#------------------------------------------------------------------------------
#$Date: 2019-11-17 09:56:17 +0100 (Sun 17 de Nov de 2019) $
#$Revision: 229456 $
#$URL: svn://www.crystallography.net/cod/cif/7/04/50/7045065.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7045065
loop_
_publ_author_name
'Cheng, Ming-Chuan'
'Hua, Shao-An'
'Lv, Qiying'
'Sigrist, Marc'
'Lee, Gene-Hsiang'
'Liu, Yu-Chiao'
'Chiang, Ming-Hsi'
'Peng, Shie-Ming'
_publ_section_title
;
 Stepwise synthesis of the heterotrimetallic chains
 [MRu₂(dpa)₄X₂]<sup>0/1+</sup> using
 group 7 to group 12 transition metal ions and
 [Ru₂(dpa)₄Cl].
;
_journal_issue                   5
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              1422
_journal_page_last               1434
_journal_paper_doi               10.1039/c7dt04114d
_journal_volume                  47
_journal_year                    2018
_chemical_formula_sum            'C43 H38 Cl8 F6 N12 P Pd Ru2'
_chemical_formula_weight         1459.96
_space_group_crystal_system      monoclinic
_space_group_IT_number           13
_space_group_name_Hall           '-P 2yac'
_space_group_name_H-M_alt        'P 1 2/n 1'
_symmetry_space_group_name_Hall  '-P 2yac'
_symmetry_space_group_name_H-M   'P 1 2/n 1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2014/7
_audit_update_record
;
2017-10-26 deposited with the CCDC.
2017-12-18 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 92.4271(10)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   12.3353(5)
_cell_length_b                   10.3177(4)
_cell_length_c                   20.5839(8)
_cell_measurement_reflns_used    9883
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      27.49
_cell_measurement_theta_min      2.57
_cell_volume                     2617.40(18)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX3'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2014/7 (Sheldrick, 2014)'
_computing_structure_solution    'SHELXS-97 (Sheldrick 2008)'
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker D8 VENTURE'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0286
_diffrn_reflns_av_unetI/netI     0.0258
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -16
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            20401
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.488
_diffrn_reflns_theta_min         2.575
_exptl_absorpt_coefficient_mu    1.416
_exptl_absorpt_correction_T_max  0.7456
_exptl_absorpt_correction_T_min  0.6755
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Bruker, 2016)'
_exptl_crystal_colour            brown
_exptl_crystal_density_diffrn    1.852
_exptl_crystal_description       block
_exptl_crystal_F_000             1438
_exptl_crystal_size_max          0.223
_exptl_crystal_size_mid          0.175
_exptl_crystal_size_min          0.142
_refine_diff_density_max         0.523
_refine_diff_density_min         -0.580
_refine_diff_density_rms         0.079
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.137
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     336
_refine_ls_number_reflns         6006
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.137
_refine_ls_R_factor_all          0.0351
_refine_ls_R_factor_gt           0.0294
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0123P)²+3.9348P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0569
_refine_ls_wR_factor_ref         0.0592
_reflns_Friedel_coverage         0.000
_reflns_number_gt                5347
_reflns_number_total             6006
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c7dt04114d2.cif
_cod_data_source_block           ic18521
_cod_depositor_comments
'Adding full bibliography for 7045062--7045073.cif.'
_cod_database_code               7045065
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;
_shelx_estimated_absorpt_t_min   0.743
_shelx_estimated_absorpt_t_max   0.824
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y, -z+1/2'
'-x, -y, -z'
'x-1/2, -y, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pd1 Pd 0.57052(2) 0.53298(2) 0.78767(2) 0.00940(5) Uani 0.5 1 d . . P A 2
Ru1 Ru 0.57052(2) 0.53298(2) 0.78767(2) 0.00940(5) Uani 0.5 1 d . . P A 1
Ru2 Ru 0.7400(3) 0.53384(3) 0.7525(3) 0.0087(4) Uani 0.5 1 d . . P . .
Cl1 Cl 0.36758(5) 0.52516(7) 0.82854(3) 0.02267(14) Uani 1 1 d . . . . .
N1 N 0.52603(16) 0.45111(19) 0.69756(10) 0.0127(4) Uani 1 1 d . . . . .
N2 N 0.70670(16) 0.39571(19) 0.68446(10) 0.0135(4) Uani 1 1 d . . . . .
N3 N 0.88986(16) 0.35177(19) 0.67196(10) 0.0129(4) Uani 1 1 d . . . . .
N4 N 0.55389(16) 0.71359(19) 0.74423(10) 0.0139(4) Uani 1 1 d . . . . .
N5 N 0.70721(16) 0.67360(19) 0.68499(10) 0.0129(4) Uani 1 1 d . . . . .
N6 N 0.86323(16) 0.62501(19) 0.62956(10) 0.0129(4) Uani 1 1 d . . . . .
C1 C 0.42342(19) 0.4694(2) 0.67282(12) 0.0164(5) Uani 1 1 d . . . . .
H1 H 0.3718 0.5084 0.6997 0.020 Uiso 1 1 calc R U . . .
C2 C 0.3910(2) 0.4342(3) 0.61083(13) 0.0205(6) Uani 1 1 d . . . . .
H2 H 0.3183 0.4474 0.5952 0.025 Uiso 1 1 calc R U . . .
C3 C 0.4669(2) 0.3787(3) 0.57147(13) 0.0228(6) Uani 1 1 d . . . . .
H3 H 0.4466 0.3532 0.5283 0.027 Uiso 1 1 calc R U . . .
C4 C 0.5715(2) 0.3608(3) 0.59514(13) 0.0197(5) Uani 1 1 d . . . . .
H4 H 0.6237 0.3232 0.5682 0.024 Uiso 1 1 calc R U . . .
C5 C 0.60165(19) 0.3977(2) 0.65902(12) 0.0135(5) Uani 1 1 d . . . . .
C6 C 0.78481(19) 0.3113(2) 0.66408(11) 0.0132(5) Uani 1 1 d . . . . .
C7 C 0.7617(2) 0.1864(2) 0.64013(13) 0.0194(5) Uani 1 1 d . . . . .
H7 H 0.6886 0.1574 0.6359 0.023 Uiso 1 1 calc R U . . .
C8 C 0.8444(2) 0.1062(3) 0.62290(14) 0.0246(6) Uani 1 1 d . . . . .
H8 H 0.8290 0.0223 0.6059 0.030 Uiso 1 1 calc R U . . .
C9 C 0.9511(2) 0.1491(3) 0.63052(14) 0.0240(6) Uani 1 1 d . . . . .
H9 H 1.0094 0.0949 0.6189 0.029 Uiso 1 1 calc R U . . .
C10 C 0.9705(2) 0.2705(3) 0.65504(12) 0.0181(5) Uani 1 1 d . . . . .
H10 H 1.0435 0.2991 0.6605 0.022 Uiso 1 1 calc R U . . .
C11 C 0.4741(2) 0.7921(3) 0.76390(13) 0.0199(5) Uani 1 1 d . . . . .
H11 H 0.4251 0.7596 0.7943 0.024 Uiso 1 1 calc R U . . .
C12 C 0.4606(2) 0.9165(3) 0.74189(14) 0.0268(6) Uani 1 1 d . . . . .
H12 H 0.4026 0.9687 0.7559 0.032 Uiso 1 1 calc R U . . .
C13 C 0.5338(2) 0.9643(3) 0.69869(14) 0.0283(6) Uani 1 1 d . . . . .
H13 H 0.5269 1.0505 0.6828 0.034 Uiso 1 1 calc R U . . .
C14 C 0.6166(2) 0.8862(3) 0.67884(13) 0.0208(6) Uani 1 1 d . . . . .
H14 H 0.6681 0.9195 0.6501 0.025 Uiso 1 1 calc R U . . .
C15 C 0.62541(19) 0.7579(2) 0.70072(11) 0.0141(5) Uani 1 1 d . . . . .
C16 C 0.76352(19) 0.6823(2) 0.62850(12) 0.0136(5) Uani 1 1 d . . . . .
C17 C 0.7209(2) 0.7383(2) 0.57076(12) 0.0179(5) Uani 1 1 d . . . . .
H17 H 0.6501 0.7747 0.5694 0.022 Uiso 1 1 calc R U . . .
C18 C 0.7814(2) 0.7407(3) 0.51613(13) 0.0211(6) Uani 1 1 d . . . . .
H18 H 0.7535 0.7808 0.4774 0.025 Uiso 1 1 calc R U . . .
C19 C 0.8837(2) 0.6839(3) 0.51817(13) 0.0236(6) Uani 1 1 d . . . . .
H19 H 0.9269 0.6849 0.4811 0.028 Uiso 1 1 calc R U . . .
C20 C 0.9208(2) 0.6264(3) 0.57485(12) 0.0191(5) Uani 1 1 d . . . . .
H20 H 0.9899 0.5856 0.5759 0.023 Uiso 1 1 calc R U . . .
P1 P 0.5000 0.0000 0.5000 0.0184(2) Uani 1 2 d S . P . .
F1 F 0.51653(13) 0.13602(15) 0.46373(8) 0.0285(4) Uani 1 1 d . . . . .
F2 F 0.60747(14) 0.02680(17) 0.54425(9) 0.0351(4) Uani 1 1 d . . . . .
F3 F 0.42904(16) 0.07052(17) 0.55221(9) 0.0393(5) Uani 1 1 d . . . . .
C21 C 0.7718(3) 0.2331(4) 0.43893(18) 0.0460(9) Uani 1 1 d . . . . .
H21A H 0.7646 0.2702 0.3946 0.055 Uiso 1 1 calc R U . . .
H21B H 0.6999 0.1997 0.4504 0.055 Uiso 1 1 calc R U . . .
Cl2 Cl 0.86561(11) 0.10452(11) 0.43952(7) 0.0758(4) Uani 1 1 d . . . . .
Cl3 Cl 0.81265(7) 0.35526(8) 0.49411(4) 0.03590(18) Uani 1 1 d . . . . .
C22 C 0.2500 0.2429(5) 0.7500 0.074(2) Uani 1 2 d S T P . .
H22A H 0.3147 0.2996 0.7536 0.089 Uiso 0.5 1 calc R U P . .
H22B H 0.1853 0.2996 0.7464 0.089 Uiso 0.5 1 calc R U P . .
Cl4 Cl 0.25584(7) 0.15178(9) 0.67929(5) 0.0449(2) Uani 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pd Pd -0.9988 1.0072 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
N4 Pd1 N6 88.35(8) . 2_656
N4 Pd1 N1 87.89(8) . .
N6 Pd1 N1 170.92(8) 2_656 .
N4 Pd1 N3 171.96(8) . 2_656
N6 Pd1 N3 90.31(8) 2_656 2_656
N1 Pd1 N3 92.26(8) . 2_656
N4 Pd1 Ru2 86.20(9) . .
N6 Pd1 Ru2 85.62(17) 2_656 .
N1 Pd1 Ru2 85.89(17) . .
N3 Pd1 Ru2 85.79(9) 2_656 .
N4 Pd1 Ru2 86.07(9) . 2_656
N6 Pd1 Ru2 85.95(15) 2_656 2_656
N1 Pd1 Ru2 85.55(15) . 2_656
N3 Pd1 Ru2 85.93(9) 2_656 2_656
Ru2 Pd1 Ru2 0.4(3) . 2_656
N4 Pd1 Cl1 94.93(6) . .
N6 Pd1 Cl1 95.52(6) 2_656 .
N1 Pd1 Cl1 93.03(5) . .
N3 Pd1 Cl1 93.10(6) 2_656 .
Ru2 Pd1 Cl1 178.41(6) . .
Ru2 Pd1 Cl1 178.24(8) 2_656 .
N4 Ru1 N6 88.35(8) . 2_656
N4 Ru1 N1 87.89(8) . .
N6 Ru1 N1 170.92(8) 2_656 .
N4 Ru1 N3 171.96(8) . 2_656
N6 Ru1 N3 90.31(8) 2_656 2_656
N1 Ru1 N3 92.26(8) . 2_656
N4 Ru1 Ru2 86.20(9) . .
N6 Ru1 Ru2 85.62(17) 2_656 .
N1 Ru1 Ru2 85.89(17) . .
N3 Ru1 Ru2 85.79(9) 2_656 .
N4 Ru1 Ru2 86.07(9) . 2_656
N6 Ru1 Ru2 85.95(15) 2_656 2_656
N1 Ru1 Ru2 85.55(15) . 2_656
N3 Ru1 Ru2 85.93(9) 2_656 2_656
Ru2 Ru1 Ru2 0.4(3) . 2_656
N4 Ru1 Cl1 94.93(6) . .
N6 Ru1 Cl1 95.52(6) 2_656 .
N1 Ru1 Cl1 93.03(5) . .
N3 Ru1 Cl1 93.10(6) 2_656 .
Ru2 Ru1 Cl1 178.41(6) . .
Ru2 Ru1 Cl1 178.24(8) 2_656 .
Ru2 Ru2 N2 88(2) 2_656 2_656
Ru2 Ru2 N5 88(2) 2_656 2_656
N2 Ru2 N5 90.4(3) 2_656 2_656
Ru2 Ru2 N2 84(2) 2_656 .
N2 Ru2 N2 89.93(12) 2_656 .
N5 Ru2 N2 172.3(2) 2_656 .
Ru2 Ru2 N5 84(2) 2_656 .
N2 Ru2 N5 172.3(2) 2_656 .
N5 Ru2 N5 88.77(12) 2_656 .
N2 Ru2 N5 89.9(3) . .
Ru2 Ru2 Ru1 177(3) 2_656 .
N2 Ru2 Ru1 94.16(17) 2_656 .
N5 Ru2 Ru1 94.41(17) 2_656 .
N2 Ru2 Ru1 93.21(17) . .
N5 Ru2 Ru1 93.58(17) . .
Ru2 Ru2 Pd1 177(3) 2_656 .
N2 Ru2 Pd1 94.16(17) 2_656 .
N5 Ru2 Pd1 94.41(17) 2_656 .
N2 Ru2 Pd1 93.21(17) . .
N5 Ru2 Pd1 93.58(17) . .
Ru2 Ru2 Pd1 3(3) 2_656 2_656
N2 Ru2 Pd1 85.79(15) 2_656 2_656
N5 Ru2 Pd1 86.14(15) 2_656 2_656
N2 Ru2 Pd1 86.23(15) . 2_656
N5 Ru2 Pd1 86.47(15) . 2_656
Pd1 Ru2 Pd1 179.4(2) . 2_656
Ru2 Ru2 Ru1 3(3) 2_656 2_656
N2 Ru2 Ru1 85.79(15) 2_656 2_656
N5 Ru2 Ru1 86.14(15) 2_656 2_656
N2 Ru2 Ru1 86.23(15) . 2_656
N5 Ru2 Ru1 86.47(15) . 2_656
Ru1 Ru2 Ru1 179.4(2) . 2_656
C1 N1 C5 119.2(2) . .
C1 N1 Ru1 118.83(16) . .
C5 N1 Ru1 121.22(16) . .
C1 N1 Pd1 118.83(16) . .
C5 N1 Pd1 121.22(16) . .
C5 N2 C6 123.6(2) . .
C5 N2 Ru2 120.65(19) . 2_656
C6 N2 Ru2 115.40(19) . 2_656
C5 N2 Ru2 114.32(19) . .
C6 N2 Ru2 122.1(2) . .
Ru2 N2 Ru2 7.7(2) 2_656 .
C10 N3 C6 118.9(2) . .
C10 N3 Ru1 119.47(16) . 2_656
C6 N3 Ru1 121.63(16) . 2_656
C10 N3 Pd1 119.47(16) . 2_656
C6 N3 Pd1 121.63(16) . 2_656
C11 N4 C15 119.8(2) . .
C11 N4 Ru1 118.03(17) . .
C15 N4 Ru1 122.01(16) . .
C11 N4 Pd1 118.03(17) . .
C15 N4 Pd1 122.01(16) . .
C15 N5 C16 123.7(2) . .
C15 N5 Ru2 121.3(2) . 2_656
C16 N5 Ru2 114.96(19) . 2_656
C15 N5 Ru2 114.40(19) . .
C16 N5 Ru2 121.95(19) . .
Ru2 N5 Ru2 7.7(2) 2_656 .
C20 N6 C16 119.1(2) . .
C20 N6 Ru1 118.80(16) . 2_656
C16 N6 Ru1 122.14(16) . 2_656
C20 N6 Pd1 118.80(16) . 2_656
C16 N6 Pd1 122.14(16) . 2_656
N1 C1 C2 122.9(2) . .
C1 C2 C3 118.4(2) . .
C4 C3 C2 119.7(2) . .
C3 C4 C5 120.2(2) . .
N1 C5 N2 116.1(2) . .
N1 C5 C4 119.6(2) . .
N2 C5 C4 124.0(2) . .
N3 C6 N2 116.3(2) . .
N3 C6 C7 120.0(2) . .
N2 C6 C7 123.5(2) . .
C8 C7 C6 120.1(2) . .
C7 C8 C9 119.4(2) . .
C10 C9 C8 118.9(2) . .
N3 C10 C9 122.8(2) . .
N4 C11 C12 122.9(2) . .
C11 C12 C13 118.3(3) . .
C14 C13 C12 119.6(3) . .
C13 C14 C15 120.4(2) . .
N4 C15 N5 116.3(2) . .
N4 C15 C14 119.0(2) . .
N5 C15 C14 124.5(2) . .
N6 C16 N5 116.3(2) . .
N6 C16 C17 119.8(2) . .
N5 C16 C17 123.8(2) . .
C18 C17 C16 120.2(2) . .
C17 C18 C19 119.3(2) . .
C20 C19 C18 118.6(2) . .
N6 C20 C19 122.9(2) . .
F3 P1 F3 180.0 . 3_656
F3 P1 F2 90.16(10) . .
F3 P1 F2 89.84(10) 3_656 .
F3 P1 F2 89.85(10) . 3_656
F3 P1 F2 90.16(10) 3_656 3_656
F2 P1 F2 180.00(12) . 3_656
F3 P1 F1 89.92(9) . .
F3 P1 F1 90.08(9) 3_656 .
F2 P1 F1 89.72(8) . .
F2 P1 F1 90.28(8) 3_656 .
F3 P1 F1 90.08(9) . 3_656
F3 P1 F1 89.92(9) 3_656 3_656
F2 P1 F1 90.28(8) . 3_656
F2 P1 F1 89.72(8) 3_656 3_656
F1 P1 F1 180.0 . 3_656
Cl3 C21 Cl2 111.5(2) . .
Cl4 C22 Cl4 114.4(3) 2_556 .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pd1 N4 2.073(2) .
Pd1 N6 2.087(2) 2_656
Pd1 N1 2.090(2) .
Pd1 N3 2.095(2) 2_656
Pd1 Ru2 2.241(3) .
Pd1 Ru2 2.512(3) 2_656
Pd1 Cl1 2.6757(7) .
Ru1 N4 2.073(2) .
Ru1 N6 2.087(2) 2_656
Ru1 N1 2.090(2) .
Ru1 N3 2.095(2) 2_656
Ru1 Ru2 2.241(3) .
Ru1 Ru2 2.512(3) 2_656
Ru1 Cl1 2.6757(7) .
Ru2 Ru2 0.272(7) 2_656
Ru2 N2 2.019(5) 2_656
Ru2 N5 2.022(5) 2_656
Ru2 N2 2.028(5) .
Ru2 N5 2.031(5) .
Ru2 Pd1 2.512(3) 2_656
Ru2 Ru1 2.512(3) 2_656
N1 C1 1.357(3) .
N1 C5 1.366(3) .
N2 C5 1.377(3) .
N2 C6 1.377(3) .
N2 Ru2 2.019(5) 2_656
N3 C10 1.358(3) .
N3 C6 1.365(3) .
N3 Ru1 2.095(2) 2_656
N3 Pd1 2.095(2) 2_656
N4 C11 1.350(3) .
N4 C15 1.363(3) .
N5 C15 1.381(3) .
N5 C16 1.383(3) .
N5 Ru2 2.022(5) 2_656
N6 C20 1.357(3) .
N6 C16 1.364(3) .
N6 Ru1 2.087(2) 2_656
N6 Pd1 2.087(2) 2_656
C1 C2 1.370(4) .
C2 C3 1.388(4) .
C3 C4 1.372(4) .
C4 C5 1.404(3) .
C6 C7 1.405(3) .
C7 C8 1.372(4) .
C8 C9 1.390(4) .
C9 C10 1.368(4) .
C11 C12 1.369(4) .
C12 C13 1.384(4) .
C13 C14 1.377(4) .
C14 C15 1.401(3) .
C16 C17 1.403(3) .
C17 C18 1.375(4) .
C18 C19 1.391(4) .
C19 C20 1.370(4) .
P1 F3 1.5906(17) .
P1 F3 1.5906(17) 3_656
P1 F2 1.6003(16) .
P1 F2 1.6004(16) 3_656
P1 F1 1.6067(15) .
P1 F1 1.6067(15) 3_656
C21 Cl3 1.756(4) .
C21 Cl2 1.760(4) .
C22 Cl4 1.737(3) 2_556
C22 Cl4 1.737(3) .
