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#$Date: 2026-04-05 05:10:31 +0200 (Sun 05 de Apr de 2026) $
#$Revision: 305271 $
#$URL: svn://www.crystallography.net/cod/cif/7/06/43/7064367.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7064367
loop_
_publ_author_name
'Sharma, Sahil'
'Pandey, Pradeep Kumar'
'Trivedi, Manoj'
'Rath, Nigam P.'
'Sharma, Raj Kishore'
_publ_section_title
;
 Catalytic hydrogenation of carbon dioxide to methanol by homogenous
 ruthenium(ii) hydrido carbonyl complexes
;
_journal_issue                   13
_journal_name_full               'New Journal of Chemistry'
_journal_page_first              5679
_journal_page_last               5686
_journal_paper_doi               10.1039/D6NJ00102E
_journal_volume                  50
_journal_year                    2026
_chemical_formula_moiety         'C41 H37 F6 N2 O P3 Ru'
_chemical_formula_sum            'C41 H37 F6 N2 O P3 Ru'
_chemical_formula_weight         881.71
_space_group_crystal_system      monoclinic
_space_group_IT_number           11
_space_group_name_Hall           '-P 2yb'
_space_group_name_H-M_alt        'P 1 21/m 1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2018/3
_audit_update_record
;
2026-02-28 deposited with the CCDC.	2026-03-04 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 110.918(14)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   9.2610(11)
_cell_length_b                   22.228(2)
_cell_length_c                   10.4259(13)
_cell_measurement_reflns_used    813
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      32.6223
_cell_measurement_theta_min      3.3184
_cell_volume                     2004.8(4)
_computing_cell_refinement
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.34.44 (release 25-10-2010 CrysAlis171 .NET)
(compiled Oct 25 2010,18:11:34)
;
_computing_data_collection
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.34.44 (release 25-10-2010 CrysAlis171 .NET)
(compiled Oct 25 2010,18:11:34)
;
_computing_data_reduction
;
CrysAlisPro, Oxford Diffraction Ltd.,
Version 1.171.34.44 (release 25-10-2010 CrysAlis171 .NET)
(compiled Oct 25 2010,18:11:34)
;
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_computing_structure_solution    'SHELXT 2018/2 (Sheldrick, 2018)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 15.9948
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Xcalibur, Sapphire3'
_diffrn_measurement_method       ω/2θ
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0976
_diffrn_reflns_av_unetI/netI     0.0482
_diffrn_reflns_Laue_measured_fraction_full 0.996
_diffrn_reflns_Laue_measured_fraction_max 0.996
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       28
_diffrn_reflns_limit_k_min       -28
_diffrn_reflns_limit_l_max       13
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            29409
_diffrn_reflns_point_group_measured_fraction_full 0.996
_diffrn_reflns_point_group_measured_fraction_max 0.996
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         27.498
_diffrn_reflns_theta_min         2.984
_diffrn_source                   'fine-focus sealed tube'
_exptl_absorpt_coefficient_mu    0.573
_exptl_absorpt_correction_T_max  0.8013
_exptl_absorpt_correction_T_min  0.7317
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro, Agilent Technologies,
Version 1.171.34.49 (release 20-01-2011 CrysAlis171 .NET)
(compiled Jan 20 2011,15:58:25)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour            Yellow
_exptl_crystal_density_diffrn    1.461
_exptl_crystal_description       Block
_exptl_crystal_F_000             896
_exptl_crystal_size_max          0.23
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.16
_refine_diff_density_max         1.754
_refine_diff_density_min         -1.106
_refine_diff_density_rms         0.118
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.228
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     264
_refine_ls_number_reflns         4711
_refine_ls_number_restraints     94
_refine_ls_restrained_S_all      1.255
_refine_ls_R_factor_all          0.0774
_refine_ls_R_factor_gt           0.0736
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0734P)²+5.2565P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1855
_refine_ls_wR_factor_ref         0.1882
_reflns_Friedel_coverage         0.000
_reflns_number_gt                4439
_reflns_number_total             4711
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d6nj00102e2.cif
_cod_data_source_block           Complex_2
_cod_original_sg_symbol_H-M      'P 21/m'
_cod_database_code               7064367
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_exptl_absorpt_special_details
;
 ?
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z'
'-x, -y, -z'
'x, -y-1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ru1 Ru 0.65323(6) 0.750000 0.53613(5) 0.02804(18) Uani 1 2 d S T P . .
H1 H 0.467258 0.750000 0.469472 0.042 Uiso 1 2 d R U P . .
P1 P 0.61943(13) 0.64465(5) 0.52603(12) 0.0303(3) Uani 1 1 d . . . . .
O1 O 0.5716(8) 0.750000 0.7876(7) 0.0666(18) Uani 1 2 d S T P . .
N1 N 0.9032(7) 0.750000 0.6187(7) 0.0395(13) Uani 1 2 d S T P . .
N2 N 0.6534(9) 0.750000 0.3362(7) 0.0497(16) Uani 1 2 d S T P . .
C1 C 0.6125(9) 0.750000 0.6971(7) 0.0399(15) Uani 1 2 d S T P . .
C6 C 0.7668(5) 0.5981(2) 0.6465(5) 0.0355(10) Uani 1 1 d . . . . .
C13 C 0.4423(7) 0.5826(2) 0.6567(6) 0.0470(12) Uani 1 1 d . . . . .
H13 H 0.533338 0.563298 0.709317 0.056 Uiso 1 1 calc R U . . .
C11 C 0.7885(6) 0.5380(2) 0.6186(6) 0.0465(12) Uani 1 1 d . . . . .
H11 H 0.728019 0.521243 0.534923 0.056 Uiso 1 1 calc R U . . .
C7 C 0.8579(6) 0.6217(2) 0.7729(5) 0.0436(11) Uani 1 1 d . . . . .
H7 H 0.844730 0.661535 0.793923 0.052 Uiso 1 1 calc R U . . .
C19 C 0.4634(7) 0.5902(3) 0.2667(7) 0.0598(16) Uani 1 1 d . . . . .
H19 H 0.375810 0.588018 0.290482 0.072 Uiso 1 1 calc R U . . .
C10 C 0.8992(7) 0.5034(3) 0.7142(7) 0.0561(15) Uani 1 1 d . . . . .
H10 H 0.913073 0.463398 0.694991 0.067 Uiso 1 1 calc R U . . .
C17 C 0.3060(6) 0.6510(3) 0.4771(6) 0.0475(12) Uani 1 1 d . . . . .
H17 H 0.304618 0.678154 0.408787 0.057 Uiso 1 1 calc R U . . .
C2 C 1.0308(9) 0.750000 0.6752(9) 0.0508(19) Uani 1 2 d S T P . .
C22 C 0.7178(8) 0.5957(3) 0.1906(7) 0.0608(16) Uani 1 1 d . . . . .
H22 H 0.804584 0.597361 0.165617 0.073 Uiso 1 1 calc R U . . .
C21 C 0.5823(10) 0.5754(3) 0.0999(7) 0.072(2) Uani 1 1 d . . . . .
H21 H 0.574561 0.563931 0.011932 0.087 Uiso 1 1 calc R U . . .
C4 C 0.6247(14) 0.750000 0.2217(9) 0.066(3) Uani 1 2 d S T P . .
C8 C 0.9673(7) 0.5867(3) 0.8670(6) 0.0558(14) Uani 1 1 d . . . . .
H8 H 1.027566 0.602897 0.951450 0.067 Uiso 1 1 calc R U . . .
C20 C 0.4562(9) 0.5720(4) 0.1395(8) 0.081(2) Uani 1 1 d . . . . .
H20 H 0.363666 0.556791 0.078221 0.097 Uiso 1 1 calc R U . . .
C16 C 0.1710(7) 0.6378(3) 0.5005(8) 0.0611(17) Uani 1 1 d . . . . .
H16 H 0.078604 0.656098 0.447368 0.073 Uiso 1 1 calc R U . . .
C3 C 1.1973(11) 0.750000 0.7547(15) 0.087(4) Uani 1 2 d S T P . .
H3A H 1.252703 0.738747 0.696222 0.131 Uiso 0.5 1 calc R U P A -1
H3B H 1.219299 0.721737 0.828897 0.131 Uiso 0.5 1 calc R U P A -1
H3C H 1.228812 0.789517 0.791114 0.131 Uiso 0.5 1 calc R U P A -1
C9 C 0.9882(8) 0.5280(3) 0.8370(7) 0.0579(15) Uani 1 1 d . . . . .
H9 H 1.063519 0.504777 0.900821 0.069 Uiso 1 1 calc R U . . .
C14 C 0.3064(8) 0.5704(3) 0.6792(7) 0.0621(17) Uani 1 1 d . . . . .
H14 H 0.307165 0.543325 0.747415 0.075 Uiso 1 1 calc R U . . .
C15 C 0.1733(7) 0.5975(3) 0.6030(9) 0.0682(19) Uani 1 1 d . . . . .
H15 H 0.082762 0.589259 0.619126 0.082 Uiso 1 1 calc R U . . .
C5 C 0.582(2) 0.750000 0.0751(11) 0.115(6) Uani 1 2 d S T P . .
H5A H 0.563361 0.790552 0.041516 0.172 Uiso 0.5 1 calc R U P B -1
H5B H 0.489858 0.726538 0.034437 0.172 Uiso 0.5 1 calc R U P B -1
H5C H 0.664265 0.732909 0.051233 0.172 Uiso 0.5 1 calc R U P B -1
C18 C 0.5997(5) 0.6120(2) 0.3598(5) 0.0340(9) Uani 1 1 d . . . . .
C12 C 0.4434(5) 0.6231(2) 0.5567(5) 0.0363(10) Uani 1 1 d . . . . .
C23 C 0.7281(7) 0.6141(3) 0.3202(6) 0.0496(13) Uani 1 1 d . . . . .
H23 H 0.821966 0.628131 0.381620 0.059 Uiso 1 1 calc R U . . .
P2 P 0.9430(5) 0.250000 0.8867(4) 0.1059(13) Uani 1 2 d DS TU P . .
F1 F 1.000(2) 0.250000 1.0335(9) 0.229(7) Uani 1 2 d DS TU P . .
F2 F 0.913(3) 0.250000 0.7378(11) 0.283(9) Uani 1 2 d DS TU P . .
F3 F 1.0388(18) 0.3033(5) 0.8905(13) 0.268(6) Uani 1 1 d D U . . .
F4 F 0.8214(16) 0.2933(6) 0.8758(18) 0.337(8) Uani 1 1 d D U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
C1 Ru1 N2 169.0(3) . . ?
C1 Ru1 N1 100.1(3) . . ?
N2 Ru1 N1 90.9(3) . . ?
C1 Ru1 P1 88.49(4) . . ?
N2 Ru1 P1 90.16(4) . . ?
N1 Ru1 P1 97.12(3) . . ?
C1 Ru1 P1 88.49(4) . 4_575 ?
N2 Ru1 P1 90.16(4) . 4_575 ?
N1 Ru1 P1 97.11(3) . 4_575 ?
P1 Ru1 P1 165.76(6) . 4_575 ?
C1 Ru1 H1 81.9 . . ?
N2 Ru1 H1 87.2 . . ?
N1 Ru1 H1 178.0 . . ?
P1 Ru1 H1 82.9 . . ?
P1 Ru1 H1 82.9 4_575 . ?
C6 P1 C18 103.0(2) . . ?
C6 P1 C12 103.1(2) . . ?
C18 P1 C12 105.5(2) . . ?
C6 P1 Ru1 118.69(16) . . ?
C18 P1 Ru1 113.80(15) . . ?
C12 P1 Ru1 111.29(16) . . ?
C2 N1 Ru1 172.2(7) . . ?
C4 N2 Ru1 167.2(9) . . ?
O1 C1 Ru1 172.8(8) . . ?
C7 C6 C11 118.4(5) . . ?
C7 C6 P1 119.6(4) . . ?
C11 C6 P1 122.0(4) . . ?
C12 C13 C14 120.4(6) . . ?
C12 C13 H13 119.8 . . ?
C14 C13 H13 119.8 . . ?
C10 C11 C6 120.5(6) . . ?
C10 C11 H11 119.7 . . ?
C6 C11 H11 119.7 . . ?
C8 C7 C6 120.5(5) . . ?
C8 C7 H7 119.8 . . ?
C6 C7 H7 119.8 . . ?
C20 C19 C18 120.2(6) . . ?
C20 C19 H19 119.9 . . ?
C18 C19 H19 119.9 . . ?
C9 C10 C11 119.8(6) . . ?
C9 C10 H10 120.1 . . ?
C11 C10 H10 120.1 . . ?
C16 C17 C12 119.4(6) . . ?
C16 C17 H17 120.3 . . ?
C12 C17 H17 120.3 . . ?
N1 C2 C3 177.7(11) . . ?
C21 C22 C23 120.4(6) . . ?
C21 C22 H22 119.8 . . ?
C23 C22 H22 119.8 . . ?
C22 C21 C20 119.1(6) . . ?
C22 C21 H21 120.5 . . ?
C20 C21 H21 120.5 . . ?
N2 C4 C5 177.8(15) . . ?
C9 C8 C7 120.3(6) . . ?
C9 C8 H8 119.9 . . ?
C7 C8 H8 119.9 . . ?
C19 C20 C21 121.6(7) . . ?
C19 C20 H20 119.2 . . ?
C21 C20 H20 119.2 . . ?
C17 C16 C15 120.3(6) . . ?
C17 C16 H16 119.9 . . ?
C15 C16 H16 119.9 . . ?
C2 C3 H3A 109.5 . . ?
C2 C3 H3B 109.5 . . ?
H3A C3 H3B 109.5 . . ?
C2 C3 H3C 109.5 . . ?
H3A C3 H3C 109.5 . . ?
H3B C3 H3C 109.5 . . ?
C10 C9 C8 120.6(5) . . ?
C10 C9 H9 119.7 . . ?
C8 C9 H9 119.7 . . ?
C15 C14 C13 120.5(6) . . ?
C15 C14 H14 119.7 . . ?
C13 C14 H14 119.7 . . ?
C14 C15 C16 120.1(5) . . ?
C14 C15 H15 120.0 . . ?
C16 C15 H15 120.0 . . ?
C4 C5 H5A 109.5 . . ?
C4 C5 H5B 109.5 . . ?
H5A C5 H5B 109.5 . . ?
C4 C5 H5C 109.5 . . ?
H5A C5 H5C 109.5 . . ?
H5B C5 H5C 109.5 . . ?
C19 C18 C23 117.9(5) . . ?
C19 C18 P1 124.3(4) . . ?
C23 C18 P1 117.5(4) . . ?
C13 C12 C17 119.3(5) . . ?
C13 C12 P1 123.2(4) . . ?
C17 C12 P1 117.4(4) . . ?
C22 C23 C18 120.8(6) . . ?
C22 C23 H23 119.6 . . ?
C18 C23 H23 119.6 . . ?
F1 P2 F4 93.8(9) . 4_565 ?
F1 P2 F4 93.8(9) . . ?
F4 P2 F4 82.9(14) 4_565 . ?
F1 P2 F3 88.9(7) . 4_565 ?
F4 P2 F3 84.9(8) 4_565 4_565 ?
F4 P2 F3 167.7(11) . 4_565 ?
F1 P2 F3 88.9(7) . . ?
F4 P2 F3 167.7(11) 4_565 . ?
F4 P2 F3 84.9(8) . . ?
F3 P2 F3 107.2(13) 4_565 . ?
F1 P2 F2 169.9(12) . . ?
F4 P2 F2 93.8(8) 4_565 . ?
F4 P2 F2 93.8(8) . . ?
F3 P2 F2 85.1(7) 4_565 . ?
F3 P2 F2 85.1(7) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ru1 C1 1.847(7) . ?
Ru1 N2 2.085(6) . ?
Ru1 N1 2.163(6) . ?
Ru1 P1 2.3599(12) . ?
Ru1 P1 2.3600(12) 4_575 ?
Ru1 H1 1.6108 . ?
P1 C6 1.813(5) . ?
P1 C18 1.827(5) . ?
P1 C12 1.833(5) . ?
O1 C1 1.135(9) . ?
N1 C2 1.116(10) . ?
N2 C4 1.126(11) . ?
C6 C7 1.389(7) . ?
C6 C11 1.396(7) . ?
C13 C12 1.381(7) . ?
C13 C14 1.387(8) . ?
C13 H13 0.9300 . ?
C11 C10 1.382(8) . ?
C11 H11 0.9300 . ?
C7 C8 1.373(8) . ?
C7 H7 0.9300 . ?
C19 C20 1.366(9) . ?
C19 C18 1.377(7) . ?
C19 H19 0.9300 . ?
C10 C9 1.365(9) . ?
C10 H10 0.9300 . ?
C17 C16 1.388(7) . ?
C17 C12 1.392(7) . ?
C17 H17 0.9300 . ?
C2 C3 1.467(12) . ?
C22 C21 1.351(10) . ?
C22 C23 1.382(8) . ?
C22 H22 0.9300 . ?
C21 C20 1.372(11) . ?
C21 H21 0.9300 . ?
C4 C5 1.436(12) . ?
C8 C9 1.372(9) . ?
C8 H8 0.9300 . ?
C20 H20 0.9300 . ?
C16 C15 1.389(10) . ?
C16 H16 0.9300 . ?
C3 H3A 0.9600 . ?
C3 H3B 0.9600 . ?
C3 H3C 0.9600 . ?
C9 H9 0.9300 . ?
C14 C15 1.347(10) . ?
C14 H14 0.9300 . ?
C15 H15 0.9300 . ?
C5 H5A 0.9600 . ?
C5 H5B 0.9600 . ?
C5 H5C 0.9600 . ?
C18 C23 1.392(7) . ?
C23 H23 0.9300 . ?
P2 F1 1.429(9) . ?
P2 F4 1.455(9) 4_565 ?
P2 F4 1.455(9) . ?
P2 F3 1.472(8) 4_565 ?
P2 F3 1.472(8) . ?
P2 F2 1.476(11) . ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_site_symmetry_A
_geom_hbond_publ_flag
C17 H17 F2 0.93 2.60 3.274(13) 130.2 3_666 yes
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
C18 P1 C6 C7 153.7(4) . . . . ?
C12 P1 C6 C7 -96.6(4) . . . . ?
Ru1 P1 C6 C7 26.9(5) . . . . ?
C18 P1 C6 C11 -28.7(5) . . . . ?
C12 P1 C6 C11 80.9(5) . . . . ?
Ru1 P1 C6 C11 -155.5(4) . . . . ?
C7 C6 C11 C10 -0.7(8) . . . . ?
P1 C6 C11 C10 -178.3(4) . . . . ?
C11 C6 C7 C8 0.6(8) . . . . ?
P1 C6 C7 C8 178.2(4) . . . . ?
C6 C11 C10 C9 0.0(9) . . . . ?
C23 C22 C21 C20 -1.5(11) . . . . ?
C6 C7 C8 C9 0.2(9) . . . . ?
C18 C19 C20 C21 -1.0(13) . . . . ?
C22 C21 C20 C19 2.0(13) . . . . ?
C12 C17 C16 C15 0.4(10) . . . . ?
C11 C10 C9 C8 0.8(10) . . . . ?
C7 C8 C9 C10 -0.9(10) . . . . ?
C12 C13 C14 C15 0.6(10) . . . . ?
C13 C14 C15 C16 0.3(12) . . . . ?
C17 C16 C15 C14 -0.8(12) . . . . ?
C20 C19 C18 C23 -0.4(10) . . . . ?
C20 C19 C18 P1 173.6(6) . . . . ?
C6 P1 C18 C19 122.8(5) . . . . ?
C12 P1 C18 C19 14.9(5) . . . . ?
Ru1 P1 C18 C19 -107.4(5) . . . . ?
C6 P1 C18 C23 -63.1(4) . . . . ?
C12 P1 C18 C23 -171.0(4) . . . . ?
Ru1 P1 C18 C23 66.7(4) . . . . ?
C14 C13 C12 C17 -1.0(9) . . . . ?
C14 C13 C12 P1 176.8(5) . . . . ?
C16 C17 C12 C13 0.5(9) . . . . ?
C16 C17 C12 P1 -177.5(5) . . . . ?
C6 P1 C12 C13 2.9(5) . . . . ?
C18 P1 C12 C13 110.7(5) . . . . ?
Ru1 P1 C12 C13 -125.4(4) . . . . ?
C6 P1 C12 C17 -179.2(4) . . . . ?
C18 P1 C12 C17 -71.4(4) . . . . ?
Ru1 P1 C12 C17 52.5(4) . . . . ?
C21 C22 C23 C18 0.1(10) . . . . ?
C19 C18 C23 C22 0.8(9) . . . . ?
P1 C18 C23 C22 -173.6(5) . . . . ?
