#------------------------------------------------------------------------------
#$Date: 2021-04-05 17:11:46 +0200 (Mon 05 de Apr de 2021) $
#$Revision: 263811 $
#$URL: svn://www.crystallography.net/cod/cif/7/06/04/7060419.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7060419
loop_
_publ_author_name
'Jiang, Qin'
'Yang, Xinda'
'Xiang, Pan'
'Dudek, Marta'
'Matczyszyn, Katarzyna'
'Samoc, Marek'
'Tian, Xiaohe'
'Zhang, Qiong'
'Luo, Yuhui'
'Wang, Daqi'
'Shi, Pengfei'
_publ_section_title
;
 Self-assembled heterometallic complexes showing enhanced two-photon
 absorption and their distribution in living cells
;
_journal_issue                   11
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              4994
_journal_page_last               5001
_journal_paper_doi               10.1039/D0NJ05219A
_journal_volume                  45
_journal_year                    2021
_chemical_formula_moiety
'C50 H36 N10  Pt Ru, 4(F6 P).[+3(C4 H10 O) +2(H2 O)]'
_chemical_formula_sum            'C62 H70 F24 N10 O5 P4 Pt Ru'
_chemical_formula_weight         1911.32
_chemical_name_common            RuPt
_space_group_crystal_system      orthorhombic
_space_group_IT_number           62
_space_group_name_Hall           '-P 2ac 2n'
_space_group_name_H-M_alt        'P n m a'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2016/6
_audit_update_record
;
2021-01-22 deposited with the CCDC.	2021-01-27 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            8
_cell_length_a                   28.21(2)
_cell_length_b                   59.04(4)
_cell_length_c                   8.653(7)
_cell_measurement_reflns_used    2562
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      26.257
_cell_measurement_theta_min      2.388
_cell_volume                     14412(18)
_computing_cell_refinement       'SMART(Bruker, 2000)'
_computing_data_collection       'SMART(Bruker, 2000)'
_computing_data_reduction        'SMART(Bruker, 2000)'
_computing_molecular_graphics    'SHELXTL, DIAMOND 3.0'
_computing_publication_material  SHELXTL
_computing_structure_refinement  'SHELXL-2016/6 (Sheldrick, 2016)'
_computing_structure_solution    'SHELXL-2014/7 (Sheldrick, 2014)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.2189
_diffrn_reflns_av_unetI/netI     0.2701
_diffrn_reflns_Laue_measured_fraction_full 0.994
_diffrn_reflns_Laue_measured_fraction_max 0.994
_diffrn_reflns_limit_h_max       33
_diffrn_reflns_limit_h_min       -27
_diffrn_reflns_limit_k_max       70
_diffrn_reflns_limit_k_min       -48
_diffrn_reflns_limit_l_max       9
_diffrn_reflns_limit_l_min       -10
_diffrn_reflns_number            71293
_diffrn_reflns_point_group_measured_fraction_full 0.994
_diffrn_reflns_point_group_measured_fraction_max 0.994
_diffrn_reflns_theta_full        25.019
_diffrn_reflns_theta_max         25.019
_diffrn_reflns_theta_min         2.571
_exptl_absorpt_coefficient_mu    2.355
_exptl_absorpt_correction_T_max  0.9115
_exptl_absorpt_correction_T_min  0.6247
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   sadabs
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.762
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             7600
_exptl_crystal_size_max          0.220
_exptl_crystal_size_mid          0.100
_exptl_crystal_size_min          0.040
_refine_diff_density_max         0.767
_refine_diff_density_min         -0.603
_refine_diff_density_rms         0.103
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.982
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     850
_refine_ls_number_reflns         12790
_refine_ls_number_restraints     707
_refine_ls_restrained_S_all      1.020
_refine_ls_R_factor_all          0.2298
_refine_ls_R_factor_gt           0.0882
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0032P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1158
_refine_ls_wR_factor_ref         0.1332
_reflns_Friedel_coverage         0.000
_reflns_number_gt                3729
_reflns_number_total             12790
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d0nj05219a2.cif
_cod_data_source_block           190413a_sq
_cod_depositor_comments
'Adding full bibliography for 7060417--7060420.cif.'
_cod_database_code               7060419
_shelx_shelxl_version_number     2016/6
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.625
_shelx_estimated_absorpt_t_max   0.912
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'x+1/2, -y+1/2, -z+1/2'
'-x, y+1/2, -z'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'-x-1/2, y-1/2, z-1/2'
'x, -y-1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Pt1 Pt -0.10683(2) 0.53381(2) 0.28497(6) 0.0810(2) Uani 1 1 d . . . . .
Ru1 Ru 0.18416(4) 0.65895(2) 0.35411(12) 0.0730(4) Uani 1 1 d . . . . .
N1 N 0.1283(3) 0.67951(18) 0.2769(12) 0.065(3) Uani 1 1 d . U . . .
N2 N 0.1330(5) 0.6359(2) 0.3293(11) 0.069(3) Uani 1 1 d . . . . .
N3 N 0.2163(4) 0.62968(18) 0.4264(11) 0.070(3) Uani 1 1 d . U . . .
N4 N -0.0531(3) 0.55673(17) 0.3023(13) 0.070(3) Uani 1 1 d . U . . .
N5 N 0.1693(6) 0.6701(2) 0.5687(15) 0.096(4) Uani 1 1 d . . . . .
N6 N 0.2345(4) 0.68148(17) 0.3837(16) 0.079(4) Uani 1 1 d . . . . .
N7 N 0.2195(4) 0.65768(19) 0.1472(13) 0.076(3) Uani 1 1 d . U . . .
N8 N -0.1631(4) 0.5553(3) 0.3360(14) 0.101(5) Uani 1 1 d . . . . .
N9 N -0.1583(4) 0.51123(19) 0.2613(13) 0.072(3) Uani 1 1 d . . . . .
N10 N -0.0686(5) 0.50597(19) 0.2293(13) 0.093(4) Uani 1 1 d . . . . .
C1 C 0.1294(5) 0.7018(2) 0.2545(17) 0.095(5) Uani 1 1 d . U . . .
H1 H 0.157630 0.709826 0.265931 0.114 Uiso 1 1 calc R U . . .
C2 C 0.0875(7) 0.7131(2) 0.2135(19) 0.117(6) Uani 1 1 d . U . . .
H2 H 0.087596 0.728881 0.211179 0.140 Uiso 1 1 calc R U . . .
C3 C 0.0460(7) 0.7018(3) 0.176(2) 0.149(7) Uani 1 1 d . U . . .
H3 H 0.020020 0.709358 0.134827 0.179 Uiso 1 1 calc R U . . .
C4 C 0.0452(5) 0.6788(3) 0.2040(17) 0.100(5) Uani 1 1 d . . . . .
H4 H 0.017001 0.670792 0.193222 0.120 Uiso 1 1 calc R U . . .
C5 C 0.0846(6) 0.6681(2) 0.2462(16) 0.081(5) Uani 1 1 d . . . . .
C6 C 0.0887(6) 0.6437(3) 0.2857(15) 0.066(4) Uani 1 1 d . . . . .
C7 C 0.0528(5) 0.6278(3) 0.2767(14) 0.078(4) Uani 1 1 d . . . . .
H7 H 0.023317 0.632655 0.241916 0.093 Uiso 1 1 calc R U . . .
C8 C 0.0579(5) 0.6047(3) 0.3169(13) 0.062(4) Uani 1 1 d . . . . .
C9 C 0.1035(6) 0.5991(2) 0.3675(13) 0.074(4) Uani 1 1 d . . . . .
H9 H 0.108939 0.584284 0.398444 0.089 Uiso 1 1 calc R U . . .
C10 C 0.1415(5) 0.6142(3) 0.3750(14) 0.063(4) Uani 1 1 d . . . . .
C11 C 0.1898(6) 0.6108(2) 0.4291(14) 0.062(4) Uani 1 1 d . . . . .
C12 C 0.2080(5) 0.5899(2) 0.4765(13) 0.072(4) Uani 1 1 d . U . . .
H12 H 0.188604 0.577167 0.482041 0.086 Uiso 1 1 calc R U . . .
C13 C 0.2566(5) 0.5884(2) 0.5160(17) 0.108(6) Uani 1 1 d . U . . .
H13 H 0.270076 0.574457 0.539287 0.130 Uiso 1 1 calc R U . . .
C14 C 0.2834(5) 0.6075(2) 0.5197(16) 0.091(5) Uani 1 1 d . U . . .
H14 H 0.314917 0.606858 0.551309 0.109 Uiso 1 1 calc R U . . .
C15 C 0.2637(5) 0.6276(2) 0.4765(14) 0.076(4) Uani 1 1 d . U . . .
H15 H 0.282407 0.640606 0.480276 0.091 Uiso 1 1 calc R U . . .
C16 C -0.0467(5) 0.5722(2) 0.1866(17) 0.088(5) Uani 1 1 d . U . . .
H16 H -0.067291 0.571697 0.102624 0.106 Uiso 1 1 calc R U . . .
C17 C -0.0116(5) 0.5884(2) 0.1870(16) 0.075(4) Uani 1 1 d . U . . .
H17 H -0.008574 0.598710 0.106571 0.090 Uiso 1 1 calc R U . . .
C18 C 0.0202(5) 0.5887(2) 0.3161(17) 0.067(4) Uani 1 1 d . . . . .
C19 C 0.0143(5) 0.5732(2) 0.4366(17) 0.090(5) Uani 1 1 d . U . . .
H19 H 0.034597 0.572835 0.521290 0.108 Uiso 1 1 calc R U . . .
C20 C -0.0247(4) 0.5582(2) 0.4216(16) 0.086(5) Uani 1 1 d . U . . .
H20 H -0.030590 0.548487 0.504060 0.103 Uiso 1 1 calc R U . . .
C21 C 0.1291(7) 0.6625(3) 0.655(2) 0.105(6) Uani 1 1 d . . . . .
H21 H 0.108970 0.650968 0.621551 0.125 Uiso 1 1 calc R U . . .
C22 C 0.1225(6) 0.6753(3) 0.809(2) 0.127(6) Uani 1 1 d . . . . .
H22 H 0.097958 0.671438 0.875866 0.152 Uiso 1 1 calc R U . . .
C23 C 0.1537(8) 0.6926(4) 0.846(2) 0.177(9) Uani 1 1 d . U . . .
H23 H 0.146916 0.700810 0.934930 0.212 Uiso 1 1 calc R U . . .
C24 C 0.1928(7) 0.6989(3) 0.767(2) 0.134(6) Uani 1 1 d . U . . .
H24 H 0.215256 0.709187 0.802316 0.161 Uiso 1 1 calc R U . . .
C25 C 0.1950(6) 0.6877(3) 0.6228(19) 0.095(5) Uani 1 1 d . U . . .
C26 C 0.2353(6) 0.6941(3) 0.524(2) 0.099(5) Uani 1 1 d . U . . .
C27 C 0.2745(6) 0.7097(2) 0.5360(17) 0.101(5) Uani 1 1 d . U . . .
H27 H 0.276235 0.718449 0.625411 0.121 Uiso 1 1 calc R U . . .
C28 C 0.3097(7) 0.7131(3) 0.427(2) 0.141(7) Uani 1 1 d . U . . .
H28 H 0.335739 0.722363 0.445328 0.169 Uiso 1 1 calc R U . . .
C29 C 0.3037(5) 0.7021(3) 0.296(2) 0.122(6) Uani 1 1 d D . . . .
H29 H 0.324500 0.705443 0.215773 0.147 Uiso 1 1 calc R U . . .
C30 C 0.2679(6) 0.6854(3) 0.267(2) 0.100(6) Uani 1 1 d D U . . .
C31 C 0.2596(6) 0.6707(3) 0.142(3) 0.098(5) Uani 1 1 d . U . . .
C32 C 0.2884(6) 0.6712(3) 0.006(3) 0.106(6) Uani 1 1 d . . . . .
H32 H 0.313389 0.681451 -0.001967 0.127 Uiso 1 1 calc R U . . .
C33 C 0.2792(7) 0.6569(4) -0.110(2) 0.126(7) Uani 1 1 d . . . . .
H33 H 0.299731 0.656539 -0.194590 0.151 Uiso 1 1 calc R U . . .
C34 C 0.2398(7) 0.6425(3) -0.1100(19) 0.109(6) Uani 1 1 d . . . . .
H34 H 0.232766 0.633048 -0.192896 0.130 Uiso 1 1 calc R U . . .
C35 C 0.2119(5) 0.6432(2) 0.023(2) 0.095(5) Uani 1 1 d . . . . .
H35 H 0.186430 0.633215 0.028860 0.114 Uiso 1 1 calc R U . . .
C36 C -0.1623(6) 0.5775(3) 0.3722(17) 0.100(5) Uani 1 1 d . U . . .
H36 H -0.133854 0.585362 0.377376 0.120 Uiso 1 1 calc R U . . .
C37 C -0.2065(6) 0.5886(3) 0.4024(17) 0.105(5) Uani 1 1 d . U . . .
H37 H -0.208537 0.604032 0.423182 0.126 Uiso 1 1 calc R U . . .
C38 C -0.2440(7) 0.5752(3) 0.3983(18) 0.130(7) Uani 1 1 d . U . . .
H38 H -0.272262 0.582418 0.423730 0.156 Uiso 1 1 calc R U . . .
C39 C -0.2489(6) 0.5529(3) 0.3639(17) 0.113(6) Uani 1 1 d . . . . .
H39 H -0.277711 0.545227 0.364304 0.136 Uiso 1 1 calc R U . . .
C40 C -0.2055(7) 0.5429(3) 0.3277(18) 0.098(5) Uani 1 1 d . U . . .
C41 C -0.2014(6) 0.5189(3) 0.2906(17) 0.084(4) Uani 1 1 d . U . . .
C42 C -0.2367(6) 0.5032(3) 0.272(2) 0.128(6) Uani 1 1 d . U . . .
H42 H -0.268107 0.507622 0.282466 0.154 Uiso 1 1 calc R U . . .
C43 C -0.2263(6) 0.4802(3) 0.2364(18) 0.113(5) Uani 1 1 d . U . . .
H43 H -0.250029 0.469269 0.230160 0.135 Uiso 1 1 calc R U . . .
C44 C -0.1784(6) 0.4748(3) 0.2112(19) 0.135(7) Uani 1 1 d . U . . .
H44 H -0.170493 0.459966 0.186598 0.163 Uiso 1 1 calc R U . . .
C45 C -0.1438(5) 0.4902(3) 0.2213(16) 0.080(4) Uani 1 1 d D . . . .
C46 C -0.0932(5) 0.4882(3) 0.2048(18) 0.086(5) Uani 1 1 d D U . . .
C47 C -0.0732(6) 0.4680(3) 0.1625(15) 0.104(5) Uani 1 1 d . U . . .
H47 H -0.092723 0.455845 0.138311 0.124 Uiso 1 1 calc R U . . .
C48 C -0.0236(7) 0.4654(3) 0.1551(18) 0.125(6) Uani 1 1 d . U . . .
H48 H -0.008789 0.451839 0.130407 0.150 Uiso 1 1 calc R U . . .
C49 C 0.0009(5) 0.4852(3) 0.1884(15) 0.090(5) Uani 1 1 d . U . . .
H49 H 0.033835 0.484705 0.187801 0.108 Uiso 1 1 calc R U . . .
C50 C -0.0211(6) 0.5055(2) 0.2225(17) 0.102(5) Uani 1 1 d . . . . .
H50 H -0.003433 0.518548 0.240350 0.122 Uiso 1 1 calc R U . . .
P1 P 0.1099(3) 0.59992(11) 0.8501(7) 0.1444(19) Uani 1 1 d . U . . .
P2 P 0.3795(2) 0.47264(12) 0.8228(7) 0.1431(19) Uani 1 1 d . U . . .
P3 P 0.2266(3) 0.750000 0.0673(11) 0.170(3) Uani 1 2 d DS TU P . .
P4 P 0.3641(3) 0.55396(17) 0.6923(9) 0.187(3) Uani 0.75 1 d D U P . .
P5 P 0.4002(4) 0.64427(17) 0.3169(11) 0.268(4) Uani 0.75 1 d D U P . .
F1 F 0.1394(5) 0.5925(2) 0.9807(15) 0.211(4) Uani 1 1 d . U . . .
F2 F 0.0767(4) 0.61245(19) 0.7148(13) 0.196(3) Uani 1 1 d . U . . .
F3 F 0.0676(4) 0.58641(18) 0.9235(12) 0.193(3) Uani 1 1 d . U . . .
F4 F 0.1142(4) 0.58047(16) 0.7327(11) 0.177(3) Uani 1 1 d . U . . .
F5 F 0.1519(4) 0.61374(15) 0.7741(11) 0.162(3) Uani 1 1 d . U . . .
F6 F 0.0964(4) 0.62180(18) 0.9514(11) 0.193(3) Uani 1 1 d . U . . .
F7 F 0.3353(4) 0.48169(19) 0.9154(12) 0.200(3) Uani 1 1 d . U . . .
F8 F 0.4238(4) 0.46241(19) 0.7375(12) 0.187(3) Uani 1 1 d . U . . .
F9 F 0.3491(4) 0.45154(19) 0.7574(13) 0.188(3) Uani 1 1 d . U . . .
F10 F 0.3857(4) 0.45688(18) 0.9751(12) 0.189(3) Uani 1 1 d . U . . .
F11 F 0.4089(4) 0.4904(2) 0.9078(12) 0.188(3) Uani 1 1 d . U . . .
F12 F 0.3669(4) 0.4864(2) 0.6807(12) 0.198(4) Uani 1 1 d . U . . .
F13 F 0.2260(3) 0.72285(12) 0.0694(11) 0.202(4) Uani 1 1 d D U . . .
F15 F 0.2802(4) 0.750000 0.1164(17) 0.209(5) Uani 1 2 d DS TU P . .
F16 F 0.2101(5) 0.750000 0.2435(13) 0.209(5) Uani 1 2 d DS TU P . .
F17 F 0.1727(4) 0.750000 0.0104(16) 0.216(5) Uani 1 2 d DS TU P . .
F18 F 0.2419(5) 0.750000 -0.1086(14) 0.218(5) Uani 1 2 d DS TU P . .
F19 F 0.3637(4) 0.5717(2) 0.5573(13) 0.209(4) Uani 0.75 1 d D U P . .
F20 F 0.3663(4) 0.5360(2) 0.8243(12) 0.229(5) Uani 0.75 1 d D U P . .
F21 F 0.3252(4) 0.5400(2) 0.6039(13) 0.222(4) Uani 0.75 1 d D U P . .
F22 F 0.3244(4) 0.5669(2) 0.7790(13) 0.229(4) Uani 0.75 1 d D U P . .
F23 F 0.4032(4) 0.5688(2) 0.7764(14) 0.245(5) Uani 0.75 1 d D U P . .
F24 F 0.4027(4) 0.5399(2) 0.6054(13) 0.213(4) Uani 0.75 1 d D U P . .
F25 F 0.3525(5) 0.6408(2) 0.2260(16) 0.280(5) Uani 0.75 1 d D U P . .
F26 F 0.4472(5) 0.6463(2) 0.4139(17) 0.283(5) Uani 0.75 1 d D U P . .
F27 F 0.3897(5) 0.6206(2) 0.3979(16) 0.265(5) Uani 0.75 1 d D U P . .
F28 F 0.3701(5) 0.6552(2) 0.4527(15) 0.274(5) Uani 0.75 1 d D U P . .
F29 F 0.4051(5) 0.6673(2) 0.2445(18) 0.294(5) Uani 0.75 1 d D U P . .
F30 F 0.4261(5) 0.6321(3) 0.1749(15) 0.294(5) Uani 0.75 1 d D U P . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pt Pt -1.7033 8.3905 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N9 Pt1 N10 79.6(5) . . ?
N9 Pt1 N4 178.1(5) . . ?
N10 Pt1 N4 99.3(5) . . ?
N9 Pt1 N8 82.7(5) . . ?
N10 Pt1 N8 162.3(6) . . ?
N4 Pt1 N8 98.5(5) . . ?
N6 Ru1 N2 178.7(5) . . ?
N6 Ru1 N3 102.2(5) . . ?
N2 Ru1 N3 77.2(5) . . ?
N6 Ru1 N5 79.0(6) . . ?
N2 Ru1 N5 99.9(6) . . ?
N3 Ru1 N5 94.9(4) . . ?
N6 Ru1 N7 77.7(6) . . ?
N2 Ru1 N7 103.5(4) . . ?
N3 Ru1 N7 91.2(4) . . ?
N5 Ru1 N7 156.6(6) . . ?
N6 Ru1 N1 101.1(4) . . ?
N2 Ru1 N1 79.4(5) . . ?
N3 Ru1 N1 156.6(5) . . ?
N5 Ru1 N1 87.1(4) . . ?
N7 Ru1 N1 96.2(4) . . ?
C1 N1 C5 117.3(11) . . ?
C1 N1 Ru1 127.0(9) . . ?
C5 N1 Ru1 115.7(9) . . ?
C6 N2 C10 123.2(13) . . ?
C6 N2 Ru1 117.3(10) . . ?
C10 N2 Ru1 118.9(10) . . ?
C11 N3 C15 116.8(12) . . ?
C11 N3 Ru1 117.4(10) . . ?
C15 N3 Ru1 125.8(9) . . ?
C20 N4 C16 116.9(12) . . ?
C20 N4 Pt1 123.9(10) . . ?
C16 N4 Pt1 119.2(10) . . ?
C21 N5 C25 119.2(15) . . ?
C21 N5 Ru1 122.9(12) . . ?
C25 N5 Ru1 117.3(13) . . ?
C30 N6 C26 121.3(15) . . ?
C30 N6 Ru1 120.3(11) . . ?
C26 N6 Ru1 118.4(12) . . ?
C35 N7 C31 116.4(14) . . ?
C35 N7 Ru1 128.5(10) . . ?
C31 N7 Ru1 114.4(12) . . ?
C36 N8 C40 122.2(15) . . ?
C36 N8 Pt1 129.0(11) . . ?
C40 N8 Pt1 108.8(12) . . ?
C41 N9 C45 129.9(13) . . ?
C41 N9 Pt1 115.1(11) . . ?
C45 N9 Pt1 115.0(10) . . ?
C46 N10 C50 121.3(14) . . ?
C46 N10 Pt1 114.7(12) . . ?
C50 N10 Pt1 124.0(10) . . ?
C2 C1 N1 119.2(13) . . ?
C2 C1 H1 120.4 . . ?
N1 C1 H1 120.4 . . ?
C1 C2 C3 122.8(16) . . ?
C1 C2 H2 118.6 . . ?
C3 C2 H2 118.6 . . ?
C2 C3 C4 116.7(17) . . ?
C2 C3 H3 121.7 . . ?
C4 C3 H3 121.7 . . ?
C5 C4 C3 120.1(15) . . ?
C5 C4 H4 119.9 . . ?
C3 C4 H4 119.9 . . ?
C4 C5 N1 123.2(13) . . ?
C4 C5 C6 126.1(16) . . ?
N1 C5 C6 110.3(13) . . ?
N2 C6 C7 117.0(14) . . ?
N2 C6 C5 116.9(14) . . ?
C7 C6 C5 126.0(16) . . ?
C6 C7 C8 124.5(14) . . ?
C6 C7 H7 117.8 . . ?
C8 C7 H7 117.8 . . ?
C7 C8 C18 124.4(14) . . ?
C7 C8 C9 113.2(13) . . ?
C18 C8 C9 122.3(14) . . ?
C10 C9 C8 125.0(14) . . ?
C10 C9 H9 117.5 . . ?
C8 C9 H9 117.5 . . ?
N2 C10 C9 116.9(14) . . ?
N2 C10 C11 112.9(13) . . ?
C9 C10 C11 130.1(17) . . ?
N3 C11 C12 122.2(15) . . ?
N3 C11 C10 113.5(13) . . ?
C12 C11 C10 124.3(15) . . ?
C11 C12 C13 118.7(14) . . ?
C11 C12 H12 120.6 . . ?
C13 C12 H12 120.6 . . ?
C14 C13 C12 119.7(14) . . ?
C14 C13 H13 120.1 . . ?
C12 C13 H13 120.1 . . ?
C15 C14 C13 119.3(15) . . ?
C15 C14 H14 120.4 . . ?
C13 C14 H14 120.4 . . ?
C14 C15 N3 123.0(13) . . ?
C14 C15 H15 118.5 . . ?
N3 C15 H15 118.5 . . ?
C17 C16 N4 123.8(14) . . ?
C17 C16 H16 118.1 . . ?
N4 C16 H16 118.1 . . ?
C16 C17 C18 117.5(12) . . ?
C16 C17 H17 121.3 . . ?
C18 C17 H17 121.3 . . ?
C17 C18 C19 120.0(13) . . ?
C17 C18 C8 118.7(13) . . ?
C19 C18 C8 121.3(14) . . ?
C20 C19 C18 115.6(13) . . ?
C20 C19 H19 122.2 . . ?
C18 C19 H19 122.2 . . ?
N4 C20 C19 126.0(13) . . ?
N4 C20 H20 117.0 . . ?
C19 C20 H20 117.0 . . ?
N5 C21 C22 113.0(15) . . ?
N5 C21 H21 123.5 . . ?
C22 C21 H21 123.5 . . ?
C23 C22 C21 118.9(17) . . ?
C23 C22 H22 120.5 . . ?
C21 C22 H22 120.5 . . ?
C22 C23 C24 127(2) . . ?
C22 C23 H23 116.4 . . ?
C24 C23 H23 116.4 . . ?
C23 C24 C25 110.7(19) . . ?
C23 C24 H24 124.6 . . ?
C25 C24 H24 124.6 . . ?
N5 C25 C24 130.0(17) . . ?
N5 C25 C26 114.3(17) . . ?
C24 C25 C26 115.2(19) . . ?
N6 C26 C27 113.8(15) . . ?
N6 C26 C25 110.4(16) . . ?
C27 C26 C25 135.7(19) . . ?
C28 C27 C26 126.4(16) . . ?
C28 C27 H27 116.8 . . ?
C26 C27 H27 116.8 . . ?
C29 C28 C27 115.2(19) . . ?
C29 C28 H28 122.4 . . ?
C27 C28 H28 122.4 . . ?
C28 C29 C30 125.4(19) . . ?
C28 C29 H29 117.3 . . ?
C30 C29 H29 117.3 . . ?
N6 C30 C29 117.4(17) . . ?
N6 C30 C31 110.1(16) . . ?
C29 C30 C31 132(2) . . ?
C32 C31 N7 120.8(18) . . ?
C32 C31 C30 122(2) . . ?
N7 C31 C30 117.1(18) . . ?
C33 C32 C31 119(2) . . ?
C33 C32 H32 120.3 . . ?
C31 C32 H32 120.3 . . ?
C32 C33 C34 122(2) . . ?
C32 C33 H33 118.8 . . ?
C34 C33 H33 118.8 . . ?
C35 C34 C33 115.7(18) . . ?
C35 C34 H34 122.2 . . ?
C33 C34 H34 122.2 . . ?
N7 C35 C34 124.6(15) . . ?
N7 C35 H35 117.7 . . ?
C34 C35 H35 117.7 . . ?
N8 C36 C37 118.4(16) . . ?
N8 C36 H36 120.8 . . ?
C37 C36 H36 120.8 . . ?
C36 C37 C38 114.6(16) . . ?
C36 C37 H37 122.7 . . ?
C38 C37 H37 122.7 . . ?
C39 C38 C37 131.9(19) . . ?
C39 C38 H38 114.0 . . ?
C37 C38 H38 114.0 . . ?
C40 C39 C38 111.7(18) . . ?
C40 C39 H39 124.1 . . ?
C38 C39 H39 124.1 . . ?
C39 C40 N8 121.0(16) . . ?
C39 C40 C41 122.0(18) . . ?
N8 C40 C41 116.8(17) . . ?
N9 C41 C42 114.4(16) . . ?
N9 C41 C40 116.5(16) . . ?
C42 C41 C40 128.9(18) . . ?
C41 C42 C43 121.6(17) . . ?
C41 C42 H42 119.2 . . ?
C43 C42 H42 119.2 . . ?
C44 C43 C42 116.5(15) . . ?
C44 C43 H43 121.8 . . ?
C42 C43 H43 121.8 . . ?
C45 C44 C43 122.6(15) . . ?
C45 C44 H44 118.7 . . ?
C43 C44 H44 118.7 . . ?
C44 C45 N9 114.9(14) . . ?
C44 C45 C46 131.4(16) . . ?
N9 C45 C46 113.6(15) . . ?
N10 C46 C47 122.5(14) . . ?
N10 C46 C45 117.0(17) . . ?
C47 C46 C45 120.4(16) . . ?
C48 C47 C46 121.0(16) . . ?
C48 C47 H47 119.5 . . ?
C46 C47 H47 119.5 . . ?
C47 C48 C49 113.2(15) . . ?
C47 C48 H48 123.4 . . ?
C49 C48 H48 123.4 . . ?
C50 C49 C48 123.4(15) . . ?
C50 C49 H49 118.3 . . ?
C48 C49 H49 118.3 . . ?
N10 C50 C49 118.3(14) . . ?
N10 C50 H50 120.8 . . ?
C49 C50 H50 120.8 . . ?
F1 P1 F4 103.8(8) . . ?
F1 P1 F5 92.9(8) . . ?
F4 P1 F5 92.9(6) . . ?
F1 P1 F6 87.4(7) . . ?
F4 P1 F6 168.4(8) . . ?
F5 P1 F6 89.4(6) . . ?
F1 P1 F3 88.1(7) . . ?
F4 P1 F3 87.0(6) . . ?
F5 P1 F3 179.0(9) . . ?
F6 P1 F3 90.5(6) . . ?
F1 P1 F2 170.9(8) . . ?
F4 P1 F2 85.0(6) . . ?
F5 P1 F2 84.2(6) . . ?
F6 P1 F2 83.9(7) . . ?
F3 P1 F2 94.8(7) . . ?
F12 P2 F11 98.6(8) . . ?
F12 P2 F8 90.6(7) . . ?
F11 P2 F8 93.3(6) . . ?
F12 P2 F7 92.6(7) . . ?
F11 P2 F7 87.3(6) . . ?
F8 P2 F7 176.6(8) . . ?
F12 P2 F10 172.5(8) . . ?
F11 P2 F10 86.8(6) . . ?
F8 P2 F10 94.3(6) . . ?
F7 P2 F10 82.3(6) . . ?
F12 P2 F9 90.3(7) . . ?
F11 P2 F9 171.0(8) . . ?
F8 P2 F9 87.8(6) . . ?
F7 P2 F9 91.1(7) . . ?
F10 P2 F9 84.2(7) . . ?
F15 P3 F13 90.5(4) . . ?
F15 P3 F13 90.5(4) . 8_575 ?
F13 P3 F13 178.1(9) . 8_575 ?
F15 P3 F18 89.9(7) . . ?
F13 P3 F18 90.8(4) . . ?
F13 P3 F18 90.8(4) 8_575 . ?
F15 P3 F16 91.3(7) . . ?
F13 P3 F16 89.2(4) . . ?
F13 P3 F16 89.2(4) 8_575 . ?
F18 P3 F16 178.8(7) . . ?
F15 P3 F17 177.8(10) . . ?
F13 P3 F17 89.6(4) . . ?
F13 P3 F17 89.6(4) 8_575 . ?
F18 P3 F17 87.9(7) . . ?
F16 P3 F17 90.9(7) . . ?
F22 P4 F20 90.6(7) . . ?
F22 P4 F24 177.4(8) . . ?
F20 P4 F24 87.9(7) . . ?
F22 P4 F23 90.4(7) . . ?
F20 P4 F23 90.7(7) . . ?
F24 P4 F23 91.8(7) . . ?
F22 P4 F19 91.5(7) . . ?
F20 P4 F19 177.9(7) . . ?
F24 P4 F19 90.0(6) . . ?
F23 P4 F19 88.7(7) . . ?
F22 P4 F21 89.3(7) . . ?
F20 P4 F21 91.7(7) . . ?
F24 P4 F21 88.6(6) . . ?
F23 P4 F21 177.7(10) . . ?
F19 P4 F21 89.0(6) . . ?
F29 P5 F25 89.3(7) . . ?
F29 P5 F26 94.4(8) . . ?
F25 P5 F26 176.2(9) . . ?
F29 P5 F28 89.5(7) . . ?
F25 P5 F28 88.0(7) . . ?
F26 P5 F28 91.4(7) . . ?
F29 P5 F30 92.5(8) . . ?
F25 P5 F30 86.9(7) . . ?
F26 P5 F30 93.5(7) . . ?
F28 P5 F30 174.6(10) . . ?
F29 P5 F27 174.2(11) . . ?
F25 P5 F27 86.9(7) . . ?
F26 P5 F27 89.4(7) . . ?
F28 P5 F27 86.0(7) . . ?
F30 P5 F27 91.7(7) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Pt1 N9 1.982(9) . ?
Pt1 N10 2.024(13) . ?
Pt1 N4 2.037(9) . ?
Pt1 N8 2.079(12) . ?
Ru1 N6 1.963(11) . ?
Ru1 N2 1.993(11) . ?
Ru1 N3 2.049(10) . ?
Ru1 N5 2.014(13) . ?
Ru1 N7 2.051(11) . ?
Ru1 N1 2.097(9) . ?
N1 C1 1.333(13) . ?
N1 C5 1.431(15) . ?
N2 C6 1.383(14) . ?
N2 C10 1.363(14) . ?
N3 C11 1.345(14) . ?
N3 C15 1.412(14) . ?
N4 C20 1.310(13) . ?
N4 C16 1.366(14) . ?
N5 C21 1.431(17) . ?
N5 C25 1.351(16) . ?
N6 C30 1.399(18) . ?
N6 C26 1.427(16) . ?
N7 C35 1.392(15) . ?
N7 C31 1.367(17) . ?
N8 C36 1.348(14) . ?
N8 C40 1.403(17) . ?
N9 C41 1.322(15) . ?
N9 C45 1.351(13) . ?
N10 C46 1.274(15) . ?
N10 C50 1.341(15) . ?
C1 C2 1.403(16) . ?
C1 H1 0.9300 . ?
C2 C3 1.386(19) . ?
C2 H2 0.9300 . ?
C3 C4 1.379(17) . ?
C3 H3 0.9300 . ?
C4 C5 1.331(16) . ?
C4 H4 0.9300 . ?
C5 C6 1.486(16) . ?
C6 C7 1.381(14) . ?
C7 C8 1.417(15) . ?
C7 H7 0.9300 . ?
C8 C18 1.422(16) . ?
C8 C9 1.398(15) . ?
C9 C10 1.395(15) . ?
C9 H9 0.9300 . ?
C10 C11 1.455(16) . ?
C11 C12 1.398(14) . ?
C12 C13 1.414(15) . ?
C12 H12 0.9300 . ?
C13 C14 1.358(15) . ?
C13 H13 0.9300 . ?
C14 C15 1.364(15) . ?
C14 H14 0.9300 . ?
C15 H15 0.9300 . ?
C16 C17 1.379(15) . ?
C16 H16 0.9300 . ?
C17 C18 1.432(15) . ?
C17 H17 0.9300 . ?
C18 C19 1.394(15) . ?
C19 C20 1.420(15) . ?
C19 H19 0.9300 . ?
C20 H20 0.9300 . ?
C21 C22 1.544(19) . ?
C21 H21 0.9300 . ?
C22 C23 1.39(2) . ?
C22 H22 0.9300 . ?
C23 C24 1.35(2) . ?
C23 H23 0.9300 . ?
C24 C25 1.412(19) . ?
C24 H24 0.9300 . ?
C25 C26 1.470(18) . ?
C26 C27 1.446(17) . ?
C27 C28 1.38(2) . ?
C27 H27 0.9300 . ?
C28 C29 1.317(18) . ?
C28 H28 0.9300 . ?
C29 C30 1.436(14) . ?
C29 H29 0.9300 . ?
C30 C31 1.41(2) . ?
C31 C32 1.43(2) . ?
C32 C33 1.338(18) . ?
C32 H32 0.9300 . ?
C33 C34 1.400(19) . ?
C33 H33 0.9300 . ?
C34 C35 1.394(16) . ?
C34 H34 0.9300 . ?
C35 H35 0.9300 . ?
C36 C37 1.432(17) . ?
C36 H36 0.9300 . ?
C37 C38 1.322(18) . ?
C37 H37 0.9300 . ?
C38 C39 1.358(17) . ?
C38 H38 0.9300 . ?
C39 C40 1.397(18) . ?
C39 H39 0.9300 . ?
C40 C41 1.457(18) . ?
C41 C42 1.370(18) . ?
C42 C43 1.421(17) . ?
C42 H42 0.9300 . ?
C43 C44 1.404(18) . ?
C43 H43 0.9300 . ?
C44 C45 1.337(16) . ?
C44 H44 0.9300 . ?
C45 C46 1.441(14) . ?
C46 C47 1.366(18) . ?
C47 C48 1.411(17) . ?
C47 H47 0.9300 . ?
C48 C49 1.383(17) . ?
C48 H48 0.9300 . ?
C49 C50 1.385(16) . ?
C49 H49 0.9300 . ?
C50 H50 0.9300 . ?
P1 F1 1.471(12) . ?
P1 F4 1.537(9) . ?
P1 F5 1.582(10) . ?
P1 F6 1.607(11) . ?
P1 F3 1.569(11) . ?
P1 F2 1.671(13) . ?
P2 F12 1.517(11) . ?
P2 F11 1.525(11) . ?
P2 F8 1.573(10) . ?
P2 F7 1.576(10) . ?
P2 F10 1.623(11) . ?
P2 F9 1.615(11) . ?
P3 F15 1.569(9) . ?
P3 F13 1.603(7) . ?
P3 F13 1.603(7) 8_575 ?
P3 F18 1.582(9) . ?
P3 F16 1.595(9) . ?
P3 F17 1.599(9) . ?
P4 F22 1.552(8) . ?
P4 F20 1.559(8) . ?
P4 F24 1.561(8) . ?
P4 F23 1.586(8) . ?
P4 F19 1.568(8) . ?
P4 F21 1.572(8) . ?
P5 F29 1.501(15) . ?
P5 F25 1.573(9) . ?
P5 F26 1.573(9) . ?
P5 F28 1.587(7) . ?
P5 F30 1.598(9) . ?
P5 F27 1.591(9) . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C5 N1 C1 C2 4(2) . . . . ?
Ru1 N1 C1 C2 -175.1(11) . . . . ?
N1 C1 C2 C3 -8(3) . . . . ?
C1 C2 C3 C4 10(3) . . . . ?
C2 C3 C4 C5 -8(3) . . . . ?
C3 C4 C5 N1 5(2) . . . . ?
C3 C4 C5 C6 177.5(15) . . . . ?
C1 N1 C5 C4 -3(2) . . . . ?
Ru1 N1 C5 C4 176.5(12) . . . . ?
C1 N1 C5 C6 -176.7(11) . . . . ?
Ru1 N1 C5 C6 3.0(14) . . . . ?
C10 N2 C6 C7 -5.5(18) . . . . ?
Ru1 N2 C6 C7 -176.6(9) . . . . ?
C10 N2 C6 C5 177.0(11) . . . . ?
Ru1 N2 C6 C5 5.9(15) . . . . ?
C4 C5 C6 N2 -178.9(14) . . . . ?
N1 C5 C6 N2 -5.7(17) . . . . ?
C4 C5 C6 C7 4(2) . . . . ?
N1 C5 C6 C7 177.2(12) . . . . ?
N2 C6 C7 C8 4(2) . . . . ?
C5 C6 C7 C8 -179.3(12) . . . . ?
C6 C7 C8 C18 176.2(12) . . . . ?
C6 C7 C8 C9 -0.1(19) . . . . ?
C7 C8 C9 C10 -1.8(18) . . . . ?
C18 C8 C9 C10 -178.1(11) . . . . ?
C6 N2 C10 C9 3.8(17) . . . . ?
Ru1 N2 C10 C9 174.8(8) . . . . ?
C6 N2 C10 C11 -174.5(11) . . . . ?
Ru1 N2 C10 C11 -3.5(14) . . . . ?
C8 C9 C10 N2 0.0(18) . . . . ?
C8 C9 C10 C11 178.0(12) . . . . ?
C15 N3 C11 C12 -1.0(17) . . . . ?
Ru1 N3 C11 C12 -179.9(9) . . . . ?
C15 N3 C11 C10 -179.7(10) . . . . ?
Ru1 N3 C11 C10 1.4(13) . . . . ?
N2 C10 C11 N3 1.2(15) . . . . ?
C9 C10 C11 N3 -176.8(11) . . . . ?
N2 C10 C11 C12 -177.4(11) . . . . ?
C9 C10 C11 C12 5(2) . . . . ?
N3 C11 C12 C13 -3.0(19) . . . . ?
C10 C11 C12 C13 175.4(12) . . . . ?
C11 C12 C13 C14 6(2) . . . . ?
C12 C13 C14 C15 -4(2) . . . . ?
C13 C14 C15 N3 0(2) . . . . ?
C11 N3 C15 C14 2.9(19) . . . . ?
Ru1 N3 C15 C14 -178.3(10) . . . . ?
C20 N4 C16 C17 2(2) . . . . ?
Pt1 N4 C16 C17 179.9(10) . . . . ?
N4 C16 C17 C18 1(2) . . . . ?
C16 C17 C18 C19 -1(2) . . . . ?
C16 C17 C18 C8 177.7(12) . . . . ?
C7 C8 C18 C17 44.9(18) . . . . ?
C9 C8 C18 C17 -139.1(12) . . . . ?
C7 C8 C18 C19 -136.1(14) . . . . ?
C9 C8 C18 C19 39.9(19) . . . . ?
C17 C18 C19 C20 -1(2) . . . . ?
C8 C18 C19 C20 180.0(12) . . . . ?
C16 N4 C20 C19 -5(2) . . . . ?
Pt1 N4 C20 C19 177.4(11) . . . . ?
C18 C19 C20 N4 4(2) . . . . ?
C25 N5 C21 C22 -3.5(19) . . . . ?
Ru1 N5 C21 C22 -174.0(9) . . . . ?
N5 C21 C22 C23 2(2) . . . . ?
C21 C22 C23 C24 -6(3) . . . . ?
C22 C23 C24 C25 9(3) . . . . ?
C21 N5 C25 C24 9(3) . . . . ?
Ru1 N5 C25 C24 -179.6(14) . . . . ?
C21 N5 C25 C26 -179.8(12) . . . . ?
Ru1 N5 C25 C26 -8.8(17) . . . . ?
C23 C24 C25 N5 -12(3) . . . . ?
C23 C24 C25 C26 177.6(15) . . . . ?
C30 N6 C26 C27 -3(2) . . . . ?
Ru1 N6 C26 C27 178.5(9) . . . . ?
C30 N6 C26 C25 176.4(12) . . . . ?
Ru1 N6 C26 C25 -1.8(16) . . . . ?
N5 C25 C26 N6 6.7(19) . . . . ?
C24 C25 C26 N6 178.9(12) . . . . ?
N5 C25 C26 C27 -173.7(15) . . . . ?
C24 C25 C26 C27 -1(3) . . . . ?
N6 C26 C27 C28 -1(2) . . . . ?
C25 C26 C27 C28 179.6(17) . . . . ?
C26 C27 C28 C29 6(3) . . . . ?
C27 C28 C29 C30 -8(3) . . . . ?
C26 N6 C30 C29 2(2) . . . . ?
Ru1 N6 C30 C29 -180.0(10) . . . . ?
C26 N6 C30 C31 179.4(12) . . . . ?
Ru1 N6 C30 C31 -2.4(18) . . . . ?
C28 C29 C30 N6 4(3) . . . . ?
C28 C29 C30 C31 -172.5(18) . . . . ?
C35 N7 C31 C32 8(2) . . . . ?
Ru1 N7 C31 C32 179.0(12) . . . . ?
C35 N7 C31 C30 -179.8(14) . . . . ?
Ru1 N7 C31 C30 -8.6(18) . . . . ?
N6 C30 C31 C32 179.5(14) . . . . ?
C29 C30 C31 C32 -3(3) . . . . ?
N6 C30 C31 N7 7(2) . . . . ?
C29 C30 C31 N7 -175.8(15) . . . . ?
N7 C31 C32 C33 -8(3) . . . . ?
C30 C31 C32 C33 -179.9(16) . . . . ?
C31 C32 C33 C34 5(3) . . . . ?
C32 C33 C34 C35 -3(3) . . . . ?
C31 N7 C35 C34 -6(2) . . . . ?
Ru1 N7 C35 C34 -175.5(10) . . . . ?
C33 C34 C35 N7 3(2) . . . . ?
C40 N8 C36 C37 0(2) . . . . ?
Pt1 N8 C36 C37 179.8(10) . . . . ?
N8 C36 C37 C38 3(2) . . . . ?
C36 C37 C38 C39 -3(3) . . . . ?
C37 C38 C39 C40 0(3) . . . . ?
C38 C39 C40 N8 3(2) . . . . ?
C38 C39 C40 C41 178.4(14) . . . . ?
C36 N8 C40 C39 -3(2) . . . . ?
Pt1 N8 C40 C39 177.0(11) . . . . ?
C36 N8 C40 C41 -178.8(14) . . . . ?
Pt1 N8 C40 C41 1.2(16) . . . . ?
C45 N9 C41 C42 -3(2) . . . . ?
Pt1 N9 C41 C42 179.2(11) . . . . ?
C45 N9 C41 C40 -178.6(14) . . . . ?
Pt1 N9 C41 C40 3.2(17) . . . . ?
C39 C40 C41 N9 -178.7(14) . . . . ?
N8 C40 C41 N9 -3(2) . . . . ?
C39 C40 C41 C42 6(3) . . . . ?
N8 C40 C41 C42 -178.3(16) . . . . ?
N9 C41 C42 C43 5(2) . . . . ?
C40 C41 C42 C43 -179.6(15) . . . . ?
C41 C42 C43 C44 -4(3) . . . . ?
C42 C43 C44 C45 1(3) . . . . ?
C43 C44 C45 N9 2(2) . . . . ?
C43 C44 C45 C46 177.9(16) . . . . ?
C41 N9 C45 C44 -1(2) . . . . ?
Pt1 N9 C45 C44 177.5(11) . . . . ?
C41 N9 C45 C46 -177.7(14) . . . . ?
Pt1 N9 C45 C46 0.6(16) . . . . ?
C50 N10 C46 C47 -3(2) . . . . ?
Pt1 N10 C46 C47 178.5(12) . . . . ?
C50 N10 C46 C45 177.4(13) . . . . ?
Pt1 N10 C46 C45 -0.6(18) . . . . ?
C44 C45 C46 N10 -176.3(17) . . . . ?
N9 C45 C46 N10 0(2) . . . . ?
C44 C45 C46 C47 5(3) . . . . ?
N9 C45 C46 C47 -179.1(14) . . . . ?
N10 C46 C47 C48 5(2) . . . . ?
C45 C46 C47 C48 -176.1(14) . . . . ?
C46 C47 C48 C49 -2(2) . . . . ?
C47 C48 C49 C50 -1(2) . . . . ?
C46 N10 C50 C49 0(2) . . . . ?
Pt1 N10 C50 C49 177.7(9) . . . . ?
C48 C49 C50 N10 3(2) . . . . ?
