#------------------------------------------------------------------------------
#$Date: 2025-07-06 19:39:12 +0200 (Sun 06 de Jul de 2025) $
#$Revision: 301072 $
#$URL: svn://www.crystallography.net/cod/cif/7/06/37/7063763.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7063763
loop_
_publ_author_name
'Tolstikov, Svyatoslav E.'
'Kolesnikov, Andrey E.'
'Smirnova, Kristina A.'
'Letyagin, Gleb A.'
'Bogomyakov, Artem S.'
'Romanenko, Galina V.'
'Ovcharenko, Victor I.'
_publ_section_title
;
 Heterospin molecular complexes of Cu(hfac)2 with pyridyl-substituted
 nitronyl nitroxides: peculiarities of structure and magnetic properties
;
_journal_issue                   18
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              7655
_journal_page_last               7660
_journal_paper_doi               10.1039/D5NJ00967G
_journal_volume                  49
_journal_year                    2025
_chemical_formula_sum            'C52 H40 Cu2 F24 N6 O12 S2'
_chemical_formula_weight         1588.10
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2023-12-29 deposited with the CCDC.	2025-04-09 downloaded from the CCDC.
;
_cell_angle_alpha                72.939(3)
_cell_angle_beta                 72.059(3)
_cell_angle_gamma                64.992(3)
_cell_formula_units_Z            1
_cell_length_a                   10.3312(5)
_cell_length_b                   11.2769(6)
_cell_length_c                   15.3209(7)
_cell_measurement_reflns_used    5605
_cell_measurement_temperature    120(2)
_cell_measurement_theta_max      26.56
_cell_measurement_theta_min      2.25
_cell_volume                     1511.14(14)
_computing_cell_refinement       'Bruker SAINT'
_computing_data_collection       'Bruker APEX2'
_computing_data_reduction        'Bruker SAINT'
_computing_molecular_graphics    'Bruker SHELXTL'
_computing_publication_material  'Bruker SHELXTL'
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      120(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.983
_diffrn_measurement_device_type  'Bruker APEX-II CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0848
_diffrn_reflns_av_unetI/netI     0.0883
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.983
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            23784
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.983
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         28.309
_diffrn_reflns_theta_min         1.423
_exptl_absorpt_coefficient_mu    0.913
_exptl_absorpt_correction_T_max  0.5786
_exptl_absorpt_correction_T_min  0.4716
_exptl_absorpt_correction_type   multi-scan
_exptl_crystal_colour            dark_red
_exptl_crystal_density_diffrn    1.745
_exptl_crystal_description       block
_exptl_crystal_F_000             796
_exptl_crystal_size_max          0.45
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.07
_refine_diff_density_max         0.723
_refine_diff_density_min         -1.028
_refine_diff_density_rms         0.099
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.005
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     502
_refine_ls_number_reflns         7401
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.005
_refine_ls_R_factor_all          0.0896
_refine_ls_R_factor_gt           0.0503
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0632P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1134
_refine_ls_wR_factor_ref         0.1331
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4778
_reflns_number_total             7401
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d5nj00967g2.cif
_cod_data_source_block           120s
_cod_depositor_comments
'Adding full bibliography for 7063753--7063771.cif.'
_cod_database_code               7063763
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
; 
The symmetry employed for this shelxl refinement is uniquely defined 
by the following loop, which should always be used as a source of 
symmetry information in preference to the above space-group names. 
They are only intended as comments. 
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Cu1 Cu 0.37964(4) 0.40612(4) 0.70665(3) 0.01905(12) Uani 1 1 d . . . . .
O1L O 0.3204(2) 0.4990(2) 0.80986(15) 0.0252(5) Uani 1 1 d . . . . .
C2L C 0.2669(4) 0.4545(4) 0.8946(2) 0.0293(8) Uani 1 1 d . . . . .
O1R O 0.7380(2) 0.4369(2) 0.37398(14) 0.0191(5) Uani 1 1 d . . . . .
C3L C 0.3013(5) 0.5005(4) 0.9653(3) 0.0375(9) Uani 1 1 d . . . . .
C3R C 0.9592(3) 0.2488(3) 0.3275(2) 0.0207(7) Uani 1 1 d . . . . .
C4R C 1.0140(4) 0.3323(4) 0.2364(2) 0.0320(8) Uani 1 1 d . . . . .
H4RA H 1.119026 0.286719 0.214415 0.048 Uiso 1 1 calc R U . . .
H4RB H 0.995975 0.419787 0.247488 0.048 Uiso 1 1 calc R U . . .
H4RC H 0.961902 0.343898 0.188928 0.048 Uiso 1 1 calc R U . . .
F4L F 0.4373(3) 0.4325(3) 0.9742(2) 0.0739(9) Uani 1 1 d . . . . .
C5R C 1.0262(4) 0.2419(3) 0.4054(2) 0.0258(7) Uani 1 1 d . . . . .
H5RA H 1.132704 0.198924 0.388453 0.039 Uiso 1 1 calc R U . . .
H5RB H 0.988115 0.190181 0.463404 0.039 Uiso 1 1 calc R U . . .
H5RC H 1.000800 0.332312 0.414349 0.039 Uiso 1 1 calc R U . . .
F5L F 0.2826(3) 0.6288(2) 0.94319(15) 0.0513(6) Uani 1 1 d . . . . .
C11R C 0.7306(3) 0.2262(3) 0.3983(2) 0.0179(6) Uani 1 1 d . . . . .
O10R O 0.8032(3) -0.0031(2) 0.41524(16) 0.0280(5) Uani 1 1 d . . . . .
N9R N 0.8280(3) 0.1043(2) 0.38359(17) 0.0189(6) Uani 1 1 d . . . . .
C9L C 0.0889(4) 0.2109(4) 0.9144(2) 0.0327(8) Uani 1 1 d . . . . .
C8R C 1.0970(4) -0.0065(3) 0.3500(2) 0.0292(8) Uani 1 1 d . . . . .
H8RA H 1.091345 -0.089167 0.345863 0.044 Uiso 1 1 calc R U . . .
H8RB H 1.095020 -0.008587 0.414834 0.044 Uiso 1 1 calc R U . . .
H8RC H 1.188146 0.002110 0.309777 0.044 Uiso 1 1 calc R U . . .
C8L C 0.1639(4) 0.3107(3) 0.8681(2) 0.0250(7) Uani 1 1 d . . . . .
C7R C 0.9564(4) 0.1071(4) 0.2220(2) 0.0323(8) Uani 1 1 d . . . . .
H7RA H 1.045010 0.112042 0.175976 0.048 Uiso 1 1 calc R U . . .
H7RB H 0.871134 0.182852 0.203695 0.048 Uiso 1 1 calc R U . . .
H7RC H 0.945539 0.023749 0.224698 0.048 Uiso 1 1 calc R U . . .
C7L C 0.1901(4) 0.3704(4) 0.9273(2) 0.0308(8) Uani 1 1 d . . . . .
H7L H 0.152792 0.351456 0.992679 0.037 Uiso 1 1 calc R U . . .
C6R C 0.9684(3) 0.1110(3) 0.3186(2) 0.0223(7) Uani 1 1 d . . . . .
F6L F 0.2193(4) 0.4825(3) 1.05142(16) 0.0745(9) Uani 1 1 d . . . . .
C12R C 0.5835(3) 0.2503(3) 0.4568(2) 0.0180(6) Uani 1 1 d . . . . .
C13R C 0.5516(3) 0.3025(3) 0.5358(2) 0.0187(6) Uani 1 1 d . . . . .
H13R H 0.621756 0.328869 0.544960 0.022 Uiso 1 1 calc R U . . .
O13L O 0.1937(2) 0.3320(2) 0.78182(15) 0.0250(5) Uani 1 1 d . . . . .
N14R N 0.4266(3) 0.3171(2) 0.59969(17) 0.0170(5) Uani 1 1 d . . . . .
O14L O 0.5020(2) 0.2416(2) 0.78284(15) 0.0254(5) Uani 1 1 d . . . . .
C15R C 0.3278(3) 0.2794(3) 0.5853(2) 0.0200(7) Uani 1 1 d . . . . .
H15R H 0.238905 0.288160 0.630351 0.024 Uiso 1 1 calc R U . . .
C15L C 0.6061(4) 0.2314(3) 0.8149(2) 0.0273(8) Uani 1 1 d . . . . .
C16R C 0.3513(3) 0.2290(3) 0.5079(2) 0.0200(7) Uani 1 1 d . . . . .
H16R H 0.279336 0.202737 0.501184 0.024 Uiso 1 1 calc R U . . .
C16L C 0.6301(4) 0.1236(3) 0.9021(2) 0.0294(8) Uani 1 1 d . . . . .
C17R C 0.4791(3) 0.2159(3) 0.4391(2) 0.0177(6) Uani 1 1 d . . . . .
F17L F 0.5110(3) 0.1400(2) 0.96912(15) 0.0504(6) Uani 1 1 d . . . . .
C18R C 0.5025(3) 0.1744(3) 0.3522(2) 0.0194(7) Uani 1 1 d . . . . .
F18L F 0.6724(2) 0.00146(19) 0.88300(14) 0.0357(5) Uani 1 1 d . . . . .
C19R C 0.5595(4) 0.2275(3) 0.2625(2) 0.0244(7) Uani 1 1 d . . . . .
H19R H 0.593736 0.298542 0.247959 0.029 Uiso 1 1 calc R U . . .
F19L F 0.7337(3) 0.1182(3) 0.93987(17) 0.0584(7) Uani 1 1 d . . . . .
C20R C 0.5609(4) 0.1644(4) 0.1954(3) 0.0372(9) Uani 1 1 d . . . . .
H20R H 0.596121 0.188926 0.130313 0.045 Uiso 1 1 calc R U . . .
C20L C 0.7005(4) 0.2989(3) 0.7805(2) 0.0300(8) Uani 1 1 d . . . . .
H20L H 0.775884 0.276934 0.812223 0.036 Uiso 1 1 calc R U . . .
C21R C 0.5081(4) 0.0666(4) 0.2316(3) 0.0341(9) Uani 1 1 d . . . . .
H21R H 0.503206 0.013356 0.195712 0.041 Uiso 1 1 calc R U . . .
C21L C 0.6894(4) 0.4001(3) 0.6994(2) 0.0282(8) Uani 1 1 d . . . . .
S22R S 0.45054(9) 0.04852(8) 0.35013(6) 0.0269(2) Uani 1 1 d . . . . .
O26L O 0.5917(2) 0.4534(2) 0.65429(15) 0.0257(5) Uani 1 1 d . . . . .
C22L C 0.8176(4) 0.4483(4) 0.6610(3) 0.0399(10) Uani 1 1 d . . . . .
N2R N 0.7964(3) 0.3144(2) 0.36132(17) 0.0174(5) Uani 1 1 d . . . . .
F23L F 0.9396(13) 0.3708(14) 0.6866(8) 0.058(3) Uani 0.60(2) 1 d . . P A 1
F13L F -0.039(3) 0.267(4) 0.8829(16) 0.073(7) Uani 0.41(5) 1 d . . P B 1
F12L F 0.053(3) 0.184(3) 1.0056(14) 0.050(5) Uani 0.41(5) 1 d . . P B 1
F11L F 0.158(4) 0.096(2) 0.885(2) 0.094(8) Uani 0.41(5) 1 d . . P B 1
F24L F 0.8519(12) 0.4660(11) 0.5653(6) 0.050(2) Uani 0.60(2) 1 d . . P A 1
F25L F 0.7782(8) 0.5687(5) 0.6773(6) 0.047(2) Uani 0.60(2) 1 d . . P A 1
F23A F 0.938(3) 0.347(3) 0.672(2) 0.132(11) Uani 0.40(2) 1 d . . P A 2
F13B F -0.013(2) 0.224(2) 0.8780(13) 0.078(5) Uani 0.59(5) 1 d . . P B 2
F12B F 0.033(2) 0.210(2) 1.0032(11) 0.064(4) Uani 0.59(5) 1 d . . P B 2
F11B F 0.1918(17) 0.0922(12) 0.9115(17) 0.082(5) Uani 0.59(5) 1 d . . P B 2
F24A F 0.825(2) 0.516(3) 0.5872(19) 0.118(10) Uani 0.40(2) 1 d . . P A 2
F25A F 0.825(2) 0.507(4) 0.727(2) 0.147(12) Uani 0.40(2) 1 d . . P A 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
O1L Cu1 O1R 93.98(9) . 2_666 ?
O1L Cu1 N14R 176.18(10) . . ?
O1R Cu1 N14R 83.10(9) 2_666 . ?
O1L Cu1 O14L 89.08(9) . . ?
O1R Cu1 O14L 176.94(9) 2_666 . ?
N14R Cu1 O14L 93.83(9) . . ?
O1L Cu1 O13L 86.12(9) . . ?
O1R Cu1 O13L 94.77(8) 2_666 . ?
N14R Cu1 O13L 91.66(9) . . ?
O14L Cu1 O13L 85.33(8) . . ?
O1L Cu1 O26L 90.00(8) . . ?
O1R Cu1 O26L 96.29(8) 2_666 . ?
N14R Cu1 O26L 92.77(9) . . ?
O14L Cu1 O26L 83.80(8) . . ?
O13L Cu1 O26L 168.50(8) . . ?
C2L O1L Cu1 124.0(2) . . ?
O1L C2L C7L 129.2(3) . . ?
O1L C2L C3L 112.7(3) . . ?
C7L C2L C3L 118.1(3) . . ?
N2R O1R Cu1 126.40(17) . 2_666 ?
F4L C3L F5L 107.5(3) . . ?
F4L C3L F6L 105.5(3) . . ?
F5L C3L F6L 105.9(3) . . ?
F4L C3L C2L 110.7(3) . . ?
F5L C3L C2L 113.3(3) . . ?
F6L C3L C2L 113.3(3) . . ?
N2R C3R C5R 104.9(2) . . ?
N2R C3R C4R 110.7(2) . . ?
C5R C3R C4R 110.5(3) . . ?
N2R C3R C6R 100.4(2) . . ?
C5R C3R C6R 114.0(3) . . ?
C4R C3R C6R 115.3(3) . . ?
N2R C11R N9R 109.0(3) . . ?
N2R C11R C12R 126.6(3) . . ?
N9R C11R C12R 123.9(3) . . ?
O10R N9R C11R 125.0(3) . . ?
O10R N9R C6R 123.0(2) . . ?
C11R N9R C6R 111.9(3) . . ?
F13B C9L F12B 106.5(11) . . ?
F13B C9L F11B 110.5(11) . . ?
F12B C9L F11B 104.2(12) . . ?
F12L C9L F11L 107.7(16) . . ?
F12L C9L F13L 106.9(13) . . ?
F11L C9L F13L 104.2(15) . . ?
F13B C9L C8L 115.0(7) . . ?
F12B C9L C8L 113.7(9) . . ?
F12L C9L C8L 118.9(9) . . ?
F11B C9L C8L 106.4(8) . . ?
F11L C9L C8L 113.8(11) . . ?
F13L C9L C8L 104.0(14) . . ?
O13L C8L C7L 127.2(3) . . ?
O13L C8L C9L 115.4(3) . . ?
C7L C8L C9L 117.3(3) . . ?
C2L C7L C8L 123.1(3) . . ?
N9R C6R C8R 110.2(3) . . ?
N9R C6R C7R 105.5(3) . . ?
C8R C6R C7R 110.9(3) . . ?
N9R C6R C3R 100.7(2) . . ?
C8R C6R C3R 114.7(3) . . ?
C7R C6R C3R 114.0(3) . . ?
C13R C12R C17R 119.9(3) . . ?
C13R C12R C11R 117.0(3) . . ?
C17R C12R C11R 123.0(3) . . ?
N14R C13R C12R 122.9(3) . . ?
C8L O13L Cu1 118.2(2) . . ?
C13R N14R C15R 117.7(3) . . ?
C13R N14R Cu1 121.1(2) . . ?
C15R N14R Cu1 120.9(2) . . ?
C15L O14L Cu1 126.4(2) . . ?
N14R C15R C16R 122.4(3) . . ?
O14L C15L C20L 129.4(3) . . ?
O14L C15L C16L 113.2(3) . . ?
C20L C15L C16L 117.3(3) . . ?
C15R C16R C17R 121.0(3) . . ?
F17L C16L F19L 106.0(3) . . ?
F17L C16L F18L 107.1(3) . . ?
F19L C16L F18L 106.0(3) . . ?
F17L C16L C15L 112.6(3) . . ?
F19L C16L C15L 113.5(3) . . ?
F18L C16L C15L 111.2(3) . . ?
C16R C17R C12R 115.9(3) . . ?
C16R C17R C18R 122.7(3) . . ?
C12R C17R C18R 121.3(3) . . ?
C19R C18R C17R 128.3(3) . . ?
C19R C18R S22R 110.2(2) . . ?
C17R C18R S22R 121.5(2) . . ?
C18R C19R C20R 112.2(3) . . ?
C21R C20R C19R 113.7(3) . . ?
C15L C20L C21L 122.2(3) . . ?
C20R C21R S22R 112.0(3) . . ?
O26L C21L C20L 129.1(3) . . ?
O26L C21L C22L 115.4(3) . . ?
C20L C21L C22L 115.5(3) . . ?
C21R S22R C18R 91.82(17) . . ?
C21L O26L Cu1 120.9(2) . . ?
F24A C22L F23A 114.0(17) . . ?
F23L C22L F25L 110.1(8) . . ?
F23L C22L F24L 104.8(8) . . ?
F25L C22L F24L 103.7(5) . . ?
F24A C22L F25A 110.8(12) . . ?
F23A C22L F25A 93.1(15) . . ?
F24A C22L C21L 118.5(10) . . ?
F23L C22L C21L 117.3(5) . . ?
F23A C22L C21L 108.6(11) . . ?
F25L C22L C21L 110.3(4) . . ?
F24L C22L C21L 109.6(6) . . ?
F25A C22L C21L 108.9(8) . . ?
O1R N2R C11R 124.1(2) . . ?
O1R N2R C3R 121.4(2) . . ?
C11R N2R C3R 112.4(2) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Cu1 O1L 1.951(2) . ?
Cu1 O1R 1.990(2) 2_666 ?
Cu1 N14R 1.998(2) . ?
Cu1 O14L 2.014(2) . ?
Cu1 O13L 2.268(2) . ?
Cu1 O26L 2.319(2) . ?
O1L C2L 1.285(4) . ?
C2L C7L 1.376(5) . ?
C2L C3L 1.514(5) . ?
O1R N2R 1.300(3) . ?
C3L F4L 1.314(5) . ?
C3L F5L 1.328(4) . ?
C3L F6L 1.342(4) . ?
C3R N2R 1.511(4) . ?
C3R C5R 1.522(4) . ?
C3R C4R 1.532(4) . ?
C3R C6R 1.560(4) . ?
C11R N2R 1.333(4) . ?
C11R N9R 1.351(4) . ?
C11R C12R 1.464(4) . ?
O10R N9R 1.268(3) . ?
N9R C6R 1.503(4) . ?
C9L F13B 1.270(16) . ?
C9L F12B 1.302(16) . ?
C9L F12L 1.31(2) . ?
C9L F11B 1.314(13) . ?
C9L F11L 1.32(2) . ?
C9L F13L 1.37(3) . ?
C9L C8L 1.517(5) . ?
C8R C6R 1.512(4) . ?
C8L O13L 1.235(4) . ?
C8L C7L 1.420(5) . ?
C7R C6R 1.538(4) . ?
C12R C13R 1.389(4) . ?
C12R C17R 1.408(4) . ?
C13R N14R 1.337(4) . ?
N14R C15R 1.353(4) . ?
O14L C15L 1.264(4) . ?
C15R C16R 1.374(4) . ?
C15L C20L 1.373(5) . ?
C15L C16L 1.522(5) . ?
C16R C17R 1.395(4) . ?
C16L F17L 1.320(4) . ?
C16L F19L 1.338(4) . ?
C16L F18L 1.350(4) . ?
C17R C18R 1.457(4) . ?
C18R C19R 1.381(4) . ?
C18R S22R 1.728(3) . ?
C19R C20R 1.407(5) . ?
C20R C21R 1.336(5) . ?
C20L C21L 1.416(5) . ?
C21R S22R 1.706(4) . ?
C21L O26L 1.238(4) . ?
C21L C22L 1.528(5) . ?
C22L F24A 1.166(19) . ?
C22L F23L 1.296(12) . ?
C22L F23A 1.30(3) . ?
C22L F25L 1.319(7) . ?
C22L F24L 1.371(10) . ?
C22L F25A 1.391(16) . ?
