#------------------------------------------------------------------------------
#$Date: 2019-11-24 01:31:56 +0100 (Sun 24 de Nov de 2019) $
#$Revision: 236275 $
#$URL: svn://www.crystallography.net/cod/cif/7/23/65/7236526.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7236526
loop_
_publ_author_name
'Wang, Lu'
'Fan, Guilan'
'Xu, Xiufang'
'Chen, Diming'
'Wang, Liang'
'Shi, Wei'
'Cheng, Peng'
_publ_section_title
;
 Detection of polychlorinated benzenes (persistent organic pollutants) by
 a luminescent sensor based on a lanthanide metal--organic framework
;
_journal_issue                   11
_journal_name_full               'Journal of Materials Chemistry A'
_journal_page_first              5541
_journal_paper_doi               10.1039/C7TA00256D
_journal_volume                  5
_journal_year                    2017
_chemical_formula_moiety         '0.25(C144 H116 Eu8 N44 O56), 2(O)'
_chemical_formula_sum            'C36 H29 Eu2 N11 O16'
_chemical_formula_weight         1175.62
_space_group_crystal_system      monoclinic
_space_group_IT_number           15
_space_group_name_Hall           '-I 2ya'
_space_group_name_H-M_alt        'I 1 2/a 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_audit_creation_date             2016-06-20
_audit_creation_method
;
Olex2 1.2
(compiled 2016.02.19 svn.r3266 for OlexSys, GUI svn.r5155)
;
_audit_update_record
;
2016-09-19 deposited with the CCDC.
2017-02-10 downloaded from the CCDC.
;
_cell_angle_alpha                90
_cell_angle_beta                 114.512(4)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   17.4164(6)
_cell_length_b                   14.2453(4)
_cell_length_c                   20.4424(7)
_cell_measurement_reflns_used    3839
_cell_measurement_temperature    122.35(10)
_cell_measurement_theta_max      28.8160
_cell_measurement_theta_min      3.2870
_cell_volume                     4614.7(3)
_computing_cell_refinement
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
(compiled Aug  2 2013,16:46:58)
;
_computing_data_collection
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
(compiled Aug  2 2013,16:46:58)
;
_computing_data_reduction
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
(compiled Aug  2 2013,16:46:58)
;
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXS (Sheldrick, 2008)'
_diffrn_ambient_temperature      122.35(10)
_diffrn_detector_area_resol_mean 16.2116
_diffrn_measured_fraction_theta_full 0.977
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_details
;
#__ type_ start__ end____ width___ exp.time_
  1 omega   41.00   78.00   1.0000   14.0000
omega____ theta____ kappa____ phi______ frames
    -       18.3497  178.0000   60.0000 37

#__ type_ start__ end____ width___ exp.time_
  2 omega  -46.00   44.00   1.0000   14.0000
omega____ theta____ kappa____ phi______ frames
    -       18.3497  -37.0000   30.0000 90

#__ type_ start__ end____ width___ exp.time_
  3 omega  -17.00   14.00   1.0000   14.0000
omega____ theta____ kappa____ phi______ frames
    -       18.3497  -99.0000  -60.0000 31

#__ type_ start__ end____ width___ exp.time_
  4 omega  -30.00   51.00   1.0000   14.0000
omega____ theta____ kappa____ phi______ frames
    -      -18.5841   37.0000 -150.0000 81
;
_diffrn_measurement_device_type  'SuperNova, Single source at offset, Eos'
_diffrn_measurement_method       'ω scans'
_diffrn_orient_matrix_UB_11      -0.0120185000
_diffrn_orient_matrix_UB_12      -0.0299894000
_diffrn_orient_matrix_UB_13      -0.0302886000
_diffrn_orient_matrix_UB_21      -0.0393484000
_diffrn_orient_matrix_UB_22      -0.0082521000
_diffrn_orient_matrix_UB_23      0.0016327000
_diffrn_orient_matrix_UB_31      -0.0176968000
_diffrn_orient_matrix_UB_32      0.0388702000
_diffrn_orient_matrix_UB_33      -0.0230849000
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0389
_diffrn_reflns_av_unetI/netI     0.0573
_diffrn_reflns_Laue_measured_fraction_full 0.977
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            9331
_diffrn_reflns_point_group_measured_fraction_full 0.977
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         25.009
_diffrn_reflns_theta_min         3.141
_diffrn_source                   'SuperNova (Mo) X-ray Source'
_exptl_absorpt_coefficient_mu    2.771
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.66702
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.32 (release 02-08-2013 CrysAlis171 .NET)
(compiled Aug  2 2013,16:46:58)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_density_diffrn    1.692
_exptl_crystal_F_000             2304
_refine_diff_density_max         2.189
_refine_diff_density_min         -1.409
_refine_diff_density_rms         0.179
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.003
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     297
_refine_ls_number_reflns         4063
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.003
_refine_ls_R_factor_all          0.0505
_refine_ls_R_factor_gt           0.0412
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.1000P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1313
_refine_ls_wR_factor_ref         0.1417
_reflns_Friedel_coverage         0.000
_reflns_number_gt                3449
_reflns_number_total             4063
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            c7ta00256d2.cif
_cod_data_source_block           p150326e
_cod_database_code               7236526
_shelxl_version_number           2013-4
_chemical_oxdiff_formula         'C EU'
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_reflns_odcompleteness_completeness 99.80
_reflns_odcompleteness_iscentric 1
_reflns_odcompleteness_theta     26.32
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C4(H4), C13(H13), C15(H15), C16(H16), C20(H20), C21(H21), C23(H23), C25(H25),
 C38(H38)
2.b Idealised Me refined as rotating group:
 C27(H27a,H27b,H27c), C37(H37a,H37b,H37c)
;
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x+1/2, y, -z'
'x+1/2, y+1/2, z+1/2'
'-x+1, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y, z'
'-x+1/2, -y+1/2, -z+1/2'
'x, -y+1/2, z+1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
Eu1 Eu 0.20785(2) 0.88692(2) 0.20392(2) 0.00767(16) Uani 1 1 d . . .
C3 C 0.1429(4) 1.0343(4) 0.2583(3) 0.0096(13) Uani 1 1 d . . .
C4 C 0.0252(5) 1.1100(4) 0.2805(3) 0.0143(15) Uani 1 1 d . . .
H4 H -0.0070 1.0564 0.2617 0.017 Uiso 1 1 calc R . .
C5 C 0.2500 0.5146(7) 0.0000 0.018(2) Uani 1 2 d S T P
O6 O 0.3581(3) 0.8895(3) 0.2650(3) 0.0208(12) Uani 1 1 d . . .
N7 N 0.2590(4) 1.0215(4) 0.1473(3) 0.0159(12) Uani 1 1 d . . .
O8 O 0.0943(3) 0.9708(3) 0.2228(2) 0.0199(10) Uani 1 1 d . . .
O9 O 0.2203(3) 1.0360(3) 0.2722(2) 0.0175(10) Uani 1 1 d . . .
C10 C 0.1067(4) 1.1144(4) 0.2865(3) 0.0120(15) Uani 1 1 d . . .
O11 O 0.2498(3) 0.7970(3) 0.1249(2) 0.0172(10) Uani 1 1 d . . .
O12 O 0.0954(3) 0.9078(4) 0.0866(2) 0.0240(12) Uani 1 1 d . . .
C13 C 0.1006(6) 0.8987(5) 0.0273(4) 0.0268(18) Uani 1 1 d . . .
H13 H 0.1521 0.9104 0.0254 0.032 Uiso 1 1 calc R . .
N14 N 0.2500 0.4131(6) 0.0000 0.0207(19) Uani 1 2 d S T P
C15 C 0.2537(4) 0.5617(5) 0.0594(3) 0.0173(15) Uani 1 1 d . . .
H15 H 0.2562 0.5285 0.0994 0.021 Uiso 1 1 calc R . .
C16 C 0.2928(5) 1.1000(5) 0.1789(4) 0.0205(17) Uani 1 1 d . . .
H16 H 0.2888 1.1229 0.2199 0.025 Uiso 1 1 calc R . .
N17 N 0.3343(4) 1.1437(4) 0.1451(3) 0.0153(12) Uani 1 1 d . . .
C18 C 0.2539(4) 0.6601(5) 0.0601(3) 0.0149(14) Uani 1 1 d . . .
N19 N 0.0359(4) 0.8732(4) -0.0321(3) 0.0223(14) Uani 1 1 d . . .
C20 C 0.2500 0.7068(6) 0.0000 0.0125(19) Uani 1 2 d S T P
H20 H 0.2500 0.7721 0.0000 0.015 Uiso 1 2 calc RS T P
C21 C 0.1558(4) 1.1945(4) 0.3138(3) 0.0144(14) Uani 1 1 d . . .
H21 H 0.2114 1.1971 0.3192 0.017 Uiso 1 1 calc R . .
O22 O 0.1272(3) 0.7541(3) 0.1878(3) 0.0299(13) Uani 1 1 d . . .
C23 C 0.3224(6) 1.0875(5) 0.0886(4) 0.0264(18) Uani 1 1 d . . .
H23 H 0.3431 1.1001 0.0543 0.032 Uiso 1 1 calc R . .
N24 N 0.2163(4) 0.2672(4) 0.0105(3) 0.0328(16) Uani 1 1 d . . .
C25 C 0.4629(4) 1.2336(4) 0.1718(3) 0.0131(13) Uani 1 1 d . . .
H25 H 0.4859 1.1825 0.1580 0.016 Uiso 1 1 calc R . .
O26 O 0.2277(3) 0.8408(4) 0.3194(2) 0.0292(13) Uani 1 1 d . . .
C27 C 0.0465(6) 0.8713(6) -0.1003(4) 0.036(2) Uani 1 1 d . . .
H27A H 0.0128 0.9199 -0.1316 0.054 Uiso 1 1 calc GR . .
H27B H 0.0289 0.8114 -0.1232 0.054 Uiso 1 1 calc GR . .
H27C H 0.1048 0.8814 -0.0905 0.054 Uiso 1 1 calc GR . .
C28 C -0.0094(4) 1.1852(4) 0.3027(3) 0.0140(14) Uani 1 1 d . . .
C29 C 0.2585(4) 0.7092(5) 0.1269(3) 0.0144(14) Uani 1 1 d . . .
C30 C 0.3812(4) 1.2298(4) 0.1672(3) 0.0123(13) Uani 1 1 d . . .
C32 C 0.3991(4) 0.8180(5) 0.2915(4) 0.0194(16) Uani 1 1 d . . .
N33 N 0.2787(4) 1.0140(4) 0.0882(3) 0.0248(14) Uani 1 1 d . . .
C37 C -0.0452(6) 0.8531(7) -0.0353(5) 0.043(2) Uani 1 1 d . . .
H37A H -0.0431 0.8542 0.0124 0.065 Uiso 1 1 calc GR . .
H37B H -0.0629 0.7921 -0.0560 0.065 Uiso 1 1 calc GR . .
H37C H -0.0847 0.8995 -0.0643 0.065 Uiso 1 1 calc GR . .
C38 C 0.1993(5) 0.3534(5) 0.0162(4) 0.0301(18) Uani 1 1 d . . .
H38 H 0.1572 0.3731 0.0299 0.036 Uiso 1 1 calc R . .
O O 0.3971(10) 1.1028(11) 0.3709(6) 0.202(9) Uani 1 1 d . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
C3 Eu1 Eu1 128.29(12) . 7_565
C3 Eu1 C32 120.01(17) . .
O6 Eu1 Eu1 71.64(10) . 7_565
O6 Eu1 C3 108.33(17) . .
O6 Eu1 N7 73.49(16) . .
O6 Eu1 O8 133.25(16) . .
O6 Eu1 O9 82.70(16) . .
O6 Eu1 O11 77.66(16) . .
O6 Eu1 O12 141.47(18) . .
O6 Eu1 C32 19.04(16) . .
N7 Eu1 Eu1 138.50(12) . 7_565
N7 Eu1 C3 83.88(18) . .
N7 Eu1 C32 90.36(18) . .
O8 Eu1 Eu1 121.17(11) . 7_565
O8 Eu1 C3 26.16(16) . .
O8 Eu1 N7 99.08(16) . .
O8 Eu1 O9 52.62(15) . .
O8 Eu1 C32 140.53(15) . .
O9 Eu1 Eu1 126.10(10) . 7_565
O9 Eu1 C3 26.46(16) . .
O9 Eu1 N7 69.69(15) . .
O9 Eu1 C32 96.82(16) . .
O11 Eu1 Eu1 70.62(11) . 7_565
O11 Eu1 C3 161.00(16) . .
O11 Eu1 N7 80.61(15) . .
O11 Eu1 O8 148.06(15) . .
O11 Eu1 O9 148.04(15) . .
O11 Eu1 O12 75.15(16) . .
O11 Eu1 C32 71.18(16) . .
O12 Eu1 Eu1 122.41(12) . 7_565
O12 Eu1 C3 90.43(17) . .
O12 Eu1 N7 75.55(17) . .
O12 Eu1 O8 73.91(16) . .
O12 Eu1 O9 107.33(16) . .
O12 Eu1 C32 145.19(17) . .
O22 Eu1 Eu1 52.80(14) . 7_565
O22 Eu1 C3 110.33(17) . .
O22 Eu1 O6 124.08(17) . .
O22 Eu1 N7 148.39(18) . .
O22 Eu1 O8 86.50(16) . .
O22 Eu1 O9 133.29(16) . .
O22 Eu1 O11 78.64(16) . .
O22 Eu1 O12 76.24(19) . .
O22 Eu1 O26 74.9(2) . .
O22 Eu1 C32 105.03(18) . .
O26 Eu1 Eu1 54.78(13) . 7_565
O26 Eu1 C3 74.11(18) . .
O26 Eu1 O6 78.75(19) . .
O26 Eu1 N7 136.76(19) . .
O26 Eu1 O8 76.76(16) . .
O26 Eu1 O9 74.49(17) . .
O26 Eu1 O11 124.88(17) . .
O26 Eu1 O12 139.63(19) . .
O26 Eu1 C32 70.46(18) . .
C32 Eu1 Eu1 52.70(12) . 7_565
O8 C3 Eu1 61.1(3) . .
O8 C3 O9 123.4(6) . .
O8 C3 C10 118.5(6) . .
O9 C3 Eu1 62.3(3) . .
O9 C3 C10 118.2(5) . .
C10 C3 Eu1 179.0(4) . .
C10 C4 H4 119.8 . .
C10 C4 C28 120.4(6) . .
C28 C4 H4 119.8 . .
C15 C5 N14 119.4(4) . .
C15 C5 N14 119.4(4) 2 .
C15 C5 C15 121.2(9) 2 .
C32 O6 Eu1 121.8(4) . .
C16 N7 Eu1 125.8(4) . .
C16 N7 N33 105.8(5) . .
N33 N7 Eu1 126.0(4) . .
C3 O8 Eu1 92.8(4) . .
C3 O9 Eu1 91.2(4) . .
C4 C10 C3 120.3(6) . .
C4 C10 C21 120.8(6) . .
C21 C10 C3 118.8(6) . .
C29 O11 Eu1 125.1(4) . .
C13 O12 Eu1 126.5(5) . .
O12 C13 H13 118.6 . .
O12 C13 N19 122.8(8) . .
N19 C13 H13 118.6 . .
C38 N14 C5 128.6(5) . .
C38 N14 C5 128.6(5) 2 .
C38 N14 C38 102.8(9) 2 .
C5 C15 H15 120.0 . .
C5 C15 C18 119.9(6) . .
C18 C15 H15 120.0 . .
N7 C16 H16 124.0 . .
N7 C16 N17 112.0(6) . .
N17 C16 H16 124.0 . .
C16 N17 C23 103.9(6) . .
C16 N17 C30 126.2(5) . .
C23 N17 C30 129.8(6) . .
C15 C18 C29 118.2(5) . .
C20 C18 C15 118.5(6) . .
C20 C18 C29 123.4(6) . .
C13 N19 C27 118.7(7) . .
C13 N19 C37 123.4(7) . .
C37 N19 C27 117.8(6) . .
C18 C20 C18 122.1(8) . 2
C18 C20 H20 119.0 . .
C18 C20 H20 119.0 2 .
C10 C21 H21 121.1 . .
C30 C21 C10 117.9(6) 7_575 .
C30 C21 H21 121.1 7_575 .
C32 O22 Eu1 154.8(5) 7_565 .
N17 C23 H23 124.2 . .
N33 C23 N17 111.5(6) . .
N33 C23 H23 124.2 . .
C38 N24 N24 106.3(5) . 2
C28 C25 H25 120.6 7_575 .
C28 C25 C30 118.8(6) 7_575 .
C30 C25 H25 120.6 . .
C29 O26 Eu1 161.1(5) 7_565 .
N19 C27 H27A 109.5 . .
N19 C27 H27B 109.5 . .
N19 C27 H27C 109.5 . .
H27A C27 H27B 109.5 . .
H27A C27 H27C 109.5 . .
H27B C27 H27C 109.5 . .
C4 C28 C32 119.9(6) . 6_575
C25 C28 C4 120.0(6) 7_575 .
C25 C28 C32 119.8(6) 7_575 6_575
O11 C29 C18 118.2(5) . .
O26 C29 O11 125.0(6) 7_565 .
O26 C29 C18 116.8(6) 7_565 .
C21 C30 N17 118.7(6) 7_575 .
C25 C30 N17 119.2(6) . .
C25 C30 C21 122.1(6) . 7_575
O6 C32 Eu1 39.2(3) . .
O6 C32 O22 126.4(7) . 7_565
O6 C32 C28 118.2(6) . 6_675
O22 C32 Eu1 89.9(4) 7_565 .
O22 C32 C28 115.4(6) 7_565 6_675
C28 C32 Eu1 151.2(5) 6_675 .
C23 N33 N7 106.8(6) . .
N19 C37 H37A 109.5 . .
N19 C37 H37B 109.5 . .
N19 C37 H37C 109.5 . .
H37A C37 H37B 109.5 . .
H37A C37 H37C 109.5 . .
H37B C37 H37C 109.5 . .
N14 C38 H38 123.8 . .
N24 C38 N14 112.3(8) . .
N24 C38 H38 123.8 . .
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Eu1 Eu1 4.3158(6) 7_565
Eu1 C3 2.823(6) .
Eu1 O6 2.387(5) .
Eu1 N7 2.581(5) .
Eu1 O8 2.474(4) .
Eu1 O9 2.501(4) .
Eu1 O11 2.401(4) .
Eu1 O12 2.404(5) .
Eu1 O22 2.297(5) .
Eu1 O26 2.333(4) .
Eu1 C32 3.212(7) .
C3 O8 1.246(7) .
C3 O9 1.258(7) .
C3 C10 1.527(8) .
C4 H4 0.9300 .
C4 C10 1.374(10) .
C4 C28 1.394(9) .
C5 N14 1.446(13) .
C5 C15 1.366(8) 2
C5 C15 1.366(8) .
O6 C32 1.233(8) .
N7 C16 1.303(9) .
N7 N33 1.391(7) .
C10 C21 1.396(9) .
O11 C29 1.258(8) .
O12 C13 1.258(9) .
C13 H13 0.9300 .
C13 N19 1.320(10) .
N14 C38 1.361(9) .
N14 C38 1.361(10) 2
C15 H15 0.9300 .
C15 C18 1.402(10) .
C16 H16 0.9300 .
C16 N17 1.342(9) .
N17 C23 1.350(9) .
N17 C30 1.438(8) .
C18 C20 1.374(7) .
C18 C29 1.506(8) .
N19 C27 1.481(9) .
N19 C37 1.417(11) .
C20 C18 1.374(7) 2
C20 H20 0.9300 .
C21 H21 0.9300 .
C21 C30 1.391(9) 7_575
O22 C32 1.267(8) 7_565
C23 H23 0.9300 .
C23 N33 1.293(9) .
N24 N24 1.409(13) 2
N24 C38 1.280(9) .
C25 H25 0.9300 .
C25 C28 1.385(9) 7_575
C25 C30 1.387(9) .
O26 C29 1.247(8) 7_565
C27 H27A 0.9600 .
C27 H27B 0.9600 .
C27 H27C 0.9600 .
C28 C25 1.385(9) 7_575
C28 C32 1.513(9) 6_575
C29 O26 1.247(8) 7_565
C30 C21 1.391(9) 7_575
C32 O22 1.267(8) 7_565
C32 C28 1.513(9) 6_675
C37 H37A 0.9600 .
C37 H37B 0.9600 .
C37 H37C 0.9600 .
C38 H38 0.9300 .
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
Eu1 O6 C32 O22 -25.0(9) . 7_565
Eu1 O6 C32 C28 156.4(4) . 6_675
Eu1 N7 C16 N17 162.3(4) . .
Eu1 N7 N33 C23 -163.0(5) . .
Eu1 O11 C29 C18 158.2(4) . .
Eu1 O11 C29 O26 -23.2(10) . 7_565
Eu1 O12 C13 N19 151.4(6) . .
C3 C10 C21 C30 174.0(5) . 7_575
C4 C10 C21 C30 -1.9(9) . 7_575
C5 N14 C38 N24 179.8(4) . .
C5 C15 C18 C20 0.2(8) . .
C5 C15 C18 C29 -179.8(5) . .
N7 C16 N17 C23 1.2(9) . .
N7 C16 N17 C30 -177.6(6) . .
O8 C3 O9 Eu1 0.8(6) . .
O8 C3 C10 C4 8.3(9) . .
O8 C3 C10 C21 -167.6(6) . .
O9 C3 O8 Eu1 -0.8(6) . .
O9 C3 C10 C4 -171.9(6) . .
O9 C3 C10 C21 12.2(8) . .
C10 C3 O8 Eu1 179.1(5) . .
C10 C3 O9 Eu1 -179.1(5) . .
C10 C4 C28 C25 2.6(9) . 7_575
C10 C4 C28 C32 176.1(6) . 6_575
O12 C13 N19 C27 175.5(7) . .
O12 C13 N19 C37 -0.3(12) . .
N14 C5 C15 C18 179.9(4) . .
C15 C5 N14 C38 51.8(5) . .
C15 C5 N14 C38 -128.2(5) . 2
C15 C5 N14 C38 51.8(5) 2 2
C15 C5 N14 C38 -128.2(5) 2 .
C15 C5 C15 C18 -0.1(4) 2 .
C15 C18 C20 C18 -0.1(4) . 2
C15 C18 C29 O11 -172.7(6) . .
C15 C18 C29 O26 8.6(9) . 7_565
C16 N7 N33 C23 0.1(8) . .
C16 N17 C23 N33 -1.2(9) . .
C16 N17 C30 C21 -47.6(9) . 7_575
C16 N17 C30 C25 129.8(7) . .
N17 C23 N33 N7 0.7(9) . .
C20 C18 C29 O11 7.3(9) . .
C20 C18 C29 O26 -171.4(6) . 7_565
C23 N17 C30 C21 133.9(8) . 7_575
C23 N17 C30 C25 -48.7(10) . .
N24 N24 C38 N14 0.5(10) 2 .
C28 C4 C10 C3 -176.6(5) . .
C28 C4 C10 C21 -0.8(10) . .
C28 C25 C30 N17 -176.1(5) 7_575 .
C28 C25 C30 C21 1.2(9) 7_575 7_575
C29 C18 C20 C18 179.9(7) . 2
C30 N17 C23 N33 177.6(7) . .
N33 N7 C16 N17 -0.8(8) . .
C38 N14 C38 N24 -0.2(4) 2 .
