt2 P2 C20 C21 . 161.8(2)
Sn1 P2 C20 C21 . 137.7(3)
C27 P2 C20 Sn1 . -99.89(16)
C33 P2 C20 Sn1 . 150.79(14)
Pt2 P2 C20 Sn1 . 24.10(13)
C508 Sn1 C20 C21 . -43.5(3)
C39 Sn1 C20 C21 . 71.8(3)
Pt2 Sn1 C20 C21 . -148.2(3)
P2 Sn1 C20 C21 . -128.3(4)
C508 Sn1 C20 P2 . 84.86(16)
C39 Sn1 C20 P2 . -159.86(13)
Pt2 Sn1 C20 P2 . -19.89(11)
P2 C20 C21 C22 . -93.1(4)
Sn1 C20 C21 C22 . 25.6(5)
P2 C20 C21 C26 . 83.1(4)
Sn1 C20 C21 C26 . -158.2(3)
C26 C21 C22 C23 . -0.7(6)
C20 C21 C22 C23 . 175.6(4)
C21 C22 C23 C24 . -0.5(6)
C22 C23 C24 C25 . 0.9(6)
C23 C24 C25 C26 . -0.2(6)
C22 C21 C26 C25 . 1.4(6)
C20 C21 C26 C25 . -175.0(3)
C24 C25 C26 C21 . -1.0(6)
C33 P2 C27 C28 . -126.3(3)
C20 P2 C27 C28 . 120.9(3)
Pt2 P2 C27 C28 . 3.4(4)
Sn1 P2 C27 C28 . 68.7(3)
C33 P2 C27 C32 . 50.0(3)
C20 P2 C27 C32 . -62.8(3)
Pt2 P2 C27 C32 . 179.7(3)
Sn1 P2 C27 C32 . -115.0(3)
C32 C27 C28 C29 . -0.6(6)
P2 C27 C28 C29 . 175.9(3)
C27 C28 C29 C30 . 0.1(6)
C28 C29 C30 C31 . 0.2(6)
C29 C30 C31 C32 . -0.1(6)
C30 C31 C32 C27 . -0.4(6)
C28 C27 C32 C31 . 0.7(6)
P2 C27 C32 C31 . -175.6(3)
C27 P2 C33 C34 . -158.6(3)
C20 P2 C33 C34 . -45.0(4)
Pt2 P2 C33 C34 . 73.4(3)
Sn1 P2 C33 C34 . -4.2(5)
C27 P2 C33 C38 . 25.7(4)
C20 P2 C33 C38 . 139.2(3)
Pt2 P2 C33 C38 . -102.4(3)
Sn1 P2 C33 C38 . -180.0(2)
C38 C33 C34 C35 . 1.2(6)
P2 C33 C34 C35 . -174.7(3)
C33 C34 C35 C36 . 0.0(7)
C34 C35 C36 C37 . -1.0(7)
C35 C36 C37 C38 . 0.7(7)
C36 C37 C38 C33 . 0.6(6)
C34 C33 C38 C37 . -1.5(6)
P2 C33 C38 C37 . 174.3(3)
C508 Sn1 C39 C44 . 154.6(3)
C20 Sn1 C39 C44 . 41.1(3)
Pt2 Sn1 C39 C44 . -61.5(3)
P2 Sn1 C39 C44 . 19.8(4)
C508 Sn1 C39 C40 . -34.4(3)
C20 Sn1 C39 C40 . -147.9(3)
Pt2 Sn1 C39 C40 . 109.6(3)
P2 Sn1 C39 C40 . -169.1(2)
C44 C39 C40 C41 . 9.8(5)
Sn1 C39 C40 C41 . -161.7(3)
C44 C39 C40 C60 . -163.7(3)
Sn1 C39 C40 C60 . 24.9(5)
C39 C40 C41 C42 . -2.7(6)
C60 C40 C41 C42 . 171.4(3)
C40 C41 C42 C43 . -4.5(6)
C41 C42 C43 C44 . 4.3(6)
C42 C43 C44 C39 . 3.1(6)
C42 C43 C44 C45 . -168.8(3)
C40 C39 C44 C43 . -10.0(5)
Sn1 C39 C44 C43 . 161.4(3)
C40 C39 C44 C45 . 160.9(3)
Sn1 C39 C44 C45 . -27.7(5)
C43 C44 C45 C46 . 86.4(4)
C39 C44 C45 C46 . -85.0(5)
C43 C44 C45 C53 . -84.4(4)
C39 C44 C45 C53 . 104.3(4)
C53 C45 C46 C47 . -1.6(5)
C44 C45 C46 C47 . -172.6(3)
C53 C45 C46 C57 . 174.9(3)
C44 C45 C46 C57 . 3.9(5)
C45 C46 C47 C48 . 2.2(6)
C57 C46 C47 C48 . -174.5(4)
C46 C47 C48 C52 . -1.2(6)
C46 C47 C48 C49 . 177.7(3)
C47 C48 C49 C50 . 128.6(5)
C52 C48 C49 C50 . -52.6(6)
C47 C48 C49 C51 . -106.4(5)
C52 C48 C49 C51 . 72.4(5)
C47 C48 C52 C53 . -0.4(6)
C49 C48 C52 C53 . -179.2(4)
C48 C52 C53 C45 . 0.8(6)
C48 C52 C53 C54 . 177.8(3)
C46 C45 C53 C52 . 0.2(5)
C44 C45 C53 C52 . 170.9(3)
C46 C45 C53 C54 . -176.7(3)
C44 C45 C53 C54 . -6.0(5)
C52 C53 C54 C56 . 50.9(5)
C45 C53 C54 C56 . -132.2(4)
C52 C53 C54 C55 . -73.8(5)
C45 C53 C54 C55 . 103.1(4)
C47 C46 C57 C58 . -36.2(5)
C45 C46 C57 C58 . 147.3(4)
C47 C46 C57 C59 . 87.3(5)
C45 C46 C57 C59 . -89.2(4)
C41 C40 C60 C68 . 76.6(4)
C39 C40 C60 C68 . -109.6(4)
C41 C40 C60 C61 . -97.6(4)
C39 C40 C60 C61 . 76.2(5)
C68 C60 C61 C62 . 1.7(5)
C40 C60 C61 C62 . 176.0(3)
C68 C60 C61 C72 . -176.6(3)
C40 C60 C61 C72 . -2.3(5)
C60 C61 C62 C63 . 1.3(6)
C72 C61 C62 C63 . 179.7(3)
C61 C62 C63 C67 . -2.6(6)
C61 C62 C63 C64 . 178.0(3)
C67 C63 C64 C66 . -101.5(4)
C62 C63 C64 C66 . 77.9(5)
C67 C63 C64 C65 . 133.3(4)
C62 C63 C64 C65 . -47.3(5)
C62 C63 C67 C68 . 0.9(6)
C64 C63 C67 C68 . -179.8(4)
C63 C67 C68 C60 . 2.1(6)
C63 C67 C68 C69 . 178.6(3)
C61 C60 C68 C67 . -3.4(5)
C40 C60 C68 C67 . -177.5(3)
C61 C60 C68 C69 . -179.7(3)
C40 C60 C68 C69 . 6.2(5)
C67 C68 C69 C71 . -75.8(4)
C60 C68 C69 C71 . 100.6(4)
C67 C68 C69 C70 . 46.7(5)
C60 C68 C69 C70 . -137.0(4)
C62 C61 C72 C73 . -91.3(4)
C60 C61 C72 C73 . 87.0(4)
C62 C61 C72 C74 . 33.4(5)
C60 C61 C72 C74 . -148.3(4)
C110 Sn2 C75 C80 . 157.9(3)
C13 Sn2 C75 C80 . 44.5(3)
Pt2 Sn2 C75 C80 . -57.2(4)
P1 Sn2 C75 C80 . 19.3(4)
C110 Sn2 C75 C76 . -30.9(3)
C13 Sn2 C75 C76 . -144.3(3)
Pt2 Sn2 C75 C76 . 114.1(3)
P1 Sn2 C75 C76 . -169.5(2)
C80 C75 C76 C77 . 9.2(5)
Sn2 C75 C76 C77 . -162.5(3)
C80 C75 C76 C95 . -165.6(3)
Sn2 C75 C76 C95 . 22.7(5)
C75 C76 C77 C78 . -1.3(6)
C95 C76 C77 C78 . 174.0(3)
C76 C77 C78 C79 . -6.0(6)
C77 C78 C79 C80 . 5.0(6)
C78 C79 C80 C75 . 3.3(6)
C78 C79 C80 C200 . -166.7(3)
C76 C75 C80 C79 . -10.2(5)
Sn2 C75 C80 C79 . 161.2(3)
C76 C75 C80 C200 . 158.8(3)
Sn2 C75 C80 C200 . -29.8(5)
C88 C200 C80 C79 . -88.5(4)
C81 C200 C80 C79 . 84.4(4)
C88 C200 C80 C75 . 102.0(4)
C81 C200 C80 C75 . -85.1(4)
C88 C200 C81 C85 . -2.4(5)
C80 C200 C81 C85 . -175.6(3)
C88 C200 C81 C82 . 170.6(3)
C80 C200 C81 C82 . -2.6(5)
C85 C81 C82 C83 . -56.2(5)
C200 C81 C82 C83 . 130.8(4)
C85 C81 C82 C84 . 67.4(4)
C200 C81 C82 C84 . -105.6(4)
C200 C81 C85 C86 . 2.1(6)
C82 C81 C85 C86 . -171.2(3)
C81 C85 C86 C87 . 0.1(6)
C81 C85 C86 C92 . 176.8(3)
C85 C86 C87 C88 . -2.0(5)
C92 C86 C87 C88 . -178.8(3)
C86 C87 C88 C200 . 1.7(5)
C86 C87 C88 C89 . 178.1(3)
C81 C200 C88 C87 . 0.6(5)
C80 C200 C88 C87 . 173.3(3)
C81 C200 C88 C89 . -175.8(3)
C80 C200 C88 C89 . -3.0(5)
C87 C88 C89 C90 . 47.7(5)
C200 C88 C89 C90 . -136.0(4)
C87 C88 C89 C91 . -77.7(4)
C200 C88 C89 C91 . 98.6(4)
C85 C86 C92 C93 . -67.5(5)
C87 C86 C92 C93 . 109.1(4)
C85 C86 C92 C94 . 57.2(5)
C87 C86 C92 C94 . -126.2(4)
C77 C76 C95 C103 . 75.3(5)
C75 C76 C95 C103 . -109.7(4)
C77 C76 C95 C96 . -98.6(4)
C75 C76 C95 C96 . 76.4(5)
C103 C95 C96 C97 . -1.5(5)
C76 C95 C96 C97 . 172.5(3)
C103 C95 C96 C107 . -179.5(3)
C76 C95 C96 C107 . -5.6(5)
C95 C96 C97 C98 . 0.5(6)
C107 C96 C97 C98 . 178.6(4)
C96 C97 C98 C102 . 0.4(6)
C96 C97 C98 C99 . -178.8(4)
C97 C98 C99 C100 . 130.8(5)
C102 C98 C99 C100 . -48.4(6)
C97 C98 C99 C101 . -92.9(6)
C102 C98 C99 C101 . 87.9(6)
C97 C98 C102 C103 . -0.4(6)
C99 C98 C102 C103 . 178.8(4)
C96 C95 C103 C102 . 1.5(5)
C76 C95 C103 C102 . -172.4(3)
C96 C95 C103 C104 . -178.4(3)
C76 C95 C103 C104 . 7.6(5)
C98 C102 C103 C95 . -0.5(6)
C98 C102 C103 C104 . 179.4(4)
C95 C103 C104 C105 . 117.6(4)
C102 C103 C104 C105 . -62.3(5)
C95 C103 C104 C106 . -116.7(4)
C102 C103 C104 C106 . 63.4(5)
C97 C96 C107 C108 . 28.8(5)
C95 C96 C107 C108 . -153.2(4)
C97 C96 C107 C109 . -95.0(4)
C95 C96 C107 C109 . 83.1(4)
C112 C111 C113 C112 3_567 -1.0(7)
C111 C112 C113 C111 3_567 1.0(7)
C119 C114 C115 C116 . -0.1(8)
C114 C115 C116 C117 . -0.8(8)
C115 C116 C117 C118 . 1.4(8)
C116 C117 C118 C119 . -1.0(8)
C117 C118 C119 C114 . 0.0(7)
C115 C114 C119 C118 . 0.5(7)
C504 C505 C501 C502 . -0.7(15)
C505 C501 C502 C507 . 6.(2)
C501 C502 C507 C503 . -8.(2)
C505 C504 C503 C507 . 0.2(15)
C502 C507 C503 C504 . 4.3(18)
