#------------------------------------------------------------------------------
#$Date: 2026-03-05 13:43:08 +0100 (Thu 05 de Mar de 2026) $
#$Revision: 304899 $
#$URL: svn://www.crystallography.net/cod/cif/7/25/14/7251478.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7251478
loop_
_publ_author_name
'Alfuth, Jan'
'Chojnacki, Jarosław'
'Połoński, Tadeusz'
'Olszewska, Teresa'
_publ_section_title
;
 Structural diversity of supramolecular networks composed of
 2,1,3-chalcogenadiazole silver(i) complexes: the role of chalcogen
 bonding in molecular self--assembly
;
_journal_issue                   7
_journal_name_full               CrystEngComm
_journal_page_first              1206
_journal_page_last               1214
_journal_paper_doi               10.1039/D5CE00963D
_journal_volume                  28
_journal_year                    2026
_chemical_formula_moiety         'C16 H16 Ag N4 Se2 +, Cl O4 -'
_chemical_formula_sum            'C16 H16 Ag Cl N4 O4 Se2'
_chemical_formula_weight         629.57
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_atom_sites_solution_secondary   difmap
_audit_creation_date             2024-09-17
_audit_creation_method
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_audit_update_record
;
2025-09-04 deposited with the CCDC.	2026-01-05 downloaded from the CCDC.
;
_cell_angle_alpha                107.42(2)
_cell_angle_beta                 98.47(2)
_cell_angle_gamma                93.08(2)
_cell_formula_units_Z            4
_cell_length_a                   7.4239(19)
_cell_length_b                   13.407(4)
_cell_length_c                   20.291(5)
_cell_measurement_reflns_used    4987
_cell_measurement_temperature    120
_cell_measurement_theta_max      25.49
_cell_measurement_theta_min      2.16
_cell_volume                     1895.7(9)
_computing_cell_refinement       'X-Area Recipe 1.34.0.0 (STOE, 2019)'
_computing_data_collection       'X-Area WinXpose 2.0.22.0 (STOE, 2016)'
_computing_data_reduction
'X-Area Integrate 1.77.0.0 (STOE, 2019) X-Area X-Red32 1.65.0.0 (STOE, 2018)'
_computing_molecular_graphics    'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement  'ShelXL (Sheldrick, 2015)'
_computing_structure_solution    'ShelXT (Sheldrick, 2015)'
_diffrn_ambient_temperature      120.0
_diffrn_detector_area_resol_mean 6.67
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'STOE IPDS 2T'
_diffrn_measurement_method       'rotation method, ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0570
_diffrn_reflns_av_unetI/netI     0.0535
_diffrn_reflns_Laue_measured_fraction_full 0.998
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       8
_diffrn_reflns_limit_h_min       -8
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       24
_diffrn_reflns_limit_l_min       -24
_diffrn_reflns_number            16208
_diffrn_reflns_point_group_measured_fraction_full 0.998
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        25.200
_diffrn_reflns_theta_max         25.200
_diffrn_reflns_theta_min         2.135
_diffrn_source                   'GeniX Mo, 0.05 x 0.05 mm2 microfocus'
_exptl_absorpt_coefficient_mu    5.077
_exptl_absorpt_correction_T_max  0.8849
_exptl_absorpt_correction_T_min  0.4053
_exptl_absorpt_correction_type   integration
_exptl_absorpt_process_details
'STOE X-Red32, absorption correction by Gaussian integration, analogous to P. Coppens, "The Evaluation of Absorption and Extinction in Single-Crystal Structure Analysis", published in F. R. Ahmed (Editor), "Crystallographic Computing", Munksgaard, Copenhagen (1970), 255 - 270'
_exptl_crystal_colour            colourless
_exptl_crystal_colour_primary    colourless
_exptl_crystal_density_diffrn    2.206
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             1216
_exptl_crystal_size_max          0.21
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.025
_refine_diff_density_max         2.057
_refine_diff_density_min         -1.308
_refine_diff_density_rms         0.266
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.184
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     513
_refine_ls_number_reflns         6804
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.184
_refine_ls_R_factor_all          0.1195
_refine_ls_R_factor_gt           0.1006
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0001P)²+112.0823P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2235
_refine_ls_wR_factor_ref         0.2341
_reflns_Friedel_coverage         0.000
_reflns_number_gt                5567
_reflns_number_total             6804
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d5ce00963d2.cif
_cod_data_source_block           8
_cod_depositor_comments
'Adding full bibliography for 7251474--7251487.cif.'
_cod_original_cell_volume        1895.6(9)
_cod_database_code               7251478
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.884
_shelx_estimated_absorpt_t_min   0.415
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Aromatic/amide H refined with riding coordinates:
 C5(H5), C6(H6), C13(H13), C14(H14), C21(H21), C22(H22), C29(H29), C30(H30)
2.b Idealised Me refined as rotating group:
 C7(H7A,H7B,H7C), C8(H8A,H8B,H8C), C15(H15A,H15B,H15C), C16(H16A,H16B,H16C),
 C23(H23A,H23B,H23C), C24(H24A,H24B,H24C), C31(H31A,H31B,H31C), C32(H32A,H32B,
 H32C)
;
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag1 Ag 0.75485(19) 0.42140(11) 0.54712(7) 0.0362(4) Uani 1 1 d . . . . .
Se1 Se 0.7539(2) 0.32838(15) 0.36743(9) 0.0331(4) Uani 1 1 d . . . . .
Se2 Se 0.7625(2) 0.64381(14) 0.69095(9) 0.0325(4) Uani 1 1 d . . . . .
N1 N 0.7493(19) 0.3003(12) 0.4484(7) 0.033(3) Uani 1 1 d . . . . .
N2 N 0.793(2) 0.1970(13) 0.3219(8) 0.040(4) Uani 1 1 d . . . . .
N3 N 0.8087(18) 0.5103(11) 0.6585(7) 0.031(3) Uani 1 1 d . . . . .
N4 N 0.790(2) 0.6423(12) 0.7801(7) 0.034(3) Uani 1 1 d . . . . .
C1 C 0.772(2) 0.1989(14) 0.4366(9) 0.031(4) Uani 1 1 d . . . . .
C2 C 0.796(2) 0.1411(15) 0.3669(9) 0.035(4) Uani 1 1 d . . . . .
C3 C 0.817(3) 0.0303(16) 0.3481(10) 0.040(5) Uani 1 1 d . . . . .
C4 C 0.811(2) -0.0161(15) 0.3979(9) 0.034(4) Uani 1 1 d . . . . .
C5 C 0.787(2) 0.0422(16) 0.4678(10) 0.039(4) Uani 1 1 d . . . . .
H5 H 0.784934 0.006014 0.501423 0.047 Uiso 1 1 calc R . . . .
C6 C 0.767(2) 0.1446(15) 0.4872(9) 0.037(4) Uani 1 1 d . . . . .
H6 H 0.749168 0.180496 0.533497 0.044 Uiso 1 1 calc R . . . .
C7 C 0.838(3) -0.0235(15) 0.2742(9) 0.040(4) Uani 1 1 d . . . . .
H7A H 0.732459 -0.014317 0.242254 0.060 Uiso 1 1 calc GR . . . .
H7B H 0.845565 -0.098580 0.267357 0.060 Uiso 1 1 calc GR . . . .
H7C H 0.950371 0.007156 0.264554 0.060 Uiso 1 1 calc GR . . . .
C8 C 0.826(3) -0.1340(16) 0.3819(11) 0.043(5) Uani 1 1 d . . . . .
H8A H 0.738365 -0.172605 0.339533 0.065 Uiso 1 1 calc GR . . . .
H8B H 0.797689 -0.156167 0.421469 0.065 Uiso 1 1 calc GR . . . .
H8C H 0.950234 -0.148951 0.374512 0.065 Uiso 1 1 calc GR . . . .
C9 C 0.844(2) 0.4741(15) 0.7116(9) 0.035(4) Uani 1 1 d . . . . .
C10 C 0.831(2) 0.5455(15) 0.7791(10) 0.034(4) Uani 1 1 d . . . . .
C11 C 0.858(2) 0.5153(14) 0.8418(9) 0.031(4) Uani 1 1 d . . . . .
C12 C 0.902(2) 0.4174(15) 0.8359(9) 0.034(4) Uani 1 1 d . . . . .
C13 C 0.920(2) 0.3444(14) 0.7693(9) 0.034(4) Uani 1 1 d . . . . .
H13 H 0.953916 0.276402 0.767611 0.041 Uiso 1 1 calc R . . . .
C14 C 0.891(2) 0.3706(14) 0.7070(9) 0.036(4) Uani 1 1 d . . . . .
H14 H 0.901155 0.321301 0.663373 0.043 Uiso 1 1 calc R . . . .
C15 C 0.836(2) 0.5927(15) 0.9090(9) 0.036(4) Uani 1 1 d . . . . .
H15A H 0.946063 0.642573 0.927626 0.054 Uiso 1 1 calc GR . . . .
H15B H 0.816257 0.555728 0.942810 0.054 Uiso 1 1 calc GR . . . .
H15C H 0.729755 0.630728 0.901038 0.054 Uiso 1 1 calc GR . . . .
C16 C 0.936(3) 0.3789(16) 0.8979(9) 0.042(5) Uani 1 1 d . . . . .
H16A H 1.053799 0.412638 0.926920 0.063 Uiso 1 1 calc GR . . . .
H16B H 0.939577 0.302559 0.881947 0.063 Uiso 1 1 calc GR . . . .
H16C H 0.837947 0.396286 0.925443 0.063 Uiso 1 1 calc GR . . . .
Ag2 Ag 0.71181(19) 1.07440(11) 0.99804(7) 0.0351(4) Uani 1 1 d . . . . .
Se3 Se 0.7237(2) 0.84236(14) 0.86228(9) 0.0323(4) Uani 1 1 d . . . . .
N5 N 0.6766(19) 0.9775(12) 0.8899(8) 0.032(3) Uani 1 1 d . . . . .
N6 N 0.714(2) 0.8412(13) 0.7740(8) 0.037(4) Uani 1 1 d . . . . .
C17 C 0.662(2) 1.0118(15) 0.8328(9) 0.031(4) Uani 1 1 d . . . . .
C18 C 0.682(2) 0.9355(13) 0.7698(8) 0.029(4) Uani 1 1 d . . . . .
C19 C 0.674(2) 0.9601(14) 0.7063(9) 0.032(4) Uani 1 1 d . . . . .
C20 C 0.648(2) 1.0633(15) 0.7087(9) 0.034(4) Uani 1 1 d . . . . .
C21 C 0.624(2) 1.1383(15) 0.7747(10) 0.038(4) Uani 1 1 d . . . . .
H21 H 0.601965 1.207724 0.775296 0.046 Uiso 1 1 calc R . . . .
C22 C 0.630(2) 1.1143(15) 0.8356(10) 0.037(4) Uani 1 1 d . . . . .
H22 H 0.613130 1.164930 0.877854 0.044 Uiso 1 1 calc R . . . .
C23 C 0.699(3) 0.8764(15) 0.6398(10) 0.038(4) Uani 1 1 d . . . . .
H23A H 0.821091 0.852537 0.646457 0.057 Uiso 1 1 calc GR . . . .
H23B H 0.687053 0.905805 0.600755 0.057 Uiso 1 1 calc GR . . . .
H23C H 0.605748 0.816704 0.629165 0.057 Uiso 1 1 calc GR . . . .
C24 C 0.649(3) 1.1005(15) 0.6464(10) 0.042(5) Uani 1 1 d . . . . .
H24A H 0.770388 1.096253 0.632883 0.062 Uiso 1 1 calc GR . . . .
H24B H 0.619832 1.173579 0.658100 0.062 Uiso 1 1 calc GR . . . .
H24C H 0.557234 1.056269 0.607330 0.062 Uiso 1 1 calc GR . . . .
Se4 Se 0.7721(2) 1.17815(14) 1.18167(9) 0.0316(4) Uani 1 1 d . . . . .
N7 N 0.736(2) 1.1987(12) 1.0976(7) 0.034(3) Uani 1 1 d . . . . .
N8 N 0.732(2) 1.3109(12) 1.2245(7) 0.033(3) Uani 1 1 d . . . . .
C25 C 0.703(2) 1.2976(14) 1.1053(9) 0.031(4) Uani 1 1 d . . . . .
C26 C 0.699(2) 1.3595(14) 1.1759(9) 0.031(4) Uani 1 1 d . . . . .
C27 C 0.662(2) 1.4661(13) 1.1933(9) 0.030(4) Uani 1 1 d . . . . .
C28 C 0.638(2) 1.5086(14) 1.1401(9) 0.034(4) Uani 1 1 d . . . . .
C29 C 0.645(2) 1.4427(15) 1.0677(10) 0.037(4) Uani 1 1 d . . . . .
H29 H 0.629148 1.474342 1.031430 0.045 Uiso 1 1 calc R . . . .
C30 C 0.673(3) 1.3416(16) 1.0505(9) 0.038(4) Uani 1 1 d . . . . .
H30 H 0.673691 1.301044 1.003239 0.046 Uiso 1 1 calc R . . . .
C31 C 0.648(3) 1.5275(15) 1.2676(9) 0.039(4) Uani 1 1 d . . . . .
H31A H 0.594306 1.480568 1.290069 0.058 Uiso 1 1 calc GR . . . .
H31B H 0.569653 1.584045 1.267201 0.058 Uiso 1 1 calc GR . . . .
H31C H 0.770067 1.557868 1.293802 0.058 Uiso 1 1 calc GR . . . .
C32 C 0.596(3) 1.6197(14) 1.1487(10) 0.041(4) Uani 1 1 d . . . . .
H32A H 0.491476 1.633992 1.173448 0.061 Uiso 1 1 calc GR . . . .
H32B H 0.565188 1.629174 1.102423 0.061 Uiso 1 1 calc GR . . . .
H32C H 0.702705 1.668373 1.175796 0.061 Uiso 1 1 calc GR . . . .
Cl1 Cl 0.7273(6) 0.6279(4) 0.4725(2) 0.0381(10) Uani 1 1 d . . . . .
O1 O 0.623(2) 0.5296(12) 0.4448(7) 0.055(4) Uani 1 1 d . . . . .
O2 O 0.8704(17) 0.6332(13) 0.4345(7) 0.049(4) Uani 1 1 d . . . . .
O3 O 0.801(2) 0.6417(14) 0.5447(6) 0.060(4) Uani 1 1 d . . . . .
O4 O 0.605(2) 0.7053(12) 0.4701(8) 0.052(4) Uani 1 1 d . . . . .
Cl2 Cl 0.8257(6) 0.8728(4) 1.0612(2) 0.0348(10) Uani 1 1 d . . . . .
O5 O 0.9742(17) 0.8268(11) 1.0301(7) 0.044(3) Uani 1 1 d . . . . .
O6 O 0.6708(19) 0.8668(12) 1.0065(7) 0.049(4) Uani 1 1 d . . . . .
O7 O 0.883(2) 0.9827(11) 1.0994(8) 0.051(4) Uani 1 1 d . . . . .
O8 O 0.771(2) 0.8191(12) 1.1078(8) 0.060(4) Uani 1 1 d . . . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Se Se -0.0929 2.2259 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
N1 Ag1 N3 162.5(6) . . ?
N2 Se1 N1 93.1(7) . . ?
N3 Se2 N4 93.1(7) . . ?
Se1 N1 Ag1 122.9(8) . . ?
C1 N1 Ag1 128.9(12) . . ?
C1 N1 Se1 107.4(11) . . ?
C2 N2 Se1 107.8(12) . . ?
Se2 N3 Ag1 122.6(8) . . ?
C9 N3 Ag1 127.8(12) . . ?
C9 N3 Se2 108.4(11) . . ?
C10 N4 Se2 106.6(11) . . ?
N1 C1 C2 116.4(16) . . ?
N1 C1 C6 124.6(16) . . ?
C6 C1 C2 118.9(16) . . ?
N2 C2 C1 115.3(16) . . ?
N2 C2 C3 123.7(16) . . ?
C1 C2 C3 121.0(16) . . ?
C2 C3 C7 117.1(17) . . ?
C4 C3 C2 117.2(17) . . ?
C4 C3 C7 125.6(19) . . ?
C3 C4 C5 121.6(18) . . ?
C3 C4 C8 120.9(17) . . ?
C5 C4 C8 117.5(17) . . ?
C4 C5 H5 118.5 . . ?
C6 C5 C4 122.9(18) . . ?
C6 C5 H5 118.5 . . ?
C1 C6 H6 120.8 . . ?
C5 C6 C1 118.3(16) . . ?
C5 C6 H6 120.8 . . ?
C3 C7 H7A 109.5 . . ?
C3 C7 H7B 109.5 . . ?
C3 C7 H7C 109.5 . . ?
H7A C7 H7B 109.5 . . ?
H7A C7 H7C 109.5 . . ?
H7B C7 H7C 109.5 . . ?
C4 C8 H8A 109.5 . . ?
C4 C8 H8B 109.5 . . ?
C4 C8 H8C 109.5 . . ?
H8A C8 H8B 109.5 . . ?
H8A C8 H8C 109.5 . . ?
H8B C8 H8C 109.5 . . ?
N3 C9 C10 115.9(16) . . ?
N3 C9 C14 125.2(16) . . ?
C14 C9 C10 118.9(16) . . ?
N4 C10 C9 115.9(16) . . ?
N4 C10 C11 121.9(16) . . ?
C11 C10 C9 122.2(16) . . ?
C10 C11 C15 118.8(16) . . ?
C12 C11 C10 117.7(16) . . ?
C12 C11 C15 123.5(16) . . ?
C11 C12 C13 121.6(17) . . ?
C11 C12 C16 121.9(16) . . ?
C13 C12 C16 116.5(17) . . ?
C12 C13 H13 118.9 . . ?
C14 C13 C12 122.1(17) . . ?
C14 C13 H13 118.9 . . ?
C9 C14 H14 121.3 . . ?
C13 C14 C9 117.5(16) . . ?
C13 C14 H14 121.3 . . ?
C11 C15 H15A 109.5 . . ?
C11 C15 H15B 109.5 . . ?
C11 C15 H15C 109.5 . . ?
H15A C15 H15B 109.5 . . ?
H15A C15 H15C 109.5 . . ?
H15B C15 H15C 109.5 . . ?
C12 C16 H16A 109.5 . . ?
C12 C16 H16B 109.5 . . ?
C12 C16 H16C 109.5 . . ?
H16A C16 H16B 109.5 . . ?
H16A C16 H16C 109.5 . . ?
H16B C16 H16C 109.5 . . ?
N5 Ag2 N7 167.9(6) . . ?
N6 Se3 N5 92.0(7) . . ?
Se3 N5 Ag2 124.1(8) . . ?
C17 N5 Ag2 126.4(12) . . ?
C17 N5 Se3 107.6(11) . . ?
C18 N6 Se3 109.1(11) . . ?
N5 C17 C18 115.0(16) . . ?
N5 C17 C22 123.0(16) . . ?
C22 C17 C18 122.0(16) . . ?
N6 C18 C17 116.3(16) . . ?
N6 C18 C19 122.2(15) . . ?
C17 C18 C19 121.5(16) . . ?
C18 C19 C23 120.0(16) . . ?
C20 C19 C18 117.3(15) . . ?
C20 C19 C23 122.7(16) . . ?
C19 C20 C21 119.0(17) . . ?
C19 C20 C24 122.3(15) . . ?
C21 C20 C24 118.6(17) . . ?
C20 C21 H21 118.2 . . ?
C22 C21 C20 123.6(18) . . ?
C22 C21 H21 118.2 . . ?
C17 C22 H22 121.7 . . ?
C21 C22 C17 116.6(17) . . ?
C21 C22 H22 121.7 . . ?
C19 C23 H23A 109.5 . . ?
C19 C23 H23B 109.5 . . ?
C19 C23 H23C 109.5 . . ?
H23A C23 H23B 109.5 . . ?
H23A C23 H23C 109.5 . . ?
H23B C23 H23C 109.5 . . ?
C20 C24 H24A 109.5 . . ?
C20 C24 H24B 109.5 . . ?
C20 C24 H24C 109.5 . . ?
H24A C24 H24B 109.5 . . ?
H24A C24 H24C 109.5 . . ?
H24B C24 H24C 109.5 . . ?
N7 Se4 N8 91.6(7) . . ?
Se4 N7 Ag2 124.4(8) . . ?
C25 N7 Ag2 125.4(12) . . ?
C25 N7 Se4 109.6(11) . . ?
C26 N8 Se4 108.3(11) . . ?
N7 C25 C26 114.5(15) . . ?
N7 C25 C30 124.9(16) . . ?
C30 C25 C26 120.7(16) . . ?
N8 C26 C25 116.1(15) . . ?
N8 C26 C27 122.0(15) . . ?
C27 C26 C25 121.9(16) . . ?
C26 C27 C31 120.7(16) . . ?
C28 C27 C26 116.9(15) . . ?
C28 C27 C31 122.3(16) . . ?
C27 C28 C29 119.7(16) . . ?
C27 C28 C32 124.2(16) . . ?
C29 C28 C32 116.1(17) . . ?
C28 C29 H29 118.1 . . ?
C30 C29 C28 123.8(18) . . ?
C30 C29 H29 118.1 . . ?
C25 C30 H30 121.5 . . ?
C29 C30 C25 116.9(16) . . ?
C29 C30 H30 121.5 . . ?
C27 C31 H31A 109.5 . . ?
C27 C31 H31B 109.5 . . ?
C27 C31 H31C 109.5 . . ?
H31A C31 H31B 109.5 . . ?
H31A C31 H31C 109.5 . . ?
H31B C31 H31C 109.5 . . ?
C28 C32 H32A 109.5 . . ?
C28 C32 H32B 109.5 . . ?
C28 C32 H32C 109.5 . . ?
H32A C32 H32B 109.5 . . ?
H32A C32 H32C 109.5 . . ?
H32B C32 H32C 109.5 . . ?
O1 Cl1 O2 110.6(9) . . ?
O1 Cl1 O3 108.0(10) . . ?
O1 Cl1 O4 107.0(10) . . ?
O2 Cl1 O3 110.2(9) . . ?
O2 Cl1 O4 112.3(9) . . ?
O4 Cl1 O3 108.6(9) . . ?
O5 Cl2 O6 109.6(8) . . ?
O5 Cl2 O7 108.7(9) . . ?
O5 Cl2 O8 110.7(9) . . ?
O7 Cl2 O6 108.4(9) . . ?
O8 Cl2 O6 109.3(10) . . ?
O8 Cl2 O7 110.1(9) . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Ag1 N1 2.161(14) . ?
Ag1 N3 2.180(14) . ?
Se1 N1 1.796(15) . ?
Se1 N2 1.789(15) . ?
Se2 N3 1.784(14) . ?
Se2 N4 1.796(14) . ?
N1 C1 1.33(2) . ?
N2 C2 1.34(2) . ?
N3 C9 1.31(2) . ?
N4 C10 1.35(2) . ?
C1 C2 1.44(2) . ?
C1 C6 1.43(3) . ?
C2 C3 1.44(3) . ?
C3 C4 1.34(3) . ?
C3 C7 1.49(2) . ?
C4 C5 1.44(3) . ?
C4 C8 1.53(3) . ?
C5 H5 0.9500 . ?
C5 C6 1.33(3) . ?
C6 H6 0.9500 . ?
C7 H7A 0.9800 . ?
C7 H7B 0.9800 . ?
C7 H7C 0.9800 . ?
C8 H8A 0.9800 . ?
C8 H8B 0.9800 . ?
C8 H8C 0.9800 . ?
C9 C10 1.44(2) . ?
C9 C14 1.43(3) . ?
C10 C11 1.44(3) . ?
C11 C12 1.34(3) . ?
C11 C15 1.49(2) . ?
C12 C13 1.44(2) . ?
C12 C16 1.49(3) . ?
C13 H13 0.9500 . ?
C13 C14 1.40(3) . ?
C14 H14 0.9500 . ?
C15 H15A 0.9800 . ?
C15 H15B 0.9800 . ?
C15 H15C 0.9800 . ?
C16 H16A 0.9800 . ?
C16 H16B 0.9800 . ?
C16 H16C 0.9800 . ?
Ag2 N5 2.158(15) . ?
Ag2 N7 2.176(14) . ?
Se3 N5 1.799(15) . ?
Se3 N6 1.776(15) . ?
N5 C17 1.36(2) . ?
N6 C18 1.32(2) . ?
C17 C18 1.41(2) . ?
C17 C22 1.39(3) . ?
C18 C19 1.42(2) . ?
C19 C20 1.39(3) . ?
C19 C23 1.52(2) . ?
C20 C21 1.46(2) . ?
C20 C24 1.49(3) . ?
C21 H21 0.9500 . ?
C21 C22 1.36(3) . ?
C22 H22 0.9500 . ?
C23 H23A 0.9800 . ?
C23 H23B 0.9800 . ?
C23 H23C 0.9800 . ?
C24 H24A 0.9800 . ?
C24 H24B 0.9800 . ?
C24 H24C 0.9800 . ?
Se4 N7 1.792(15) . ?
Se4 N8 1.794(14) . ?
N7 C25 1.33(2) . ?
N8 C26 1.34(2) . ?
C25 C26 1.43(2) . ?
C25 C30 1.40(2) . ?
C26 C27 1.42(2) . ?
C27 C28 1.36(3) . ?
C27 C31 1.51(2) . ?
C28 C29 1.48(2) . ?
C28 C32 1.50(2) . ?
C29 H29 0.9500 . ?
C29 C30 1.33(3) . ?
C30 H30 0.9500 . ?
C31 H31A 0.9800 . ?
C31 H31B 0.9800 . ?
C31 H31C 0.9800 . ?
C32 H32A 0.9800 . ?
C32 H32B 0.9800 . ?
C32 H32C 0.9800 . ?
Cl1 O1 1.404(16) . ?
Cl1 O2 1.412(13) . ?
Cl1 O3 1.440(14) . ?
Cl1 O4 1.420(14) . ?
Cl2 O5 1.429(12) . ?
Cl2 O6 1.457(13) . ?
Cl2 O7 1.451(15) . ?
Cl2 O8 1.437(15) . ?
