#------------------------------------------------------------------------------
#$Date: 2025-08-21 22:04:39 +0200 (Thu 21 de Aug de 2025) $
#$Revision: 301851 $
#$URL: svn://www.crystallography.net/cod/cif/7/05/26/7052641.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7052641
loop_
_publ_author_name
'Monteiro, Jorge H. S. K.'
'Adati, Renata D.'
'Davolos, Marian R.'
'Vicenti, Juliano R. M.'
'Burrow, Robert A.'
_publ_section_title
;
 Correlation between structural data and spectroscopic studies of a new
 β-diketonate complex with trivalent europium and gadolinium
;
_journal_issue                   6
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              1234
_journal_paper_doi               10.1039/c0nj00831a
_journal_volume                  35
_journal_year                    2011
_chemical_formula_moiety         'C78 H78 Eu O10 P'
_chemical_formula_sum            'C78 H78 Eu O10 P'
_chemical_formula_weight         1358.33
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           'APEX2 v2010.1-2'
_cell_angle_alpha                96.589(2)
_cell_angle_beta                 103.689(2)
_cell_angle_gamma                103.835(2)
_cell_formula_units_Z            2
_cell_length_a                   12.7980(7)
_cell_length_b                   13.1163(7)
_cell_length_c                   21.6536(12)
_cell_measurement_reflns_used    9770
_cell_measurement_temperature    296.(2)
_cell_measurement_theta_max      30.4069
_cell_measurement_theta_min      2.6606
_cell_volume                     3372.1(3)
_computing_cell_refinement       'SAINT V7.68A (Bruker AXS, 2009)'
_computing_data_collection       'Bruker Instrument Service v2009, 11, 0, 0'
_computing_data_reduction        'SAINT V7.68A (Bruker AXS, 2009)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      296.(2)
_diffrn_detector_area_resol_mean 8.3333
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0331
_diffrn_reflns_av_sigmaI/netI    0.0461
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       30
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_number            67448
_diffrn_reflns_theta_full        30.55
_diffrn_reflns_theta_max         30.55
_diffrn_reflns_theta_min         2.66
_exptl_absorpt_coefficient_mu    1.013
_exptl_absorpt_correction_T_max  0.85
_exptl_absorpt_correction_T_min  0.71
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'SADABS V2008/1 (Bruker AXS)'
_exptl_crystal_colour            'pale yellow'
_exptl_crystal_density_diffrn    1.338
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1408
_exptl_crystal_size_max          0.44
_exptl_crystal_size_mid          0.40
_exptl_crystal_size_min          0.17
_refine_diff_density_max         0.973
_refine_diff_density_min         -0.872
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.061
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     838
_refine_ls_number_reflns         20518
_refine_ls_number_restraints     60
_refine_ls_restrained_S_all      1.071
_refine_ls_R_factor_all          0.0460
_refine_ls_R_factor_gt           0.0352
_refine_ls_shift/su_max          0.006
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0408P)²+0.9651P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0787
_refine_ls_wR_factor_ref         0.0831
_reflns_number_gt                17569
_reflns_number_total             20518
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            c0nj00831a.txt
_cod_data_source_block           RB_UNESP_MD_Eutppo
_cod_database_code               7052641
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu1 Eu 0.962078(7) 0.894227(7) 0.724714(5) 0.01727(3) Uani 1 1 d . C .
O1 O 0.90565(11) 0.75650(10) 0.78381(7) 0.0198(3) Uani 1 1 d . . .
O2 O 1.57765(12) 0.72160(13) 0.82736(9) 0.0321(4) Uani 1 1 d . . .
O3 O 1.11776(11) 0.83583(12) 0.77007(8) 0.0280(3) Uani 1 1 d . . .
O4 O 1.06715(12) 0.90081(11) 0.65087(7) 0.0254(3) Uani 1 1 d . . .
O5 O 1.38207(13) 0.81356(13) 0.48368(8) 0.0322(4) Uani 1 1 d . . .
O6 O 0.97000(14) 1.05158(12) 0.68532(8) 0.0305(4) Uani 1 1 d . . .
O7 O 0.82978(12) 0.79357(12) 0.63283(7) 0.0252(3) Uani 1 1 d . . .
O8 O 0.43311(17) 1.1849(2) 0.74637(12) 0.0683(7) Uani 1 1 d . . .
O9 O 0.79074(11) 0.93188(12) 0.72707(7) 0.0233(3) Uani 1 1 d . . .
O10 O 1.03667(13) 1.01969(12) 0.82035(8) 0.0309(4) Uani 1 1 d . . .
C1 C 0.95520(15) 0.70378(14) 0.82079(9) 0.0174(4) Uani 1 1 d . . .
C2 C 1.06782(15) 0.70519(16) 0.83178(10) 0.0211(4) Uani 1 1 d . . .
H2 H 1.0947 0.6622 0.8593 0.025 Uiso 1 1 calc R . .
C3 C 1.14271(15) 0.76782(16) 0.80366(10) 0.0204(4) Uani 1 1 d . . .
C4 C 1.08830(15) 0.95603(15) 0.60845(10) 0.0200(4) Uani 1 1 d . . .
C5 C 1.05049(17) 1.04614(16) 0.59817(10) 0.0227(4) Uani 1 1 d . . .
H5 H 1.0627 1.0779 0.5633 0.027 Uiso 1 1 calc R . .
C6 C 0.99501(16) 1.09061(15) 0.63821(10) 0.0199(4) Uani 1 1 d . . .
C7 C 0.73528(16) 0.79857(16) 0.59963(10) 0.0228(4) Uani 1 1 d . . .
C8 C 0.67181(16) 0.86064(16) 0.62114(10) 0.0233(4) Uani 1 1 d . . .
H8 H 0.6045 0.8598 0.5927 0.028 Uiso 1 1 calc R . .
C9 C 0.70255(16) 0.92434(16) 0.68282(10) 0.0217(4) Uani 1 1 d . . .
C11 C 0.88538(15) 0.63233(15) 0.85413(10) 0.0189(4) Uani 1 1 d . . .
C12 C 0.77359(17) 0.58263(17) 0.82307(11) 0.0268(5) Uani 1 1 d . . .
H12 H 0.7429 0.5938 0.7818 0.032 Uiso 1 1 calc R . .
C13 C 0.70667(17) 0.51615(18) 0.85282(12) 0.0320(5) Uani 1 1 d . . .
H13 H 0.6324 0.4824 0.8305 0.038 Uiso 1 1 calc R . .
C14 C 0.74787(17) 0.49906(17) 0.91469(11) 0.0259(5) Uani 1 1 d . . .
C15 C 0.86102(18) 0.54967(18) 0.94624(11) 0.0285(5) Uani 1 1 d . . .
H15 H 0.8912 0.5399 0.9879 0.034 Uiso 1 1 calc R . .
C16 C 0.92873(17) 0.61421(17) 0.91618(11) 0.0264(5) Uani 1 1 d . . .
H16 H 1.0038 0.6457 0.9376 0.032 Uiso 1 1 calc R . .
C17 C 0.67566(19) 0.42740(19) 0.94898(12) 0.0337(5) Uani 1 1 d . . .
C18 C 0.5531(2) 0.3815(2) 0.90681(15) 0.0516(8) Uani 1 1 d . . .
H18A H 0.5517 0.3399 0.8670 0.077 Uiso 1 1 calc R . .
H18B H 0.5211 0.4391 0.8977 0.077 Uiso 1 1 calc R . .
H18C H 0.5106 0.3370 0.9296 0.077 Uiso 1 1 calc R . .
C19 C 0.6770(3) 0.4911(2) 1.01248(16) 0.0616(10) Uani 1 1 d . . .
H19A H 0.6280 0.4475 1.0325 0.092 Uiso 1 1 calc R . .
H19B H 0.6520 0.5530 1.0044 0.092 Uiso 1 1 calc R . .
H19C H 0.7517 0.5131 1.0407 0.092 Uiso 1 1 calc R . .
C20 C 0.7222(2) 0.3331(2) 0.96254(15) 0.0491(7) Uani 1 1 d . . .
H20A H 0.7191 0.2912 0.9224 0.074 Uiso 1 1 calc R . .
H20B H 0.6784 0.2897 0.9852 0.074 Uiso 1 1 calc R . .
H20C H 0.7984 0.3590 0.9885 0.074 Uiso 1 1 calc R . .
C31 C 1.25786(15) 0.75574(16) 0.81218(10) 0.0221(4) Uani 1 1 d . . .
C32 C 1.29690(16) 0.67944(16) 0.84344(10) 0.0229(4) Uani 1 1 d . . .
H32 H 1.2505 0.6345 0.8621 0.027 Uiso 1 1 calc R . .
C33 C 1.40291(16) 0.66938(17) 0.84719(11) 0.0245(4) Uani 1 1 d . . .
H33 H 1.4268 0.6172 0.8677 0.029 Uiso 1 1 calc R . .
C34 C 1.47448(16) 0.73726(17) 0.82038(11) 0.0245(4) Uani 1 1 d . . .
C35 C 1.43755(18) 0.81377(19) 0.78924(13) 0.0354(6) Uani 1 1 d . . .
H35 H 1.4846 0.8598 0.7715 0.042 Uiso 1 1 calc R . .
C36 C 1.33010(18) 0.82120(19) 0.78474(13) 0.0344(6) Uani 1 1 d . . .
H36 H 1.3053 0.8715 0.7627 0.041 Uiso 1 1 calc R . .
C37 C 1.65269(19) 0.7893(2) 0.79975(15) 0.0420(7) Uani 1 1 d . . .
H37A H 1.6220 0.7772 0.7537 0.063 Uiso 1 1 calc R . .
H37B H 1.7236 0.7735 0.8096 0.063 Uiso 1 1 calc R . .
H37C H 1.6627 0.8627 0.8174 0.063 Uiso 1 1 calc R . .
C41 C 1.16191(16) 0.92083(15) 0.57111(10) 0.0201(4) Uani 1 1 d . . .
C42 C 1.19597(17) 0.82961(16) 0.58365(10) 0.0237(4) Uani 1 1 d . . .
H42 H 1.1692 0.7911 0.6128 0.028 Uiso 1 1 calc R . .
C43 C 1.26822(17) 0.79602(17) 0.55357(11) 0.0246(4) Uani 1 1 d . . .
H43 H 1.2901 0.7354 0.5627 0.030 Uiso 1 1 calc R . .
C44 C 1.30892(16) 0.85268(17) 0.50931(10) 0.0233(4) Uani 1 1 d . . .
C45 C 1.27493(17) 0.94235(17) 0.49538(10) 0.0243(4) Uani 1 1 d . . .
H45 H 1.3005 0.9796 0.4654 0.029 Uiso 1 1 calc R . .
C46 C 1.20252(16) 0.97616(16) 0.52643(10) 0.0226(4) Uani 1 1 d . . .
H46 H 1.1807 1.0367 0.5173 0.027 Uiso 1 1 calc R . .
C47 C 1.4173(2) 0.8607(2) 0.43276(12) 0.0379(6) Uani 1 1 d . . .
H47A H 1.3528 0.8589 0.3988 0.057 Uiso 1 1 calc R . .
H47B H 1.4620 0.8214 0.4160 0.057 Uiso 1 1 calc R . .
H47C H 1.4607 0.9334 0.4494 0.057 Uiso 1 1 calc R . .
C71 C 0.69480(17) 0.73330(16) 0.53297(11) 0.0240(4) Uani 1 1 d . . .
C72 C 0.77284(18) 0.72056(17) 0.49962(11) 0.0279(5) Uani 1 1 d . . .
H72 H 0.8479 0.7570 0.5178 0.033 Uiso 1 1 calc R . .
C73 C 0.74040(19) 0.65501(19) 0.44044(12) 0.0332(5) Uani 1 1 d . . .
H73 H 0.7938 0.6501 0.4185 0.040 Uiso 1 1 calc R . .
C74 C 0.6296(2) 0.5955(2) 0.41229(12) 0.0350(5) Uani 1 1 d . A .
C75 C 0.5514(2) 0.6111(2) 0.44460(13) 0.0390(6) Uani 1 1 d . . .
H75 H 0.4764 0.5745 0.4264 0.047 Uiso 1 1 calc R . .
C76 C 0.58276(18) 0.6800(2) 0.50332(12) 0.0339(5) Uani 1 1 d . . .
H76 H 0.5284 0.6908 0.5232 0.041 Uiso 1 1 calc R . .
C77 C 0.5976(2) 0.5150(2) 0.35041(12) 0.0448(7) Uani 1 1 d D . .
C78 C 0.7038(4) 0.4930(6) 0.3324(3) 0.061(2) Uani 0.531(6) 1 d PDU A 1
H78A H 0.7502 0.4747 0.3688 0.091 Uiso 0.531(6) 1 calc PR A 1
H78B H 0.7454 0.5559 0.3211 0.091 Uiso 0.531(6) 1 calc PR A 1
H78C H 0.6803 0.4350 0.2963 0.091 Uiso 0.531(6) 1 calc PR A 1
C79 C 0.5195(5) 0.5361(5) 0.2974(3) 0.0547(17) Uani 0.531(6) 1 d PDU A 1
H79A H 0.5034 0.4815 0.2603 0.082 Uiso 0.531(6) 1 calc PR A 1
H79B H 0.5512 0.6043 0.2876 0.082 Uiso 0.531(6) 1 calc PR A 1
H79C H 0.4517 0.5367 0.3090 0.082 Uiso 0.531(6) 1 calc PR A 1
C80 C 0.5444(5) 0.4021(4) 0.3673(3) 0.0541(17) Uani 0.531(6) 1 d PDU A 1
H80A H 0.5291 0.3469 0.3306 0.081 Uiso 0.531(6) 1 calc PR A 1
H80B H 0.4759 0.4029 0.3781 0.081 Uiso 0.531(6) 1 calc PR A 1
H80C H 0.5960 0.3887 0.4034 0.081 Uiso 0.531(6) 1 calc PR A 1
C78A C 0.6477(9) 0.4288(7) 0.3578(5) 0.098(4) Uani 0.469(6) 1 d PDU A 2
H78D H 0.6102 0.3711 0.3219 0.147 Uiso 0.469(6) 1 calc PR A 2
H78E H 0.6411 0.4045 0.3973 0.147 Uiso 0.469(6) 1 calc PR A 2
H78F H 0.7253 0.4530 0.3592 0.147 Uiso 0.469(6) 1 calc PR A 2
C79A C 0.6259(8) 0.5786(6) 0.2966(3) 0.086(3) Uani 0.469(6) 1 d PDU A 2
H79D H 0.7041 0.6160 0.3093 0.129 Uiso 0.469(6) 1 calc PR A 2
H79E H 0.5825 0.6289 0.2910 0.129 Uiso 0.469(6) 1 calc PR A 2
H79F H 0.6085 0.5297 0.2567 0.129 Uiso 0.469(6) 1 calc PR A 2
C80A C 0.4677(5) 0.4686(6) 0.3218(3) 0.066(2) Uani 0.469(6) 1 d PDU A 2
H80D H 0.4518 0.4226 0.2809 0.099 Uiso 0.469(6) 1 calc PR A 2
H80E H 0.4342 0.5262 0.3159 0.099 Uiso 0.469(6) 1 calc PR A 2
H80F H 0.4377 0.4286 0.3511 0.099 Uiso 0.469(6) 1 calc PR A 2
C61 C 0.96391(16) 1.19174(15) 0.62876(10) 0.0197(4) Uani 1 1 d . . .
C62 C 0.98800(17) 1.24999(16) 0.58148(11) 0.0252(4) Uani 1 1 d . . .
H62 H 1.0239 1.2251 0.5528 0.030 Uiso 1 1 calc R . .
C63 C 0.95900(19) 1.34419(17) 0.57687(12) 0.0310(5) Uani 1 1 d . . .
H63 H 0.9778 1.3824 0.5456 0.037 Uiso 1 1 calc R . .
C64 C 0.90254(19) 1.38397(16) 0.61749(11) 0.0281(5) Uani 1 1 d . B .
C65 C 0.8761(2) 1.32369(19) 0.66308(12) 0.0366(6) Uani 1 1 d . . .
H65 H 0.8369 1.3467 0.6904 0.044 Uiso 1 1 calc R . .
C66 C 0.9067(2) 1.23013(18) 0.66899(12) 0.0335(5) Uani 1 1 d . . .
H66 H 0.8886 1.1923 0.7005 0.040 Uiso 1 1 calc R . .
C67 C 0.8685(2) 1.48719(17) 0.61017(12) 0.0357(6) Uani 1 1 d D . .
C68 C 0.7780(3) 1.4672(2) 0.54550(15) 0.0407(8) Uani 0.875(4) 1 d PD B 1
H68A H 0.7178 1.4060 0.5436 0.061 Uiso 0.875(4) 1 calc PR B 1
H68B H 0.8099 1.4546 0.5104 0.061 Uiso 0.875(4) 1 calc PR B 1
H68C H 0.7500 1.5286 0.5422 0.061 Uiso 0.875(4) 1 calc PR B 1
C69 C 0.9683(3) 1.5779(2) 0.61317(18) 0.0453(9) Uani 0.875(4) 1 d PD B 1
H69A H 1.0000 1.5611 0.5786 0.068 Uiso 0.875(4) 1 calc PR B 1
H69B H 1.0232 1.5887 0.6539 0.068 Uiso 0.875(4) 1 calc PR B 1
H69C H 0.9452 1.6418 0.6089 0.068 Uiso 0.875(4) 1 calc PR B 1
C70 C 0.8142(3) 1.5203(2) 0.66327(15) 0.0430(8) Uani 0.875(4) 1 d PD B 1
H70A H 0.7950 1.5855 0.6571 0.064 Uiso 0.875(4) 1 calc PR B 1
H70B H 0.8661 1.5307 0.7050 0.064 Uiso 0.875(4) 1 calc PR B 1
H70C H 0.7478 1.4651 0.6605 0.064 Uiso 0.875(4) 1 calc PR B 1
C68A C 0.7516(10) 1.490(2) 0.5889(13) 0.082(10) Uiso 0.125(4) 1 d PD B 2
H68D H 0.7471 1.5461 0.5641 0.124 Uiso 0.125(4) 1 calc PR B 2
H68E H 0.7248 1.5041 0.6260 0.124 Uiso 0.125(4) 1 calc PR B 2
H68F H 0.7064 1.4230 0.5627 0.124 Uiso 0.125(4) 1 calc PR B 2
C69A C 0.9309(19) 1.536(2) 0.5605(10) 0.064(8) Uiso 0.125(4) 1 d PD B 2
H69D H 0.8912 1.4982 0.5174 0.096 Uiso 0.125(4) 1 calc PR B 2
H69E H 1.0057 1.5288 0.5708 0.096 Uiso 0.125(4) 1 calc PR B 2
H69F H 0.9334 1.6100 0.5631 0.096 Uiso 0.125(4) 1 calc PR B 2
C70A C 0.9415(17) 1.5668(17) 0.6718(7) 0.059(7) Uiso 0.125(4) 1 d PD B 2
H70D H 0.9399 1.6380 0.6661 0.089 Uiso 0.125(4) 1 calc PR B 2
H70E H 1.0171 1.5621 0.6801 0.089 Uiso 0.125(4) 1 calc PR B 2
H70F H 0.9129 1.5501 0.7078 0.089 Uiso 0.125(4) 1 calc PR B 2
C91 C 0.62831(17) 0.98981(17) 0.69848(10) 0.0238(4) Uani 1 1 d . . .
C92 C 0.51397(17) 0.96148(18) 0.66828(11) 0.0270(5) Uani 1 1 d . . .
H92 H 0.4821 0.8992 0.6375 0.032 Uiso 1 1 calc R . .
C93 C 0.44623(19) 1.0237(2) 0.68285(12) 0.0336(5) Uani 1 1 d . . .
H93 H 0.3700 1.0030 0.6621 0.040 Uiso 1 1 calc R . .
C94 C 0.4925(2) 1.1168(2) 0.72847(13) 0.0416(6) Uani 1 1 d . . .
C95 C 0.6068(2) 1.1470(2) 0.75897(14) 0.0452(7) Uani 1 1 d . . .
H95 H 0.6386 1.2100 0.7892 0.054 Uiso 1 1 calc R . .
C96 C 0.67320(19) 1.0836(2) 0.74446(12) 0.0337(5) Uani 1 1 d . . .
H96 H 0.7492 1.1040 0.7658 0.040 Uiso 1 1 calc R . .
C97 C 0.3163(3) 1.1566(4) 0.7120(2) 0.0945(17) Uani 1 1 d . . .
H97A H 0.3084 1.1483 0.6664 0.142 Uiso 1 1 calc R . .
H97B H 0.2842 1.2119 0.7248 0.142 Uiso 1 1 calc R . .
H97C H 0.2784 1.0906 0.7220 0.142 Uiso 1 1 calc R . .
P1 P 1.06954(12) 1.10959(7) 0.87672(4) 0.0299(2) Uani 0.884(4) 1 d P C 1
C111 C 0.97221(19) 1.09013(18) 0.92521(9) 0.0346(7) Uani 0.884(4) 1 d PG C 1
C112 C 1.0004(2) 1.12600(17) 0.99153(9) 0.0439(8) Uani 0.884(4) 1 d PG C 1
H112 H 1.0751 1.1544 1.0148 0.053 Uiso 0.884(4) 1 calc PR C 1
C113 C 0.9169(2) 1.11942(18) 1.02313(8) 0.0552(12) Uani 0.884(4) 1 d PG C 1
H113 H 0.9358 1.1434 1.0675 0.066 Uiso 0.884(4) 1 calc PR C 1
C114 C 0.8053(2) 1.0770(2) 0.98841(11) 0.0493(9) Uani 0.884(4) 1 d PG C 1
H114 H 0.7494 1.0726 1.0096 0.059 Uiso 0.884(4) 1 calc PR C 1
C115 C 0.77709(18) 1.0411(2) 0.92210(10) 0.0541(9) Uani 0.884(4) 1 d PG C 1
H115 H 0.7024 1.0127 0.8989 0.065 Uiso 0.884(4) 1 calc PR C 1
C116 C 0.8606(2) 1.0477(2) 0.89050(8) 0.0453(8) Uani 0.884(4) 1 d PG C 1
H116 H 0.8417 1.0237 0.8461 0.054 Uiso 0.884(4) 1 calc PR C 1
C121 C 1.21126(18) 1.1249(2) 0.92125(12) 0.0418(9) Uani 0.884(4) 1 d PG C 1
C122 C 1.2676(2) 1.0570(2) 0.89848(14) 0.0528(11) Uani 0.884(4) 1 d PG C 1
H122 H 1.2319 1.0061 0.8611 0.063 Uiso 0.884(4) 1 calc PR C 1
C123 C 1.3774(2) 1.0651(3) 0.93160(19) 0.0771(16) Uani 0.884(4) 1 d PG C 1
H123 H 1.4151 1.0197 0.9164 0.093 Uiso 0.884(4) 1 calc PR C 1
C124 C 1.43075(19) 1.1412(3) 0.98748(18) 0.0850(19) Uani 0.884(4) 1 d PG C 1
H124 H 1.5042 1.1466 1.0096 0.102 Uiso 0.884(4) 1 calc PR C 1
C125 C 1.3744(2) 1.2091(3) 1.01024(14) 0.0785(18) Uani 0.884(4) 1 d PG C 1
H125 H 1.4101 1.2600 1.0476 0.094 Uiso 0.884(4) 1 calc PR C 1
C126 C 1.2646(2) 1.2010(2) 0.97713(13) 0.0572(12) Uani 0.884(4) 1 d PG C 1
H126 H 1.2269 1.2464 0.9924 0.069 Uiso 0.884(4) 1 calc PR C 1
C131 C 1.0699(2) 1.23720(14) 0.85285(11) 0.0359(7) Uani 0.884(4) 1 d PG C 1
C132 C 0.9901(2) 1.28995(17) 0.85991(12) 0.0454(8) Uani 0.884(4) 1 d PG C 1
H132 H 0.9362 1.2621 0.8803 0.055 Uiso 0.884(4) 1 calc PR C 1
C133 C 0.9909(2) 1.38440(17) 0.83650(14) 0.0561(10) Uani 0.884(4) 1 d PG C 1
H133 H 0.9375 1.4197 0.8412 0.067 Uiso 0.884(4) 1 calc PR C 1
C134 C 1.0715(3) 1.42608(15) 0.80603(13) 0.0641(13) Uani 0.884(4) 1 d PG C 1
H134 H 1.0720 1.4893 0.7904 0.077 Uiso 0.884(4) 1 calc PR C 1
C135 C 1.1512(3) 1.37333(18) 0.79897(13) 0.0678(12) Uani 0.884(4) 1 d PG C 1
H135 H 1.2051 1.4012 0.7786 0.081 Uiso 0.884(4) 1 calc PR C 1
C136 C 1.1505(2) 1.27888(17) 0.82238(13) 0.0553(10) Uani 0.884(4) 1 d PG C 1
H136 H 1.2038 1.2436 0.8177 0.066 Uiso 0.884(4) 1 calc PR C 1
P2 P 1.1065(8) 1.1169(6) 0.8730(4) 0.0299(2) Uani 0.116(4) 1 d P C 2
C211 C 1.0174(15) 1.0993(16) 0.9298(8) 0.0346(7) Uani 0.116(4) 1 d PG C 2
C212 C 1.0596(16) 1.1326(15) 0.9963(8) 0.0439(8) Uani 0.116(4) 1 d PG C 2
H212 H 1.1364 1.1578 1.0148 0.053 Uiso 0.116(4) 1 calc PR C 2
C213 C 0.987(2) 1.1284(15) 1.0351(7) 0.0552(12) Uani 0.116(4) 1 d PG C 2
H213 H 1.0150 1.1508 1.0796 0.066 Uiso 0.116(4) 1 calc PR C 2
C214 C 0.8720(19) 1.0909(17) 1.0074(9) 0.0493(9) Uani 0.116(4) 1 d PG C 2
H214 H 0.8233 1.0881 1.0334 0.059 Uiso 0.116(4) 1 calc PR C 2
C215 C 0.8298(15) 1.057(2) 0.9409(9) 0.0541(9) Uani 0.116(4) 1 d PG C 2
H215 H 0.7530 1.0323 0.9224 0.065 Uiso 0.116(4) 1 calc PR C 2
C216 C 0.9025(16) 1.0617(19) 0.9021(7) 0.0453(8) Uani 0.116(4) 1 d PG C 2
H216 H 0.8743 1.0393 0.8576 0.054 Uiso 0.116(4) 1 calc PR C 2
C221 C 1.2435(15) 1.110(2) 0.9150(12) 0.0418(9) Uani 0.116(4) 1 d PG C 2
C222 C 1.2883(18) 1.038(2) 0.8851(12) 0.0528(11) Uani 0.116(4) 1 d PG C 2
H222 H 1.2457 0.9923 0.8466 0.063 Uiso 0.116(4) 1 calc PR C 2
C223 C 1.397(2) 1.034(2) 0.9128(16) 0.0771(16) Uani 0.116(4) 1 d PG C 2
H223 H 1.4266 0.9860 0.8927 0.093 Uiso 0.116(4) 1 calc PR C 2
C224 C 1.4603(16) 1.102(3) 0.9703(15) 0.0850(19) Uani 0.116(4) 1 d PG C 2
H224 H 1.5328 1.0997 0.9888 0.102 Uiso 0.116(4) 1 calc PR C 2
C225 C 1.416(2) 1.174(2) 1.0002(12) 0.0785(18) Uani 0.116(4) 1 d PG C 2
H225 H 1.4581 1.2199 1.0387 0.094 Uiso 0.116(4) 1 calc PR C 2
C226 C 1.307(2) 1.178(2) 0.9725(13) 0.0572(12) Uani 0.116(4) 1 d PG C 2
H226 H 1.2772 1.2262 0.9926 0.069 Uiso 0.116(4) 1 calc PR C 2
C231 C 1.1182(17) 1.2411(13) 0.8518(10) 0.0359(7) Uani 0.116(4) 1 d PG C 2
C232 C 1.0334(16) 1.2911(16) 0.8493(11) 0.0454(8) Uani 0.116(4) 1 d PG C 2
H232 H 0.9717 1.2611 0.8634 0.055 Uiso 0.116(4) 1 calc PR C 2
C233 C 1.0407(19) 1.3860(15) 0.8257(12) 0.0561(10) Uani 0.116(4) 1 d PG C 2
H233 H 0.9840 1.4195 0.8240 0.067 Uiso 0.116(4) 1 calc PR C 2
C234 C 1.133(2) 1.4308(13) 0.8045(12) 0.0641(13) Uani 0.116(4) 1 d PG C 2
H234 H 1.1378 1.4943 0.7887 0.077 Uiso 0.116(4) 1 calc PR C 2
C235 C 1.2177(19) 1.3808(16) 0.8070(12) 0.0678(12) Uani 0.116(4) 1 d PG C 2
H235 H 1.2794 1.4108 0.7929 0.081 Uiso 0.116(4) 1 calc PR C 2
C236 C 1.2103(17) 1.2859(15) 0.8307(11) 0.0553(10) Uani 0.116(4) 1 d PG C 2
H236 H 1.2671 1.2525 0.8324 0.066 Uiso 0.116(4) 1 calc PR C 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O7 Eu1 O6 93.06(6) . . y
O7 Eu1 O4 78.98(5) . . y
O6 Eu1 O4 71.38(5) . . y
O7 Eu1 O10 157.82(6) . . y
O6 Eu1 O10 78.99(6) . . y
O4 Eu1 O10 116.98(6) . . y
O7 Eu1 O3 119.91(6) . . y
O6 Eu1 O3 125.03(5) . . y
O4 Eu1 O3 73.54(5) . . y
O10 Eu1 O3 80.91(6) . . y
O7 Eu1 O9 73.23(5) . . y
O6 Eu1 O9 75.02(5) . . y
O4 Eu1 O9 134.62(5) . . y
O10 Eu1 O9 84.69(5) . . y
O3 Eu1 O9 151.82(5) . . y
O7 Eu1 O1 89.42(5) . . y
O6 Eu1 O1 158.08(5) . . y
O4 Eu1 O1 130.35(5) . . y
O10 Eu1 O1 90.65(5) . . y
O3 Eu1 O1 71.24(4) . . y
O9 Eu1 O1 84.90(5) . . y
C1 O1 Eu1 135.61(11) . . ?
C34 O2 C37 116.98(17) . . ?
C3 O3 Eu1 139.73(12) . . ?
C4 O4 Eu1 138.10(13) . . ?
C44 O5 C47 117.77(18) . . ?
C6 O6 Eu1 137.88(14) . . ?
C7 O7 Eu1 135.33(14) . . ?
C94 O8 C97 115.7(2) . . ?
C9 O9 Eu1 132.36(13) . . ?
P1 O10 P2 18.4(3) . . ?
P1 O10 Eu1 170.00(11) . . ?
P2 O10 Eu1 164.5(4) . . ?
O1 C1 C2 125.58(15) . . ?
O1 C1 C11 116.68(16) . . ?
C2 C1 C11 117.72(17) . . ?
C1 C2 C3 123.86(18) . . ?
C1 C2 H2 118.1 . . ?
C3 C2 H2 118.1 . . ?
O3 C3 C2 123.32(18) . . ?
O3 C3 C31 116.34(15) . . ?
C2 C3 C31 120.34(17) . . ?
O4 C4 C5 123.70(18) . . ?
O4 C4 C41 115.04(18) . . ?
C5 C4 C41 121.22(16) . . ?
C4 C5 C6 122.87(17) . . ?
C4 C5 H5 118.6 . . ?
C6 C5 H5 118.6 . . ?
O6 C6 C5 123.91(18) . . ?
O6 C6 C61 114.81(17) . . ?
C5 C6 C61 121.25(17) . . ?
O7 C7 C8 124.6(2) . . ?
O7 C7 C71 115.11(19) . . ?
C8 C7 C71 120.33(19) . . ?
C7 C8 C9 124.55(19) . . ?
C7 C8 H8 117.7 . . ?
C9 C8 H8 117.7 . . ?
O9 C9 C8 124.79(19) . . ?
O9 C9 C91 116.44(19) . . ?
C8 C9 C91 118.77(18) . . ?
C12 C11 C16 118.08(16) . . ?
C12 C11 C1 119.56(17) . . ?
C16 C11 C1 122.36(17) . . ?
C11 C12 C13 120.9(2) . . ?
C11 C12 H12 119.6 . . ?
C13 C12 H12 119.6 . . ?
C14 C13 C12 121.7(2) . . ?
C14 C13 H13 119.2 . . ?
C12 C13 H13 119.2 . . ?
C13 C14 C15 117.43(17) . . ?
C13 C14 C17 122.80(19) . . ?
C15 C14 C17 119.8(2) . . ?
C16 C15 C14 121.1(2) . . ?
C16 C15 H15 119.5 . . ?
C14 C15 H15 119.5 . . ?
C15 C16 C11 120.84(19) . . ?
C15 C16 H16 119.6 . . ?
C11 C16 H16 119.6 . . ?
C19 C17 C20 109.2(2) . . ?
C19 C17 C14 109.61(19) . . ?
C20 C17 C14 109.65(19) . . ?
C19 C17 C18 109.2(2) . . ?
C20 C17 C18 107.4(2) . . ?
C14 C17 C18 111.72(19) . . ?
C17 C18 H18A 109.5 . . ?
C17 C18 H18B 109.5 . . ?
H18A C18 H18B 109.5 . . ?
C17 C18 H18C 109.5 . . ?
H18A C18 H18C 109.5 . . ?
H18B C18 H18C 109.5 . . ?
C17 C19 H19A 109.5 . . ?
C17 C19 H19B 109.5 . . ?
H19A C19 H19B 109.5 . . ?
C17 C19 H19C 109.5 . . ?
H19A C19 H19C 109.5 . . ?
H19B C19 H19C 109.5 . . ?
C17 C20 H20A 109.5 . . ?
C17 C20 H20B 109.5 . . ?
H20A C20 H20B 109.5 . . ?
C17 C20 H20C 109.5 . . ?
H20A C20 H20C 109.5 . . ?
H20B C20 H20C 109.5 . . ?
C36 C31 C32 117.38(18) . . ?
C36 C31 C3 118.38(18) . . ?
C32 C31 C3 124.17(15) . . ?
C33 C32 C31 121.28(16) . . ?
C33 C32 H32 119.4 . . ?
C31 C32 H32 119.4 . . ?
C32 C33 C34 120.26(19) . . ?
C32 C33 H33 119.9 . . ?
C34 C33 H33 119.9 . . ?
O2 C34 C35 124.91(17) . . ?
O2 C34 C33 115.65(19) . . ?
C35 C34 C33 119.44(18) . . ?
C36 C35 C34 119.49(18) . . ?
C36 C35 H35 120.3 . . ?
C34 C35 H35 120.3 . . ?
C35 C36 C31 122.1(2) . . ?
C35 C36 H36 118.9 . . ?
C31 C36 H36 118.9 . . ?
O2 C37 H37A 109.5 . . ?
O2 C37 H37B 109.5 . . ?
H37A C37 H37B 109.5 . . ?
O2 C37 H37C 109.5 . . ?
H37A C37 H37C 109.5 . . ?
H37B C37 H37C 109.5 . . ?
C46 C41 C42 118.05(18) . . ?
C46 C41 C4 123.79(18) . . ?
C42 C41 C4 118.11(16) . . ?
C43 C42 C41 121.16(18) . . ?
C43 C42 H42 119.4 . . ?
C41 C42 H42 119.4 . . ?
C42 C43 C44 120.2(2) . . ?
C42 C43 H43 119.9 . . ?
C44 C43 H43 119.9 . . ?
O5 C44 C45 125.28(18) . . ?
O5 C44 C43 115.05(19) . . ?
C45 C44 C43 119.66(18) . . ?
C44 C45 C46 119.72(18) . . ?
C44 C45 H45 120.1 . . ?
C46 C45 H45 120.1 . . ?
C45 C46 C41 121.22(19) . . ?
C45 C46 H46 119.4 . . ?
C41 C46 H46 119.4 . . ?
O5 C47 H47A 109.5 . . ?
O5 C47 H47B 109.5 . . ?
H47A C47 H47B 109.5 . . ?
O5 C47 H47C 109.5 . . ?
H47A C47 H47C 109.5 . . ?
H47B C47 H47C 109.5 . . ?
C72 C71 C76 117.8(2) . . ?
C72 C71 C7 118.88(18) . . ?
C76 C71 C7 123.22(19) . . ?
C73 C72 C71 120.9(2) . . ?
C73 C72 H72 119.6 . . ?
C71 C72 H72 119.6 . . ?
C72 C73 C74 121.8(2) . . ?
C72 C73 H73 119.1 . . ?
C74 C73 H73 119.1 . . ?
C75 C74 C73 117.1(2) . . ?
C75 C74 C77 121.9(2) . . ?
C73 C74 C77 121.0(2) . . ?
C76 C75 C74 121.4(2) . . ?
C76 C75 H75 119.3 . . ?
C74 C75 H75 119.3 . . ?
C75 C76 C71 120.8(2) . . ?
C75 C76 H76 119.6 . . ?
C71 C76 H76 119.6 . . ?
C78A C77 C79 132.7(5) . . ?
C78A C77 C74 112.6(4) . . ?
C79 C77 C74 114.6(3) . . ?
C78A C77 C80A 109.4(5) . . ?
C79 C77 C80A 47.8(4) . . ?
C74 C77 C80A 112.8(3) . . ?
C78A C77 C79A 114.4(6) . . ?
C79 C77 C79A 53.1(4) . . ?
C74 C77 C79A 107.0(4) . . ?
C80A C77 C79A 100.1(5) . . ?
C78A C77 C78 48.2(5) . . ?
C79 C77 C78 113.4(4) . . ?
C74 C77 C78 111.8(3) . . ?
C80A C77 C78 135.3(4) . . ?
C79A C77 C78 69.5(5) . . ?
C78A C77 C80 52.8(5) . . ?
C79 C77 C80 109.5(4) . . ?
C74 C77 C80 106.2(3) . . ?
C80A C77 C80 64.4(4) . . ?
C79A C77 C80 146.8(4) . . ?
C78 C77 C80 100.1(4) . . ?
C77 C78 H78A 109.5 . . ?
C77 C78 H78B 109.5 . . ?
H78A C78 H78B 109.5 . . ?
C77 C78 H78C 109.5 . . ?
H78A C78 H78C 109.5 . . ?
H78B C78 H78C 109.5 . . ?
C77 C79 H79A 109.5 . . ?
C77 C79 H79B 109.5 . . ?
H79A C79 H79B 109.5 . . ?
C77 C79 H79C 109.5 . . ?
H79A C79 H79C 109.5 . . ?
H79B C79 H79C 109.5 . . ?
C77 C80 H80A 109.5 . . ?
C77 C80 H80B 109.5 . . ?
H80A C80 H80B 109.5 . . ?
C77 C80 H80C 109.5 . . ?
H80A C80 H80C 109.5 . . ?
H80B C80 H80C 109.5 . . ?
C77 C78A H78D 109.5 . . ?
C77 C78A H78E 109.5 . . ?
H78D C78A H78E 109.5 . . ?
C77 C78A H78F 109.5 . . ?
H78D C78A H78F 109.5 . . ?
H78E C78A H78F 109.5 . . ?
C77 C79A H79D 109.5 . . ?
C77 C79A H79E 109.5 . . ?
H79D C79A H79E 109.5 . . ?
C77 C79A H79F 109.5 . . ?
H79D C79A H79F 109.5 . . ?
H79E C79A H79F 109.5 . . ?
C77 C80A H80D 109.5 . . ?
C77 C80A H80E 109.5 . . ?
H80D C80A H80E 109.5 . . ?
C77 C80A H80F 109.5 . . ?
H80D C80A H80F 109.5 . . ?
H80E C80A H80F 109.5 . . ?
C66 C61 C62 117.54(19) . . ?
C66 C61 C6 118.41(17) . . ?
C62 C61 C6 124.05(18) . . ?
C63 C62 C61 120.6(2) . . ?
C63 C62 H62 119.7 . . ?
C61 C62 H62 119.7 . . ?
C62 C63 C64 122.24(19) . . ?
C62 C63 H63 118.9 . . ?
C64 C63 H63 118.9 . . ?
C65 C64 C63 116.6(2) . . ?
C65 C64 C67 122.2(2) . . ?
C63 C64 C67 121.2(2) . . ?
C66 C65 C64 121.7(2) . . ?
C66 C65 H65 119.2 . . ?
C64 C65 H65 119.2 . . ?
C65 C66 C61 121.3(2) . . ?
C65 C66 H66 119.4 . . ?
C61 C66 H66 119.4 . . ?
C68A C67 C69 124.5(12) . . ?
C68A C67 C64 123.4(12) . . ?
C69 C67 C64 110.9(2) . . ?
C68A C67 C70A 115.7(12) . . ?
C69 C67 C70A 55.0(8) . . ?
C64 C67 C70A 104.4(10) . . ?
C68A C67 C68 43.0(11) . . ?
C69 C67 C68 111.2(2) . . ?
C64 C67 C68 108.4(2) . . ?
C70A C67 C68 147.2(10) . . ?
C68A C67 C70 62.8(11) . . ?
C69 C67 C70 108.2(2) . . ?
C64 C67 C70 112.3(2) . . ?
C70A C67 C70 60.4(9) . . ?
C68 C67 C70 105.9(2) . . ?
C68A C67 C69A 107.6(11) . . ?
C69 C67 C69A 43.3(9) . . ?
C64 C67 C69A 104.1(11) . . ?
C70A C67 C69A 98.3(10) . . ?
C68 C67 C69A 73.8(9) . . ?
C70 C67 C69A 141.1(10) . . ?
C67 C68 H68A 109.5 . . ?
C67 C68 H68B 109.5 . . ?
H68A C68 H68B 109.5 . . ?
C67 C68 H68C 109.5 . . ?
H68A C68 H68C 109.5 . . ?
H68B C68 H68C 109.5 . . ?
C67 C69 H69A 109.5 . . ?
C67 C69 H69B 109.5 . . ?
H69A C69 H69B 109.5 . . ?
C67 C69 H69C 109.5 . . ?
H69A C69 H69C 109.5 . . ?
H69B C69 H69C 109.5 . . ?
C67 C70 H70A 109.5 . . ?
C67 C70 H70B 109.5 . . ?
H70A C70 H70B 109.5 . . ?
C67 C70 H70C 109.5 . . ?
H70A C70 H70C 109.5 . . ?
H70B C70 H70C 109.5 . . ?
C67 C68A H68D 109.5 . . ?
C67 C68A H68E 109.5 . . ?
H68D C68A H68E 109.5 . . ?
C67 C68A H68F 109.5 . . ?
H68D C68A H68F 109.5 . . ?
H68E C68A H68F 109.5 . . ?
C67 C69A H69D 109.5 . . ?
C67 C69A H69E 109.5 . . ?
H69D C69A H69E 109.5 . . ?
C67 C69A H69F 109.5 . . ?
H69D C69A H69F 109.5 . . ?
H69E C69A H69F 109.5 . . ?
C67 C70A H70D 109.5 . . ?
C67 C70A H70E 109.5 . . ?
H70D C70A H70E 109.5 . . ?
C67 C70A H70F 109.5 . . ?
H70D C70A H70F 109.5 . . ?
H70E C70A H70F 109.5 . . ?
C92 C91 C96 117.6(2) . . ?
C92 C91 C9 122.4(2) . . ?
C96 C91 C9 120.00(19) . . ?
C93 C92 C91 121.8(2) . . ?
C93 C92 H92 119.1 . . ?
C91 C92 H92 119.1 . . ?
C94 C93 C92 119.8(2) . . ?
C94 C93 H93 120.1 . . ?
C92 C93 H93 120.1 . . ?
O8 C94 C93 124.6(2) . . ?
O8 C94 C95 116.0(2) . . ?
C93 C94 C95 119.4(2) . . ?
C96 C95 C94 120.2(2) . . ?
C96 C95 H95 119.9 . . ?
C94 C95 H95 119.9 . . ?
C95 C96 C91 121.2(2) . . ?
C95 C96 H96 119.4 . . ?
C91 C96 H96 119.4 . . ?
O8 C97 H97A 109.5 . . ?
O8 C97 H97B 109.5 . . ?
H97A C97 H97B 109.5 . . ?
O8 C97 H97C 109.5 . . ?
H97A C97 H97C 109.5 . . ?
H97B C97 H97C 109.5 . . ?
O10 P1 C121 108.81(12) . . ?
O10 P1 C131 113.05(11) . . ?
C121 P1 C131 104.90(12) . . ?
O10 P1 C111 111.33(10) . . ?
C121 P1 C111 113.54(12) . . ?
C131 P1 C111 105.09(11) . . ?
C112 C111 C116 120.0 . . ?
C112 C111 P1 124.52(11) . . ?
C116 C111 P1 114.99(11) . . ?
C111 C112 C113 120.0 . . ?
C111 C112 H112 120.0 . . ?
C113 C112 H112 120.0 . . ?
C114 C113 C112 120.0 . . ?
C114 C113 H113 120.0 . . ?
C112 C113 H113 120.0 . . ?
C113 C114 C115 120.0 . . ?
C113 C114 H114 120.0 . . ?
C115 C114 H114 120.0 . . ?
C116 C115 C114 120.0 . . ?
C116 C115 H115 120.0 . . ?
C114 C115 H115 120.0 . . ?
C115 C116 C111 120.0 . . ?
C115 C116 H116 120.0 . . ?
C111 C116 H116 120.0 . . ?
C122 C121 C126 120.0 . . ?
C122 C121 P1 117.83(14) . . ?
C126 C121 P1 122.17(14) . . ?
C123 C122 C121 120.0 . . ?
C123 C122 H122 120.0 . . ?
C121 C122 H122 120.0 . . ?
C122 C123 C124 120.0 . . ?
C122 C123 H123 120.0 . . ?
C124 C123 H123 120.0 . . ?
C123 C124 C125 120.0 . . ?
C123 C124 H124 120.0 . . ?
C125 C124 H124 120.0 . . ?
C124 C125 C126 120.0 . . ?
C124 C125 H125 120.0 . . ?
C126 C125 H125 120.0 . . ?
C125 C126 C121 120.0 . . ?
C125 C126 H126 120.0 . . ?
C121 C126 H126 120.0 . . ?
C132 C131 C136 120.0 . . ?
C132 C131 P1 123.03(11) . . ?
C136 C131 P1 116.84(11) . . ?
C131 C132 C133 120.0 . . ?
C131 C132 H132 120.0 . . ?
C133 C132 H132 120.0 . . ?
C132 C133 C134 120.0 . . ?
C132 C133 H133 120.0 . . ?
C134 C133 H133 120.0 . . ?
C135 C134 C133 120.0 . . ?
C135 C134 H134 120.0 . . ?
C133 C134 H134 120.0 . . ?
C136 C135 C134 120.0 . . ?
C136 C135 H135 120.0 . . ?
C134 C135 H135 120.0 . . ?
C135 C136 C131 120.0 . . ?
C135 C136 H136 120.0 . . ?
C131 C136 H136 120.0 . . ?
O10 P2 C221 115.3(10) . . ?
O10 P2 C231 117.0(9) . . ?
C221 P2 C231 108.8(11) . . ?
O10 P2 C211 97.7(7) . . ?
C221 P2 C211 107.6(11) . . ?
C231 P2 C211 109.4(10) . . ?
C212 C211 C216 120.0 . . ?
C212 C211 P2 123.1(10) . . ?
C216 C211 P2 116.5(10) . . ?
C211 C212 C213 120.0 . . ?
C211 C212 H212 120.0 . . ?
C213 C212 H212 120.0 . . ?
C212 C213 C214 120.0 . . ?
C212 C213 H213 120.0 . . ?
C214 C213 H213 120.0 . . ?
C215 C214 C213 120.0 . . ?
C215 C214 H214 120.0 . . ?
C213 C214 H214 120.0 . . ?
C214 C215 C216 120.0 . . ?
C214 C215 H215 120.0 . . ?
C216 C215 H215 120.0 . . ?
C215 C216 C211 120.0 . . ?
C215 C216 H216 120.0 . . ?
C211 C216 H216 120.0 . . ?
C222 C221 C226 120.0 . . ?
C222 C221 P2 117.3(15) . . ?
C226 C221 P2 122.6(14) . . ?
C223 C222 C221 120.0 . . ?
C223 C222 H222 120.0 . . ?
C221 C222 H222 120.0 . . ?
C222 C223 C224 120.0 . . ?
C222 C223 H223 120.0 . . ?
C224 C223 H223 120.0 . . ?
C225 C224 C223 120.0 . . ?
C225 C224 H224 120.0 . . ?
C223 C224 H224 120.0 . . ?
C224 C225 C226 120.0 . . ?
C224 C225 H225 120.0 . . ?
C226 C225 H225 120.0 . . ?
C225 C226 C221 120.0 . . ?
C225 C226 H226 120.0 . . ?
C221 C226 H226 120.0 . . ?
C232 C231 C236 120.0 . . ?
C232 C231 P2 121.7(10) . . ?
C236 C231 P2 118.0(11) . . ?
C233 C232 C231 120.0 . . ?
C233 C232 H232 120.0 . . ?
C231 C232 H232 120.0 . . ?
C232 C233 C234 120.0 . . ?
C232 C233 H233 120.0 . . ?
C234 C233 H233 120.0 . . ?
C235 C234 C233 120.0 . . ?
C235 C234 H234 120.0 . . ?
C233 C234 H234 120.0 . . ?
C234 C235 C236 120.0 . . ?
C234 C235 H235 120.0 . . ?
C236 C235 H235 120.0 . . ?
C235 C236 C231 120.0 . . ?
C235 C236 H236 120.0 . . ?
C231 C236 H236 120.0 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Eu1 O7 2.3027(15) . y
Eu1 O6 2.3113(14) . y
Eu1 O4 2.3166(13) . y
Eu1 O10 2.3321(16) . y
Eu1 O3 2.3447(15) . y
Eu1 O9 2.3706(14) . y
Eu1 O1 2.4013(12) . y
O1 C1 1.272(2) . ?
O2 C34 1.360(2) . ?
O2 C37 1.433(2) . ?
O3 C3 1.266(2) . ?
O4 C4 1.272(2) . ?
O5 C44 1.363(2) . ?
O5 C47 1.435(3) . ?
O6 C6 1.266(2) . ?
O7 C7 1.273(3) . ?
O8 C94 1.382(3) . ?
O8 C97 1.439(4) . ?
O9 C9 1.271(2) . ?
O10 P1 1.4990(18) . ?
O10 P2 1.537(8) . ?
C1 C2 1.399(3) . ?
C1 C11 1.503(2) . ?
C2 C3 1.407(2) . ?
C2 H2 0.9300 . ?
C3 C31 1.490(3) . ?
C4 C5 1.401(3) . ?
C4 C41 1.496(3) . ?
C5 C6 1.403(3) . ?
C5 H5 0.9300 . ?
C6 C61 1.495(3) . ?
C7 C8 1.396(3) . ?
C7 C71 1.495(3) . ?
C8 C9 1.405(3) . ?
C8 H8 0.9300 . ?
C9 C91 1.494(3) . ?
C11 C12 1.386(3) . ?
C11 C16 1.398(3) . ?
C12 C13 1.393(2) . ?
C12 H12 0.9300 . ?
C13 C14 1.384(3) . ?
C13 H13 0.9300 . ?
C14 C15 1.404(3) . ?
C14 C17 1.536(2) . ?
C15 C16 1.390(2) . ?
C15 H15 0.9300 . ?
C16 H16 0.9300 . ?
C17 C19 1.519(4) . ?
C17 C20 1.525(4) . ?
C17 C18 1.549(4) . ?
C18 H18A 0.9600 . ?
C18 H18B 0.9600 . ?
C18 H18C 0.9600 . ?
C19 H19A 0.9600 . ?
C19 H19B 0.9600 . ?
C19 H19C 0.9600 . ?
C20 H20A 0.9600 . ?
C20 H20B 0.9600 . ?
C20 H20C 0.9600 . ?
C31 C36 1.394(2) . ?
C31 C32 1.394(3) . ?
C32 C33 1.379(3) . ?
C32 H32 0.9300 . ?
C33 C34 1.396(2) . ?
C33 H33 0.9300 . ?
C34 C35 1.384(3) . ?
C35 C36 1.383(3) . ?
C35 H35 0.9300 . ?
C36 H36 0.9300 . ?
C37 H37A 0.9600 . ?
C37 H37B 0.9600 . ?
C37 H37C 0.9600 . ?
C41 C46 1.397(2) . ?
C41 C42 1.401(3) . ?
C42 C43 1.374(3) . ?
C42 H42 0.9300 . ?
C43 C44 1.399(3) . ?
C43 H43 0.9300 . ?
C44 C45 1.388(3) . ?
C45 C46 1.389(3) . ?
C45 H45 0.9300 . ?
C46 H46 0.9300 . ?
C47 H47A 0.9600 . ?
C47 H47B 0.9600 . ?
C47 H47C 0.9600 . ?
C71 C72 1.393(3) . ?
C71 C76 1.392(3) . ?
C72 C73 1.371(3) . ?
C72 H72 0.9300 . ?
C73 C74 1.394(3) . ?
C73 H73 0.9300 . ?
C74 C75 1.390(3) . ?
C74 C77 1.512(3) . ?
C75 C76 1.384(3) . ?
C75 H75 0.9300 . ?
C76 H76 0.9300 . ?
C77 C78A 1.434(6) . ?
C77 C79 1.433(5) . ?
C77 C80A 1.568(6) . ?
C77 C79A 1.570(7) . ?
C77 C78 1.580(5) . ?
C77 C80 1.597(5) . ?
C78 H78A 0.9600 . ?
C78 H78B 0.9600 . ?
C78 H78C 0.9600 . ?
C79 H79A 0.9600 . ?
C79 H79B 0.9600 . ?
C79 H79C 0.9600 . ?
C80 H80A 0.9600 . ?
C80 H80B 0.9600 . ?
C80 H80C 0.9600 . ?
C78A H78D 0.9600 . ?
C78A H78E 0.9600 . ?
C78A H78F 0.9600 . ?
C79A H79D 0.9600 . ?
C79A H79E 0.9600 . ?
C79A H79F 0.9600 . ?
C80A H80D 0.9600 . ?
C80A H80E 0.9600 . ?
C80A H80F 0.9600 . ?
C61 C66 1.388(3) . ?
C61 C62 1.394(3) . ?
C62 C63 1.380(3) . ?
C62 H62 0.9300 . ?
C63 C64 1.394(3) . ?
C63 H63 0.9300 . ?
C64 C65 1.387(3) . ?
C64 C67 1.532(3) . ?
C65 C66 1.385(3) . ?
C65 H65 0.9300 . ?
C66 H66 0.9300 . ?
C67 C68A 1.471(9) . ?
C67 C69 1.505(3) . ?
C67 C70A 1.539(9) . ?
C67 C68 1.541(4) . ?
C67 C70 1.550(4) . ?
C67 C69A 1.588(9) . ?
C68 H68A 0.9600 . ?
C68 H68B 0.9600 . ?
C68 H68C 0.9600 . ?
C69 H69A 0.9600 . ?
C69 H69B 0.9600 . ?
C69 H69C 0.9600 . ?
C70 H70A 0.9600 . ?
C70 H70B 0.9600 . ?
C70 H70C 0.9600 . ?
C68A H68D 0.9600 . ?
C68A H68E 0.9600 . ?
C68A H68F 0.9600 . ?
C69A H69D 0.9600 . ?
C69A H69E 0.9600 . ?
C69A H69F 0.9600 . ?
C70A H70D 0.9600 . ?
C70A H70E 0.9600 . ?
C70A H70F 0.9600 . ?
C91 C92 1.392(3) . ?
C91 C96 1.395(3) . ?
C92 C93 1.388(3) . ?
C92 H92 0.9300 . ?
C93 C94 1.385(4) . ?
C93 H93 0.9300 . ?
C94 C95 1.392(4) . ?
C95 C96 1.384(4) . ?
C95 H95 0.9300 . ?
C96 H96 0.9300 . ?
C97 H97A 0.9600 . ?
C97 H97B 0.9600 . ?
C97 H97C 0.9600 . ?
P1 C121 1.793(2) . ?
P1 C131 1.8068(17) . ?
P1 C111 1.8021(17) . ?
C111 C112 1.3900 . ?
C111 C116 1.3900 . ?
C112 C113 1.3900 . ?
C112 H112 0.9300 . ?
C113 C114 1.3900 . ?
C113 H113 0.9300 . ?
C114 C115 1.3900 . ?
C114 H114 0.9300 . ?
C115 C116 1.3900 . ?
C115 H115 0.9300 . ?
C116 H116 0.9300 . ?
C121 C122 1.3900 . ?
C121 C126 1.3900 . ?
C122 C123 1.3900 . ?
C122 H122 0.9300 . ?
C123 C124 1.3900 . ?
C123 H123 0.9300 . ?
C124 C125 1.3900 . ?
C124 H124 0.9300 . ?
C125 C126 1.3900 . ?
C125 H125 0.9300 . ?
C126 H126 0.9300 . ?
C131 C132 1.3900 . ?
C131 C136 1.3900 . ?
C132 C133 1.3900 . ?
C132 H132 0.9300 . ?
C133 C134 1.3900 . ?
C133 H133 0.9300 . ?
C134 C135 1.3900 . ?
C134 H134 0.9300 . ?
C135 C136 1.3900 . ?
C135 H135 0.9300 . ?
C136 H136 0.9300 . ?
P2 C221 1.80(2) . ?
P2 C231 1.724(16) . ?
P2 C211 1.863(14) . ?
C211 C212 1.3900 . ?
C211 C216 1.3900 . ?
C212 C213 1.3900 . ?
C212 H212 0.9300 . ?
C213 C214 1.3900 . ?
C213 H213 0.9300 . ?
C214 C215 1.3900 . ?
C214 H214 0.9300 . ?
C215 C216 1.3900 . ?
C215 H215 0.9300 . ?
C216 H216 0.9300 . ?
C221 C222 1.3900 . ?
C221 C226 1.3900 . ?
C222 C223 1.3900 . ?
C222 H222 0.9300 . ?
C223 C224 1.3900 . ?
C223 H223 0.9300 . ?
C224 C225 1.3900 . ?
C224 H224 0.9300 . ?
C225 C226 1.3900 . ?
C225 H225 0.9300 . ?
C226 H226 0.9300 . ?
C231 C232 1.3900 . ?
C231 C236 1.3900 . ?
C232 C233 1.3900 . ?
C232 H232 0.9300 . ?
C233 C234 1.3900 . ?
C233 H233 0.9300 . ?
C234 C235 1.3900 . ?
C234 H234 0.9300 . ?
C235 C236 1.3900 . ?
C235 H235 0.9300 . ?
C236 H236 0.9300 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
O7 Eu1 O1 C1 128.38(18) . . . . ?
O6 Eu1 O1 C1 -134.9(2) . . . . ?
O4 Eu1 O1 C1 53.4(2) . . . . ?
O10 Eu1 O1 C1 -73.80(18) . . . . ?
O3 Eu1 O1 C1 6.37(18) . . . . ?
O9 Eu1 O1 C1 -158.41(18) . . . . ?
O7 Eu1 O3 C3 -76.3(2) . . . . ?
O6 Eu1 O3 C3 165.1(2) . . . . ?
O4 Eu1 O3 C3 -142.7(2) . . . . ?
O10 Eu1 O3 C3 95.5(2) . . . . ?
O9 Eu1 O3 C3 35.3(3) . . . . ?
O1 Eu1 O3 C3 1.7(2) . . . . ?
O7 Eu1 O4 C4 85.2(2) . . . . ?
O6 Eu1 O4 C4 -11.9(2) . . . . ?
O10 Eu1 O4 C4 -78.4(2) . . . . ?
O3 Eu1 O4 C4 -148.8(2) . . . . ?
O9 Eu1 O4 C4 32.5(2) . . . . ?
O1 Eu1 O4 C4 164.89(18) . . . . ?
O7 Eu1 O6 C6 -61.2(2) . . . . ?
O4 Eu1 O6 C6 16.1(2) . . . . ?
O10 Eu1 O6 C6 139.7(2) . . . . ?
O3 Eu1 O6 C6 69.1(2) . . . . ?
O9 Eu1 O6 C6 -132.9(2) . . . . ?
O1 Eu1 O6 C6 -157.26(18) . . . . ?
O6 Eu1 O7 C7 -51.63(18) . . . . ?
O4 Eu1 O7 C7 -121.99(18) . . . . ?
O10 Eu1 O7 C7 16.3(3) . . . . ?
O3 Eu1 O7 C7 174.44(16) . . . . ?
O9 Eu1 O7 C7 21.73(17) . . . . ?
O1 Eu1 O7 C7 106.58(18) . . . . ?
O7 Eu1 O9 C9 -23.42(16) . . . . ?
O6 Eu1 O9 C9 74.53(17) . . . . ?
O4 Eu1 O9 C9 31.27(19) . . . . ?
O10 Eu1 O9 C9 154.53(17) . . . . ?
O3 Eu1 O9 C9 -146.11(16) . . . . ?
O1 Eu1 O9 C9 -114.35(17) . . . . ?
O7 Eu1 O10 P1 -27.1(7) . . . . ?
O6 Eu1 O10 P1 43.4(6) . . . . ?
O4 Eu1 O10 P1 105.8(6) . . . . ?
O3 Eu1 O10 P1 172.0(6) . . . . ?
O9 Eu1 O10 P1 -32.3(6) . . . . ?
O1 Eu1 O10 P1 -117.1(6) . . . . ?
O7 Eu1 O10 P2 -117.7(14) . . . . ?
O6 Eu1 O10 P2 -47.2(14) . . . . ?
O4 Eu1 O10 P2 15.2(14) . . . . ?
O3 Eu1 O10 P2 81.4(14) . . . . ?
O9 Eu1 O10 P2 -122.9(14) . . . . ?
O1 Eu1 O10 P2 152.3(14) . . . . ?
Eu1 O1 C1 C2 -8.6(3) . . . . ?
Eu1 O1 C1 C11 172.81(12) . . . . ?
O1 C1 C2 C3 1.2(3) . . . . ?
C11 C1 C2 C3 179.77(19) . . . . ?
Eu1 O3 C3 C2 -7.2(4) . . . . ?
Eu1 O3 C3 C31 172.36(15) . . . . ?
C1 C2 C3 O3 6.3(3) . . . . ?
C1 C2 C3 C31 -173.3(2) . . . . ?
Eu1 O4 C4 C5 5.0(3) . . . . ?
Eu1 O4 C4 C41 -177.55(13) . . . . ?
O4 C4 C5 C6 6.7(3) . . . . ?
C41 C4 C5 C6 -170.64(19) . . . . ?
Eu1 O6 C6 C5 -13.1(3) . . . . ?
Eu1 O6 C6 C61 168.67(15) . . . . ?
C4 C5 C6 O6 -3.0(3) . . . . ?
C4 C5 C6 C61 175.14(18) . . . . ?
Eu1 O7 C7 C8 -16.0(3) . . . . ?
Eu1 O7 C7 C71 162.83(13) . . . . ?
O7 C7 C8 C9 -1.4(3) . . . . ?
C71 C7 C8 C9 179.87(17) . . . . ?
Eu1 O9 C9 C8 20.1(3) . . . . ?
Eu1 O9 C9 C91 -159.07(12) . . . . ?
C7 C8 C9 O9 -1.4(3) . . . . ?
C7 C8 C9 C91 177.82(17) . . . . ?
O1 C1 C11 C12 33.4(3) . . . . ?
C2 C1 C11 C12 -145.3(2) . . . . ?
O1 C1 C11 C16 -146.1(2) . . . . ?
C2 C1 C11 C16 35.1(3) . . . . ?
C16 C11 C12 C13 -0.3(3) . . . . ?
C1 C11 C12 C13 -179.8(2) . . . . ?
C11 C12 C13 C14 1.6(4) . . . . ?
C12 C13 C14 C15 -1.3(4) . . . . ?
C12 C13 C14 C17 179.2(2) . . . . ?
C13 C14 C15 C16 -0.1(3) . . . . ?
C17 C14 C15 C16 179.4(2) . . . . ?
C14 C15 C16 C11 1.4(4) . . . . ?
C12 C11 C16 C15 -1.1(3) . . . . ?
C1 C11 C16 C15 178.4(2) . . . . ?
C13 C14 C17 C19 -123.0(3) . . . . ?
C15 C14 C17 C19 57.5(3) . . . . ?
C13 C14 C17 C20 117.1(3) . . . . ?
C15 C14 C17 C20 -62.4(3) . . . . ?
C13 C14 C17 C18 -1.9(3) . . . . ?
C15 C14 C17 C18 178.6(2) . . . . ?
O3 C3 C31 C36 1.9(3) . . . . ?
C2 C3 C31 C36 -178.5(2) . . . . ?
O3 C3 C31 C32 -175.0(2) . . . . ?
C2 C3 C31 C32 4.6(3) . . . . ?
C36 C31 C32 C33 0.2(3) . . . . ?
C3 C31 C32 C33 177.1(2) . . . . ?
C31 C32 C33 C34 1.0(3) . . . . ?
C37 O2 C34 C35 -0.5(3) . . . . ?
C37 O2 C34 C33 179.4(2) . . . . ?
C32 C33 C34 O2 179.2(2) . . . . ?
C32 C33 C34 C35 -0.9(3) . . . . ?
O2 C34 C35 C36 179.4(2) . . . . ?
C33 C34 C35 C36 -0.5(4) . . . . ?
C34 C35 C36 C31 1.8(4) . . . . ?
C32 C31 C36 C35 -1.6(4) . . . . ?
C3 C31 C36 C35 -178.7(2) . . . . ?
O4 C4 C41 C46 -174.34(19) . . . . ?
C5 C4 C41 C46 3.2(3) . . . . ?
O4 C4 C41 C42 2.8(3) . . . . ?
C5 C4 C41 C42 -179.61(19) . . . . ?
C46 C41 C42 C43 0.8(3) . . . . ?
C4 C41 C42 C43 -176.59(19) . . . . ?
C41 C42 C43 C44 -0.3(3) . . . . ?
C47 O5 C44 C45 -7.6(3) . . . . ?
C47 O5 C44 C43 173.2(2) . . . . ?
C42 C43 C44 O5 178.47(19) . . . . ?
C42 C43 C44 C45 -0.7(3) . . . . ?
O5 C44 C45 C46 -177.9(2) . . . . ?
C43 C44 C45 C46 1.2(3) . . . . ?
C44 C45 C46 C41 -0.7(3) . . . . ?
C42 C41 C46 C45 -0.3(3) . . . . ?
C4 C41 C46 C45 176.93(19) . . . . ?
O7 C7 C71 C72 -33.5(3) . . . . ?
C8 C7 C71 C72 145.4(2) . . . . ?
O7 C7 C71 C76 143.3(2) . . . . ?
C8 C7 C71 C76 -37.8(3) . . . . ?
C76 C71 C72 C73 -2.0(3) . . . . ?
C7 C71 C72 C73 175.1(2) . . . . ?
C71 C72 C73 C74 -2.5(4) . . . . ?
C72 C73 C74 C75 4.5(4) . . . . ?
C72 C73 C74 C77 -173.5(2) . . . . ?
C73 C74 C75 C76 -2.2(4) . . . . ?
C77 C74 C75 C76 175.8(3) . . . . ?
C74 C75 C76 C71 -2.1(4) . . . . ?
C72 C71 C76 C75 4.2(4) . . . . ?
C7 C71 C76 C75 -172.7(2) . . . . ?
C75 C74 C77 C78A -114.2(6) . . . . ?
C73 C74 C77 C78A 63.7(6) . . . . ?
C75 C74 C77 C79 62.6(4) . . . . ?
C73 C74 C77 C79 -119.5(4) . . . . ?
C75 C74 C77 C80A 10.1(5) . . . . ?
C73 C74 C77 C80A -172.0(4) . . . . ?
C75 C74 C77 C79A 119.2(5) . . . . ?
C73 C74 C77 C79A -62.9(5) . . . . ?
C75 C74 C77 C78 -166.6(4) . . . . ?
C73 C74 C77 C78 11.3(5) . . . . ?
C75 C74 C77 C80 -58.4(4) . . . . ?
C73 C74 C77 C80 119.5(3) . . . . ?
O6 C6 C61 C66 -3.3(3) . . . . ?
C5 C6 C61 C66 178.4(2) . . . . ?
O6 C6 C61 C62 177.3(2) . . . . ?
C5 C6 C61 C62 -1.0(3) . . . . ?
C66 C61 C62 C63 2.2(3) . . . . ?
C6 C61 C62 C63 -178.3(2) . . . . ?
C61 C62 C63 C64 -1.6(4) . . . . ?
C62 C63 C64 C65 -0.3(4) . . . . ?
C62 C63 C64 C67 -178.3(2) . . . . ?
C63 C64 C65 C66 1.5(4) . . . . ?
C67 C64 C65 C66 179.6(2) . . . . ?
C64 C65 C66 C61 -0.9(4) . . . . ?
C62 C61 C66 C65 -1.0(4) . . . . ?
C6 C61 C66 C65 179.6(2) . . . . ?
C65 C64 C67 C68A -65.3(13) . . . . ?
C63 C64 C67 C68A 112.7(13) . . . . ?
C65 C64 C67 C69 127.1(3) . . . . ?
C63 C64 C67 C69 -54.9(3) . . . . ?
C65 C64 C67 C70A 69.5(9) . . . . ?
C63 C64 C67 C70A -112.5(9) . . . . ?
C65 C64 C67 C68 -110.6(3) . . . . ?
C63 C64 C67 C68 67.4(3) . . . . ?
C65 C64 C67 C70 6.0(3) . . . . ?
C63 C64 C67 C70 -176.1(2) . . . . ?
C65 C64 C67 C69A 172.1(10) . . . . ?
C63 C64 C67 C69A -10.0(10) . . . . ?
O9 C9 C91 C92 -154.11(19) . . . . ?
C8 C9 C91 C92 26.6(3) . . . . ?
O9 C9 C91 C96 26.5(3) . . . . ?
C8 C9 C91 C96 -152.8(2) . . . . ?
C96 C91 C92 C93 0.1(3) . . . . ?
C9 C91 C92 C93 -179.3(2) . . . . ?
C91 C92 C93 C94 0.1(4) . . . . ?
C97 O8 C94 C93 -2.8(5) . . . . ?
C97 O8 C94 C95 176.5(3) . . . . ?
C92 C93 C94 O8 179.6(3) . . . . ?
C92 C93 C94 C95 0.3(4) . . . . ?
O8 C94 C95 C96 179.7(3) . . . . ?
C93 C94 C95 C96 -0.9(4) . . . . ?
C94 C95 C96 C91 1.2(4) . . . . ?
C92 C91 C96 C95 -0.8(4) . . . . ?
C9 C91 C96 C95 178.7(2) . . . . ?
P2 O10 P1 C121 -34.9(10) . . . . ?
Eu1 O10 P1 C121 -157.4(6) . . . . ?
P2 O10 P1 C131 81.2(10) . . . . ?
Eu1 O10 P1 C131 -41.3(6) . . . . ?
P2 O10 P1 C111 -160.8(10) . . . . ?
Eu1 O10 P1 C111 76.7(6) . . . . ?
O10 P1 C111 C112 149.19(14) . . . . ?
C121 P1 C111 C112 26.0(2) . . . . ?
C131 P1 C111 C112 -88.08(17) . . . . ?
O10 P1 C111 C116 -38.89(15) . . . . ?
C121 P1 C111 C116 -162.10(14) . . . . ?
C131 P1 C111 C116 83.83(14) . . . . ?
C116 C111 C112 C113 0.0 . . . . ?
P1 C111 C112 C113 171.53(19) . . . . ?
C111 C112 C113 C114 0.0 . . . . ?
C112 C113 C114 C115 0.0 . . . . ?
C113 C114 C115 C116 0.0 . . . . ?
C114 C115 C116 C111 0.0 . . . . ?
C112 C111 C116 C115 0.0 . . . . ?
P1 C111 C116 C115 -172.31(17) . . . . ?
O10 P1 C121 C122 0.76(18) . . . . ?
C131 P1 C121 C122 -120.47(15) . . . . ?
C111 P1 C121 C122 125.34(16) . . . . ?
O10 P1 C121 C126 -178.73(16) . . . . ?
C131 P1 C121 C126 60.03(19) . . . . ?
C111 P1 C121 C126 -54.1(2) . . . . ?
C126 C121 C122 C123 0.0 . . . . ?
P1 C121 C122 C123 -179.5(2) . . . . ?
C121 C122 C123 C124 0.0 . . . . ?
C122 C123 C124 C125 0.0 . . . . ?
C123 C124 C125 C126 0.0 . . . . ?
C124 C125 C126 C121 0.0 . . . . ?
C122 C121 C126 C125 0.0 . . . . ?
P1 C121 C126 C125 179.5(2) . . . . ?
O10 P1 C131 C132 108.46(17) . . . . ?
C121 P1 C131 C132 -133.13(16) . . . . ?
C111 P1 C131 C132 -13.15(18) . . . . ?
O10 P1 C131 C136 -67.29(17) . . . . ?
C121 P1 C131 C136 51.12(17) . . . . ?
C111 P1 C131 C136 171.10(13) . . . . ?
C136 C131 C132 C133 0.0 . . . . ?
P1 C131 C132 C133 -175.62(19) . . . . ?
C131 C132 C133 C134 0.0 . . . . ?
C132 C133 C134 C135 0.0 . . . . ?
C133 C134 C135 C136 0.0 . . . . ?
C134 C135 C136 C131 0.0 . . . . ?
C132 C131 C136 C135 0.0 . . . . ?
P1 C131 C136 C135 175.88(18) . . . . ?
P1 O10 P2 C221 135.3(15) . . . . ?
Eu1 O10 P2 C221 -78.0(17) . . . . ?
P1 O10 P2 C231 -94.8(14) . . . . ?
Eu1 O10 P2 C231 51.9(18) . . . . ?
P1 O10 P2 C211 21.7(10) . . . . ?
Eu1 O10 P2 C211 168.3(13) . . . . ?
O10 P2 C211 C212 150.9(12) . . . . ?
C221 P2 C211 C212 31.2(17) . . . . ?
C231 P2 C211 C212 -86.9(15) . . . . ?
O10 P2 C211 C216 -36.4(11) . . . . ?
C221 P2 C211 C216 -156.1(13) . . . . ?
C231 P2 C211 C216 85.8(13) . . . . ?
C216 C211 C212 C213 0.0 . . . . ?
P2 C211 C212 C213 172.4(16) . . . . ?
C211 C212 C213 C214 0.0 . . . . ?
C212 C213 C214 C215 0.0 . . . . ?
C213 C214 C215 C216 0.0 . . . . ?
C214 C215 C216 C211 0.0 . . . . ?
C212 C211 C216 C215 0.0 . . . . ?
P2 C211 C216 C215 -172.9(15) . . . . ?
O10 P2 C221 C222 19.4(16) . . . . ?
C231 P2 C221 C222 -114.4(15) . . . . ?
C211 P2 C221 C222 127.1(14) . . . . ?
O10 P2 C221 C226 -165.4(13) . . . . ?
C231 P2 C221 C226 60.8(18) . . . . ?
C211 P2 C221 C226 -57.6(18) . . . . ?
C226 C221 C222 C223 0.0 . . . . ?
P2 C221 C222 C223 175.4(19) . . . . ?
C221 C222 C223 C224 0.0 . . . . ?
C222 C223 C224 C225 0.0 . . . . ?
C223 C224 C225 C226 0.0 . . . . ?
C224 C225 C226 C221 0.0 . . . . ?
C222 C221 C226 C225 0.0 . . . . ?
P2 C221 C226 C225 -175(2) . . . . ?
O10 P2 C231 C232 79.7(15) . . . . ?
C221 P2 C231 C232 -147.4(14) . . . . ?
C211 P2 C231 C232 -30.1(16) . . . . ?
O10 P2 C231 C236 -93.8(13) . . . . ?
C221 P2 C231 C236 39.1(16) . . . . ?
C211 P2 C231 C236 156.4(12) . . . . ?
C236 C231 C232 C233 0.0 . . . . ?
P2 C231 C232 C233 -173.4(17) . . . . ?
C231 C232 C233 C234 0.0 . . . . ?
C232 C233 C234 C235 0.0 . . . . ?
C233 C234 C235 C236 0.0 . . . . ?
C234 C235 C236 C231 0.0 . . . . ?
C232 C231 C236 C235 0.0 . . . . ?
P2 C231 C236 C235 173.6(16) . . . . ?
loop_
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1 PubChem 139175991
