#------------------------------------------------------------------------------
#$Date: 2026-02-13 00:00:11 +0100 (Fri 13 de Feb de 2026) $
#$Revision: 304307 $
#$URL: svn://www.crystallography.net/cod/cif/7/72/00/7720042.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_7720042
loop_
_publ_author_name
'Ott, Adrian'
'Leis, Wolfgang'
'Seitz, Michael'
'Schnepf, Andreas'
_publ_section_title
;
 [Au₈(TePh)₄dppm₂(Ph₂PCHPPh₂)₂]Cl₂:
 a water and air stable red-luminescent gold-tellurolate cluster with an
 excellent quantum yield.
;
_journal_issue                   6
_journal_name_full
'Dalton transactions (Cambridge, England : 2003)'
_journal_page_first              2438
_journal_page_last               2442
_journal_paper_doi               10.1039/d5dt02489g
_journal_volume                  55
_journal_year                    2026
_chemical_formula_moiety         'C124 H106 Au8 P8 Te4, 2(Cl), 8(C H Cl3)'
_chemical_formula_sum            'C132 H114 Au8 Cl26 P8 Te4'
_chemical_formula_weight         4955.82
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     dual
_audit_creation_date             2024-09-30
_audit_creation_method
;
Olex2 1.5
(compiled 2024.02.16 svn.r378c4104 for OlexSys, GUI svn.r6928)
;
_audit_update_record
;
2025-08-28 deposited with the CCDC.	2025-12-19 downloaded from the CCDC.
;
_cell_angle_alpha                113.5700(10)
_cell_angle_beta                 105.3850(10)
_cell_angle_gamma                90.9070(10)
_cell_formula_units_Z            1
_cell_length_a                   13.6754(5)
_cell_length_b                   16.6156(6)
_cell_length_c                   18.9107(7)
_cell_measurement_reflns_used    9979
_cell_measurement_temperature    99.95
_cell_measurement_theta_max      28.256
_cell_measurement_theta_min      2.255
_cell_volume                     3761.0(2)
_computing_cell_refinement       'SAINT V8.40B (?, 2016)'
_computing_data_reduction        'SAINT V8.40B (?, 2016)'
_computing_molecular_graphics    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material  'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement  'SHELXL 2014/7 (Sheldrick, 2015)'
_computing_structure_solution    'SHELXT 2014/5 (Sheldrick, 2014)'
_diffrn_ambient_temperature      99.95
_diffrn_detector                 'Bruker APEX2 area detector'
_diffrn_detector_area_resol_mean 7.9
_diffrn_detector_type            'CCD area detector'
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device       'three-circle diffractometer'
_diffrn_measurement_device_type  'Bruker SMART APEX2 area detector'
_diffrn_measurement_method       'ω and φ scans'
_diffrn_radiation_monochromator  'mirror optics'
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0275
_diffrn_reflns_av_unetI/netI     0.0173
_diffrn_reflns_Laue_measured_fraction_full 0.999
_diffrn_reflns_Laue_measured_fraction_max 0.998
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            115499
_diffrn_reflns_point_group_measured_fraction_full 0.999
_diffrn_reflns_point_group_measured_fraction_max 0.998
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         28.282
_diffrn_reflns_theta_min         1.917
_diffrn_source                   'microfocus sealed X-ray tube'
_diffrn_source_current           0.59
_diffrn_source_power             0.0295
_diffrn_source_type              'Incoatec I\ms'
_diffrn_source_voltage           50.0
_exptl_absorpt_coefficient_mu    9.123
_exptl_absorpt_correction_T_max  0.7457
_exptl_absorpt_correction_T_min  0.5263
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.0999 before and 0.0404 after correction.
The Ratio of minimum to maximum transmission is 0.7058.
The λ/2 correction factor is Not present.
;
_exptl_crystal_colour            orange
_exptl_crystal_colour_primary    orange
_exptl_crystal_density_diffrn    2.188
_exptl_crystal_description       plate
_exptl_crystal_F_000             2308
_exptl_crystal_preparation       Luminescent
_exptl_crystal_size_max          0.183
_exptl_crystal_size_mid          0.17
_exptl_crystal_size_min          0.037
_refine_diff_density_max         1.589
_refine_diff_density_min         -1.323
_refine_diff_density_rms         0.138
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.100
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     802
_refine_ls_number_reflns         18634
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.100
_refine_ls_R_factor_all          0.0279
_refine_ls_R_factor_gt           0.0225
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0190P)²+13.8418P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0505
_refine_ls_wR_factor_ref         0.0533
_reflns_Friedel_coverage         0.000
_reflns_number_gt                16775
_reflns_number_total             18634
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            d5dt02489g2.cif
_cod_data_source_block           9
_cod_database_code               7720042
_shelx_shelxl_version_number     2014/7
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_max   0.729
_shelx_estimated_absorpt_t_min   0.286
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
2.a Ternary CH refined with riding coordinates:
 C213(H213), C1(H1), C2(H2), C3(H3), C4(H4)
2.b Secondary CH2 refined with riding coordinates:
 C113(H11A,H11B)
2.c Aromatic/amide H refined with riding coordinates:
 C102(H102), C103(H103), C104(H104), C105(H105), C106(H106), C108(H108),
 C109(H109), C110(H110), C111(H111), C112(H112), C115(H115), C116(H116),
 C117(H117), C118(H118), C119(H119), C121(H121), C122(H122), C123(H123),
 C124(H124), C125(H125), C202(H202), C203(H203), C204(H204), C205(H205),
 C206(H206), C208(H208), C209(H209), C210(H210), C211(H211), C212(H212),
 C215(H215), C216(H216), C217(H217), C218(H218), C219(H219), C221(H221),
 C222(H222), C223(H223), C224(H224), C225(H225), C502(H502), C503(H503),
 C504(H504), C505(H505), C506(H506), C602(H602), C603(H603), C604(H604),
 C605(H605), C606(H606)
;
_olex2_submission_special_instructions 'No special instructions were received'
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au1 Au 0.45022(2) 0.25725(2) 0.78294(2) 0.01326(3) Uani 1 1 d . . . . .
Au2 Au 0.62691(2) 0.09726(2) 0.69416(2) 0.01633(3) Uani 1 1 d . . . . .
Au3 Au 0.37951(2) 0.04682(2) 0.64492(2) 0.01576(3) Uani 1 1 d . . . . .
Au4 Au 0.49783(2) 0.15370(2) 0.57472(2) 0.01548(3) Uani 1 1 d . . . . .
Te1 Te 0.51445(2) -0.05673(2) 0.66436(2) 0.01556(4) Uani 1 1 d . . . . .
Te2 Te 0.64492(2) 0.06206(2) 0.54550(2) 0.01410(4) Uani 1 1 d . . . . .
P11 P 0.56622(6) 0.27709(6) 0.90284(5) 0.01321(16) Uani 1 1 d . . . . .
P12 P 0.72865(6) 0.17928(6) 0.82421(5) 0.01290(15) Uani 1 1 d . . . . .
P21 P 0.26306(6) 0.14471(6) 0.64652(5) 0.01395(16) Uani 1 1 d . . . . .
P22 P 0.39766(7) 0.26197(6) 0.61167(5) 0.01427(16) Uani 1 1 d . . . . .
C101 C 0.5044(3) 0.2596(2) 0.9705(2) 0.0151(6) Uani 1 1 d . . . . .
C102 C 0.3988(3) 0.2348(2) 0.9458(2) 0.0183(7) Uani 1 1 d . . . . .
H102 H 0.3590 0.2282 0.8938 0.022 Uiso 1 1 calc R U . . .
C103 C 0.3513(3) 0.2195(3) 0.9965(2) 0.0230(8) Uani 1 1 d . . . . .
H103 H 0.2792 0.2029 0.9793 0.028 Uiso 1 1 calc R U . . .
C104 C 0.4089(3) 0.2284(2) 1.0722(2) 0.0234(8) Uani 1 1 d . . . . .
H104 H 0.3763 0.2179 1.1069 0.028 Uiso 1 1 calc R U . . .
C105 C 0.5138(3) 0.2527(3) 1.0974(2) 0.0225(7) Uani 1 1 d . . . . .
H105 H 0.5531 0.2583 1.1491 0.027 Uiso 1 1 calc R U . . .
C106 C 0.5623(3) 0.2690(2) 1.0475(2) 0.0192(7) Uani 1 1 d . . . . .
H106 H 0.6343 0.2864 1.0654 0.023 Uiso 1 1 calc R U . . .
C107 C 0.6304(3) 0.3906(2) 0.9550(2) 0.0166(7) Uani 1 1 d . . . . .
C108 C 0.5845(3) 0.4540(3) 0.9317(2) 0.0249(8) Uani 1 1 d . . . . .
H108 H 0.5217 0.4369 0.8894 0.030 Uiso 1 1 calc R U . . .
C109 C 0.6294(4) 0.5418(3) 0.9696(3) 0.0328(9) Uani 1 1 d . . . . .
H109 H 0.5971 0.5844 0.9534 0.039 Uiso 1 1 calc R U . . .
C110 C 0.7210(3) 0.5675(3) 1.0309(3) 0.0280(8) Uani 1 1 d . . . . .
H110 H 0.7519 0.6277 1.0567 0.034 Uiso 1 1 calc R U . . .
C111 C 0.7677(3) 0.5050(3) 1.0546(2) 0.0267(8) Uani 1 1 d . . . . .
H111 H 0.8308 0.5226 1.0965 0.032 Uiso 1 1 calc R U . . .
C112 C 0.7230(3) 0.4168(2) 1.0175(2) 0.0193(7) Uani 1 1 d . . . . .
H112 H 0.7550 0.3745 1.0344 0.023 Uiso 1 1 calc R U . . .
C113 C 0.6656(2) 0.2051(2) 0.90317(19) 0.0139(6) Uani 1 1 d . . . . .
H11A H 0.6348 0.1485 0.8991 0.017 Uiso 1 1 calc R U . . .
H11B H 0.7188 0.2332 0.9561 0.017 Uiso 1 1 calc R U . . .
C114 C 0.8251(3) 0.1119(2) 0.8479(2) 0.0155(6) Uani 1 1 d . . . . .
C115 C 0.8715(3) 0.1213(2) 0.9266(2) 0.0193(7) Uani 1 1 d . . . . .
H115 H 0.8532 0.1642 0.9705 0.023 Uiso 1 1 calc R U . . .
C116 C 0.9445(3) 0.0676(3) 0.9407(2) 0.0252(8) Uani 1 1 d . . . . .
H116 H 0.9764 0.0745 0.9943 0.030 Uiso 1 1 calc R U . . .
C117 C 0.9708(3) 0.0040(3) 0.8767(3) 0.0251(8) Uani 1 1 d . . . . .
H117 H 1.0200 -0.0329 0.8865 0.030 Uiso 1 1 calc R U . . .
C118 C 0.9255(3) -0.0054(2) 0.7987(2) 0.0233(8) Uani 1 1 d . . . . .
H118 H 0.9439 -0.0488 0.7551 0.028 Uiso 1 1 calc R U . . .
C119 C 0.8532(3) 0.0482(2) 0.7836(2) 0.0193(7) Uani 1 1 d . . . . .
H119 H 0.8227 0.0418 0.7300 0.023 Uiso 1 1 calc R U . . .
C120 C 0.8001(3) 0.2848(2) 0.8480(2) 0.0155(6) Uani 1 1 d . . . . .
C121 C 0.8963(3) 0.3154(2) 0.9058(2) 0.0181(7) Uani 1 1 d . . . . .
H121 H 0.9247 0.2818 0.9348 0.022 Uiso 1 1 calc R U . . .
C122 C 0.9504(3) 0.3950(2) 0.9208(2) 0.0216(7) Uani 1 1 d . . . . .
H122 H 1.0166 0.4149 0.9590 0.026 Uiso 1 1 calc R U . . .
C123 C 0.9077(3) 0.4452(3) 0.8801(2) 0.0259(8) Uani 1 1 d . . . . .
H123 H 0.9449 0.4994 0.8902 0.031 Uiso 1 1 calc R U . . .
C124 C 0.8116(4) 0.4169(3) 0.8250(3) 0.0313(9) Uani 1 1 d . . . . .
H124 H 0.7817 0.4525 0.7986 0.038 Uiso 1 1 calc R U . . .
C125 C 0.7582(3) 0.3359(3) 0.8078(2) 0.0238(8) Uani 1 1 d . . . . .
H125 H 0.6928 0.3156 0.7685 0.029 Uiso 1 1 calc R U . . .
C201 C 0.1958(3) 0.1614(2) 0.7213(2) 0.0172(7) Uani 1 1 d . . . . .
C202 C 0.1384(3) 0.2315(3) 0.7416(3) 0.0282(8) Uani 1 1 d . . . . .
H202 H 0.1358 0.2716 0.7169 0.034 Uiso 1 1 calc R U . . .
C203 C 0.0851(3) 0.2431(3) 0.7974(3) 0.0308(9) Uani 1 1 d . . . . .
H203 H 0.0472 0.2916 0.8114 0.037 Uiso 1 1 calc R U . . .
C204 C 0.0872(3) 0.1846(3) 0.8323(2) 0.0271(8) Uani 1 1 d . . . . .
H204 H 0.0503 0.1923 0.8701 0.032 Uiso 1 1 calc R U . . .
C205 C 0.1427(3) 0.1149(3) 0.8124(3) 0.0288(9) Uani 1 1 d . . . . .
H205 H 0.1440 0.0746 0.8367 0.035 Uiso 1 1 calc R U . . .
C206 C 0.1974(3) 0.1027(3) 0.7568(2) 0.0233(8) Uani 1 1 d . . . . .
H206 H 0.2355 0.0543 0.7434 0.028 Uiso 1 1 calc R U . . .
C207 C 0.1599(3) 0.1163(2) 0.5533(2) 0.0170(7) Uani 1 1 d . . . . .
C208 C 0.1062(3) 0.1816(3) 0.5374(2) 0.0210(7) Uani 1 1 d . . . . .
H208 H 0.1229 0.2418 0.5757 0.025 Uiso 1 1 calc R U . . .
C209 C 0.0289(3) 0.1578(3) 0.4654(2) 0.0265(8) Uani 1 1 d . . . . .
H209 H -0.0074 0.2018 0.4545 0.032 Uiso 1 1 calc R U . . .
C210 C 0.0041(3) 0.0700(3) 0.4093(2) 0.0287(9) Uani 1 1 d . . . . .
H210 H -0.0482 0.0544 0.3597 0.034 Uiso 1 1 calc R U . . .
C211 C 0.0549(3) 0.0052(3) 0.4250(2) 0.0253(8) Uani 1 1 d . . . . .
H211 H 0.0372 -0.0549 0.3867 0.030 Uiso 1 1 calc R U . . .
C212 C 0.1325(3) 0.0285(2) 0.4974(2) 0.0188(7) Uani 1 1 d . . . . .
H212 H 0.1669 -0.0162 0.5086 0.023 Uiso 1 1 calc R U . . .
C213 C 0.3337(2) 0.2529(2) 0.68020(19) 0.0136(6) Uani 1 1 d . . . . .
H213 H 0.2903 0.3012 0.6957 0.016 Uiso 1 1 calc R U . . .
C214 C 0.3074(3) 0.2738(2) 0.5271(2) 0.0173(7) Uani 1 1 d . . . . .
C215 C 0.2871(3) 0.2066(3) 0.4489(2) 0.0212(7) Uani 1 1 d . . . . .
H215 H 0.3193 0.1547 0.4400 0.025 Uiso 1 1 calc R U . . .
C216 C 0.2199(3) 0.2162(3) 0.3844(2) 0.0265(8) Uani 1 1 d . . . . .
H216 H 0.2064 0.1708 0.3314 0.032 Uiso 1 1 calc R U . . .
C217 C 0.1723(3) 0.2913(3) 0.3968(2) 0.0287(9) Uani 1 1 d . . . . .
H217 H 0.1260 0.2972 0.3524 0.034 Uiso 1 1 calc R U . . .
C218 C 0.1920(3) 0.3584(3) 0.4743(3) 0.0287(9) Uani 1 1 d . . . . .
H218 H 0.1593 0.4100 0.4827 0.034 Uiso 1 1 calc R U . . .
C219 C 0.2598(3) 0.3496(3) 0.5393(2) 0.0222(7) Uani 1 1 d . . . . .
H219 H 0.2735 0.3955 0.5922 0.027 Uiso 1 1 calc R U . . .
C220 C 0.4779(3) 0.3689(2) 0.6646(2) 0.0191(7) Uani 1 1 d . . . . .
C221 C 0.5614(3) 0.3809(3) 0.6385(3) 0.0265(8) Uani 1 1 d . . . . .
H221 H 0.5761 0.3331 0.5957 0.032 Uiso 1 1 calc R U . . .
C222 C 0.6229(3) 0.4626(3) 0.6749(3) 0.0324(9) Uani 1 1 d . . . . .
H222 H 0.6789 0.4710 0.6566 0.039 Uiso 1 1 calc R U . . .
C223 C 0.6022(3) 0.5318(3) 0.7382(3) 0.0356(11) Uani 1 1 d . . . . .
H223 H 0.6454 0.5871 0.7640 0.043 Uiso 1 1 calc R U . . .
C224 C 0.5196(4) 0.5210(3) 0.7638(3) 0.0310(9) Uani 1 1 d . . . . .
H224 H 0.5051 0.5691 0.8064 0.037 Uiso 1 1 calc R U . . .
C225 C 0.4573(3) 0.4395(3) 0.7273(2) 0.0245(8) Uani 1 1 d . . . . .
H225 H 0.4005 0.4321 0.7452 0.029 Uiso 1 1 calc R U . . .
C501 C 0.5461(3) -0.0286(2) 0.7890(2) 0.0198(7) Uani 1 1 d . . . . .
C502 C 0.4796(3) 0.0114(2) 0.8323(2) 0.0231(8) Uani 1 1 d . . . . .
H502 H 0.4159 0.0232 0.8056 0.028 Uiso 1 1 calc R U . . .
C503 C 0.5061(3) 0.0343(3) 0.9146(2) 0.0273(8) Uani 1 1 d . . . . .
H503 H 0.4606 0.0620 0.9442 0.033 Uiso 1 1 calc R U . . .
C504 C 0.5985(4) 0.0169(3) 0.9539(2) 0.0311(9) Uani 1 1 d . . . . .
H504 H 0.6167 0.0335 1.0105 0.037 Uiso 1 1 calc R U . . .
C505 C 0.6643(3) -0.0246(3) 0.9107(2) 0.0285(9) Uani 1 1 d . . . . .
H505 H 0.7274 -0.0371 0.9376 0.034 Uiso 1 1 calc R U . . .
C506 C 0.6387(3) -0.0481(3) 0.8279(2) 0.0225(7) Uani 1 1 d . . . . .
H506 H 0.6837 -0.0772 0.7981 0.027 Uiso 1 1 calc R U . . .
C601 C 0.7491(3) 0.1713(2) 0.5632(2) 0.0197(7) Uani 1 1 d . . . . .
C602 C 0.8209(3) 0.2192(3) 0.6374(3) 0.0339(10) Uani 1 1 d . . . . .
H602 H 0.8254 0.2030 0.6808 0.041 Uiso 1 1 calc R U . . .
C603 C 0.8865(4) 0.2910(3) 0.6483(3) 0.0415(12) Uani 1 1 d . . . . .
H603 H 0.9348 0.3241 0.6997 0.050 Uiso 1 1 calc R U . . .
C604 C 0.8822(3) 0.3146(3) 0.5858(3) 0.0354(10) Uani 1 1 d . . . . .
H604 H 0.9252 0.3650 0.5942 0.043 Uiso 1 1 calc R U . . .
C605 C 0.8147(4) 0.2642(3) 0.5109(3) 0.0390(11) Uani 1 1 d . . . . .
H605 H 0.8140 0.2780 0.4666 0.047 Uiso 1 1 calc R U . . .
C606 C 0.7478(3) 0.1935(3) 0.4993(3) 0.0343(10) Uani 1 1 d . . . . .
H606 H 0.7008 0.1600 0.4474 0.041 Uiso 1 1 calc R U . . .
Cl1 Cl 0.84372(7) 0.27977(6) 1.11379(5) 0.02362(18) Uani 1 1 d . . . . .
Cl11 Cl 1.13775(9) 0.31925(8) 1.07564(7) 0.0379(2) Uani 1 1 d . . . . .
Cl12 Cl 1.15775(12) 0.21436(9) 1.16762(9) 0.0523(3) Uani 1 1 d . . . . .
Cl13 Cl 1.12049(9) 0.39661(8) 1.23805(7) 0.0379(2) Uani 1 1 d . . . . .
C1 C 1.0962(3) 0.2987(3) 1.1485(2) 0.0264(8) Uani 1 1 d . . . . .
H1 H 1.0207 0.2786 1.1266 0.032 Uiso 1 1 calc R U . . .
Cl21 Cl 0.91697(10) 0.20847(11) 1.29145(9) 0.0566(4) Uani 1 1 d . . . . .
Cl22 Cl 0.69964(12) 0.18755(10) 1.27600(9) 0.0543(3) Uani 1 1 d . . . . .
Cl23 Cl 0.77746(10) 0.06922(9) 1.15132(9) 0.0516(3) Uani 1 1 d . . . . .
C2 C 0.7923(3) 0.1787(3) 1.2249(3) 0.0309(9) Uani 1 1 d . . . . .
H2 H 0.7807 0.2193 1.1972 0.037 Uiso 1 1 calc R U . . .
Cl31 Cl 0.95930(11) 0.46745(9) 1.38546(7) 0.0468(3) Uani 1 1 d . . . . .
Cl32 Cl 0.86295(11) 0.54451(8) 1.27691(8) 0.0467(3) Uani 1 1 d . . . . .
Cl33 Cl 0.74418(11) 0.41427(9) 1.29685(10) 0.0543(4) Uani 1 1 d . . . . .
C3 C 0.8650(4) 0.4476(3) 1.2939(3) 0.0334(9) Uani 1 1 d . . . . .
H3 H 0.8825 0.3992 1.2486 0.040 Uiso 1 1 calc R U . . .
Cl41 Cl 0.62793(13) 0.36650(14) 1.45022(10) 0.0681(5) Uani 1 1 d . . . . .
Cl42 Cl 0.46739(14) 0.27865(10) 1.29840(8) 0.0590(4) Uani 1 1 d . . . . .
Cl43 Cl 0.41843(10) 0.39439(9) 1.44128(8) 0.0472(3) Uani 1 1 d . . . . .
C4 C 0.5104(4) 0.3760(4) 1.3899(3) 0.0393(11) Uani 1 1 d . . . . .
H4 H 0.5204 0.4276 1.3767 0.047 Uiso 1 1 calc R U . . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Te Te -0.5308 1.6751 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
-1.00 0.00 -1.00 0.0610
1.00 -1.00 1.00 0.0760
-1.00 1.00 -1.00 0.0590
1.00 -1.00 -1.00 0.0710
-1.00 1.00 1.00 0.0810
-1.00 1.00 0.00 0.0670
1.00 -1.00 0.00 0.0760
0.00 0.00 1.00 0.0790
0.00 1.00 -1.00 0.0180
0.00 -1.00 1.00 0.0070
0.00 -1.00 -1.00 0.0780
0.00 1.00 1.00 0.0870
-1.00 -1.00 1.00 0.0740
1.00 1.00 -1.00 0.0930
1.00 1.00 0.00 0.0860
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle_publ_flag
P11 Au1 Au3 115.62(2) . . ?
P11 Au1 P21 146.74(3) . . ?
P21 Au1 Au3 41.705(17) . . ?
C213 Au1 Au3 70.58(9) . . ?
C213 Au1 P11 172.55(9) . . ?
C213 Au1 P21 36.01(9) . . ?
Au4 Au2 Au3 62.518(5) . . ?
Te1 Au2 Au3 50.405(6) . . ?
Te1 Au2 Au4 102.463(7) . . ?
Te2 Au2 Au3 98.946(6) . . ?
Te2 Au2 Au4 54.075(6) . . ?
Te2 Au2 Te1 101.022(8) . . ?
P12 Au2 Au3 123.76(2) . . ?
P12 Au2 Au4 130.61(2) . . ?
P12 Au2 Te1 117.33(2) . . ?
P12 Au2 Te2 134.55(2) . . ?
Au2 Au3 Au1 70.347(4) . . ?
Au4 Au3 Au1 71.636(5) . . ?
Au4 Au3 Au2 54.102(4) . . ?
Au4 Au3 Te2 66.912(5) . 2_656 ?
Te1 Au3 Au1 113.267(7) . . ?
Te1 Au3 Au2 54.291(6) . . ?
Te1 Au3 Au4 98.535(7) . . ?
Te1 Au3 Te2 84.540(7) . 2_656 ?
Te2 Au3 Au1 136.902(6) 2_656 . ?
Te2 Au3 Au2 93.818(6) 2_656 . ?
P21 Au3 Au1 61.66(2) . . ?
P21 Au3 Au2 125.25(2) . . ?
P21 Au3 Au4 85.80(2) . . ?
P21 Au3 Te1 172.05(2) . . ?
P21 Au3 Te2 103.33(2) . 2_656 ?
Au2 Au4 Au3 63.380(5) . . ?
Te2 Au4 Au2 58.202(6) . . ?
Te2 Au4 Au3 102.399(7) . . ?
P22 Au4 Au2 121.03(2) . . ?
P22 Au4 Au3 87.82(2) . . ?
P22 Au4 Te2 166.48(2) . . ?
Au3 Te1 Au2 75.303(8) . . ?
C501 Te1 Au2 93.76(9) . . ?
C501 Te1 Au3 102.68(10) . . ?
Au2 Te2 Au3 159.203(9) . 2_656 ?
Au4 Te2 Au2 67.723(6) . . ?
Au4 Te2 Au3 113.983(8) . 2_656 ?
C601 Te2 Au2 105.06(10) . . ?
C601 Te2 Au3 95.50(9) . 2_656 ?
C601 Te2 Au4 95.46(10) . . ?
C101 P11 Au1 111.72(12) . . ?
C101 P11 C107 106.34(15) . . ?
C101 P11 C113 101.32(15) . . ?
C107 P11 Au1 109.89(12) . . ?
C107 P11 C113 107.01(16) . . ?
C113 P11 Au1 119.56(11) . . ?
C113 P12 Au2 116.00(11) . . ?
C114 P12 Au2 107.17(11) . . ?
C114 P12 C113 103.94(16) . . ?
C120 P12 Au2 118.89(12) . . ?
C120 P12 C113 104.12(15) . . ?
C120 P12 C114 105.30(16) . . ?
Au3 P21 Au1 76.63(2) . . ?
C201 P21 Au1 88.40(11) . . ?
C201 P21 Au3 113.64(13) . . ?
C201 P21 C207 103.35(16) . . ?
C207 P21 Au1 155.27(12) . . ?
C207 P21 Au3 116.63(12) . . ?
C213 P21 Au1 43.92(10) . . ?
C213 P21 Au3 107.57(11) . . ?
C213 P21 C201 103.38(16) . . ?
C213 P21 C207 111.53(16) . . ?
C213 P22 Au4 113.04(11) . . ?
C213 P22 C214 110.89(16) . . ?
C213 P22 C220 106.16(16) . . ?
C214 P22 Au4 114.29(12) . . ?
C220 P22 Au4 108.95(12) . . ?
C220 P22 C214 102.64(16) . . ?
C102 C101 P11 120.2(3) . . ?
C102 C101 C106 119.1(3) . . ?
C106 C101 P11 120.6(3) . . ?
C101 C102 H102 119.7 . . ?
C103 C102 C101 120.6(3) . . ?
C103 C102 H102 119.7 . . ?
C102 C103 H103 120.0 . . ?
C104 C103 C102 120.0(3) . . ?
C104 C103 H103 120.0 . . ?
C103 C104 H104 120.0 . . ?
C105 C104 C103 120.0(3) . . ?
C105 C104 H104 120.0 . . ?
C104 C105 H105 119.7 . . ?
C104 C105 C106 120.6(4) . . ?
C106 C105 H105 119.7 . . ?
C101 C106 H106 120.2 . . ?
C105 C106 C101 119.7(3) . . ?
C105 C106 H106 120.2 . . ?
C108 C107 P11 118.0(3) . . ?
C108 C107 C112 119.1(3) . . ?
C112 C107 P11 122.9(3) . . ?
C107 C108 H108 119.7 . . ?
C109 C108 C107 120.7(4) . . ?
C109 C108 H108 119.7 . . ?
C108 C109 H109 119.9 . . ?
C110 C109 C108 120.3(4) . . ?
C110 C109 H109 119.9 . . ?
C109 C110 H110 120.2 . . ?
C109 C110 C111 119.6(4) . . ?
C111 C110 H110 120.2 . . ?
C110 C111 H111 119.7 . . ?
C110 C111 C112 120.7(4) . . ?
C112 C111 H111 119.7 . . ?
C107 C112 H112 120.2 . . ?
C111 C112 C107 119.7(3) . . ?
C111 C112 H112 120.2 . . ?
P11 C113 P12 117.22(19) . . ?
P11 C113 H11A 108.0 . . ?
P11 C113 H11B 108.0 . . ?
P12 C113 H11A 108.0 . . ?
P12 C113 H11B 108.0 . . ?
H11A C113 H11B 107.2 . . ?
C115 C114 P12 122.7(3) . . ?
C115 C114 C119 119.3(3) . . ?
C119 C114 P12 117.9(3) . . ?
C114 C115 H115 120.0 . . ?
C116 C115 C114 120.0(3) . . ?
C116 C115 H115 120.0 . . ?
C115 C116 H116 119.8 . . ?
C117 C116 C115 120.3(4) . . ?
C117 C116 H116 119.8 . . ?
C116 C117 H117 120.0 . . ?
C118 C117 C116 120.0(4) . . ?
C118 C117 H117 120.0 . . ?
C117 C118 H118 119.8 . . ?
C117 C118 C119 120.4(4) . . ?
C119 C118 H118 119.8 . . ?
C114 C119 H119 120.0 . . ?
C118 C119 C114 119.9(3) . . ?
C118 C119 H119 120.0 . . ?
C121 C120 P12 121.4(3) . . ?
C125 C120 P12 119.2(3) . . ?
C125 C120 C121 119.3(3) . . ?
C120 C121 H121 120.0 . . ?
C122 C121 C120 120.1(3) . . ?
C122 C121 H121 120.0 . . ?
C121 C122 H122 120.0 . . ?
C123 C122 C121 119.9(4) . . ?
C123 C122 H122 120.0 . . ?
C122 C123 H123 119.8 . . ?
C124 C123 C122 120.3(4) . . ?
C124 C123 H123 119.8 . . ?
C123 C124 H124 120.0 . . ?
C123 C124 C125 120.1(4) . . ?
C125 C124 H124 120.0 . . ?
C120 C125 C124 120.2(4) . . ?
C120 C125 H125 119.9 . . ?
C124 C125 H125 119.9 . . ?
C202 C201 P21 120.6(3) . . ?
C206 C201 P21 120.4(3) . . ?
C206 C201 C202 118.9(3) . . ?
C201 C202 H202 119.7 . . ?
C203 C202 C201 120.7(4) . . ?
C203 C202 H202 119.7 . . ?
C202 C203 H203 120.0 . . ?
C204 C203 C202 120.0(4) . . ?
C204 C203 H203 120.0 . . ?
C203 C204 H204 120.0 . . ?
C203 C204 C205 119.9(4) . . ?
C205 C204 H204 120.0 . . ?
C204 C205 H205 119.6 . . ?
C204 C205 C206 120.8(4) . . ?
C206 C205 H205 119.6 . . ?
C201 C206 C205 119.7(4) . . ?
C201 C206 H206 120.1 . . ?
C205 C206 H206 120.1 . . ?
C208 C207 P21 121.2(3) . . ?
C212 C207 P21 119.5(3) . . ?
C212 C207 C208 119.2(3) . . ?
C207 C208 H208 120.2 . . ?
C209 C208 C207 119.7(4) . . ?
C209 C208 H208 120.2 . . ?
C208 C209 H209 119.8 . . ?
C208 C209 C210 120.4(4) . . ?
C210 C209 H209 119.8 . . ?
C209 C210 H210 119.8 . . ?
C211 C210 C209 120.4(4) . . ?
C211 C210 H210 119.8 . . ?
C210 C211 H211 120.2 . . ?
C210 C211 C212 119.6(4) . . ?
C212 C211 H211 120.2 . . ?
C207 C212 C211 120.6(4) . . ?
C207 C212 H212 119.7 . . ?
C211 C212 H212 119.7 . . ?
Au1 C213 H213 111.7 . . ?
P21 C213 Au1 100.08(15) . . ?
P21 C213 H213 111.7 . . ?
P22 C213 Au1 106.69(15) . . ?
P22 C213 P21 114.37(18) . . ?
P22 C213 H213 111.7 . . ?
C215 C214 P22 119.8(3) . . ?
C219 C214 P22 120.7(3) . . ?
C219 C214 C215 119.6(3) . . ?
C214 C215 H215 120.1 . . ?
C216 C215 C214 119.8(4) . . ?
C216 C215 H215 120.1 . . ?
C215 C216 H216 119.8 . . ?
C217 C216 C215 120.5(4) . . ?
C217 C216 H216 119.8 . . ?
C216 C217 H217 119.9 . . ?
C216 C217 C218 120.2(4) . . ?
C218 C217 H217 119.9 . . ?
C217 C218 H218 120.1 . . ?
C217 C218 C219 119.8(4) . . ?
C219 C218 H218 120.1 . . ?
C214 C219 H219 119.9 . . ?
C218 C219 C214 120.2(4) . . ?
C218 C219 H219 119.9 . . ?
C221 C220 P22 117.9(3) . . ?
C225 C220 P22 122.7(3) . . ?
C225 C220 C221 119.3(4) . . ?
C220 C221 H221 119.9 . . ?
C222 C221 C220 120.1(4) . . ?
C222 C221 H221 119.9 . . ?
C221 C222 H222 120.1 . . ?
C223 C222 C221 119.8(4) . . ?
C223 C222 H222 120.1 . . ?
C222 C223 H223 119.7 . . ?
C224 C223 C222 120.5(4) . . ?
C224 C223 H223 119.7 . . ?
C223 C224 H224 120.0 . . ?
C223 C224 C225 120.1(4) . . ?
C225 C224 H224 120.0 . . ?
C220 C225 C224 120.2(4) . . ?
C220 C225 H225 119.9 . . ?
C224 C225 H225 119.9 . . ?
C502 C501 Te1 121.6(3) . . ?
C502 C501 C506 120.1(4) . . ?
C506 C501 Te1 118.3(3) . . ?
C501 C502 H502 120.1 . . ?
C501 C502 C503 119.9(4) . . ?
C503 C502 H502 120.1 . . ?
C502 C503 H503 119.7 . . ?
C504 C503 C502 120.5(4) . . ?
C504 C503 H503 119.7 . . ?
C503 C504 H504 120.1 . . ?
C505 C504 C503 119.8(4) . . ?
C505 C504 H504 120.1 . . ?
C504 C505 H505 119.8 . . ?
C504 C505 C506 120.4(4) . . ?
C506 C505 H505 119.8 . . ?
C501 C506 H506 120.4 . . ?
C505 C506 C501 119.3(4) . . ?
C505 C506 H506 120.4 . . ?
C602 C601 Te2 120.8(3) . . ?
C602 C601 C606 118.7(4) . . ?
C606 C601 Te2 120.5(3) . . ?
C601 C602 H602 119.9 . . ?
C601 C602 C603 120.1(4) . . ?
C603 C602 H602 119.9 . . ?
C602 C603 H603 119.6 . . ?
C604 C603 C602 120.8(4) . . ?
C604 C603 H603 119.6 . . ?
C603 C604 H604 120.4 . . ?
C603 C604 C605 119.2(4) . . ?
C605 C604 H604 120.4 . . ?
C604 C605 H605 119.7 . . ?
C604 C605 C606 120.7(4) . . ?
C606 C605 H605 119.7 . . ?
C601 C606 H606 119.8 . . ?
C605 C606 C601 120.4(4) . . ?
C605 C606 H606 119.8 . . ?
Cl11 C1 H1 108.6 . . ?
Cl12 C1 Cl11 109.9(2) . . ?
Cl12 C1 Cl13 110.8(2) . . ?
Cl12 C1 H1 108.6 . . ?
Cl13 C1 Cl11 110.2(2) . . ?
Cl13 C1 H1 108.6 . . ?
Cl21 C2 Cl22 111.8(3) . . ?
Cl21 C2 Cl23 110.0(3) . . ?
Cl21 C2 H2 108.6 . . ?
Cl22 C2 Cl23 109.3(2) . . ?
Cl22 C2 H2 108.6 . . ?
Cl23 C2 H2 108.6 . . ?
Cl31 C3 H3 108.9 . . ?
Cl32 C3 Cl31 109.6(2) . . ?
Cl32 C3 H3 108.9 . . ?
Cl33 C3 Cl31 110.4(3) . . ?
Cl33 C3 Cl32 110.2(3) . . ?
Cl33 C3 H3 108.9 . . ?
Cl41 C4 Cl42 110.2(3) . . ?
Cl41 C4 H4 108.7 . . ?
Cl42 C4 H4 108.7 . . ?
Cl43 C4 Cl41 110.7(3) . . ?
Cl43 C4 Cl42 109.9(3) . . ?
Cl43 C4 H4 108.7 . . ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
_geom_bond_publ_flag
Au1 Au3 3.3508(2) . ?
Au1 P11 2.2899(9) . ?
Au1 P21 3.0315(9) . ?
Au1 C213 2.136(3) . ?
Au2 Au3 3.2605(2) . ?
Au2 Au4 2.9544(2) . ?
Au2 Te1 2.7371(3) . ?
Au2 Te2 2.7135(3) . ?
Au2 P12 2.2989(8) . ?
Au3 Au4 3.2356(2) . ?
Au3 Te1 2.5974(3) . ?
Au3 Te2 3.2380(3) 2_656 ?
Au3 P21 2.2914(9) . ?
Au4 Te2 2.5854(3) . ?
Au4 P22 2.2762(9) . ?
Te1 C501 2.130(4) . ?
Te2 Au3 3.2380(3) 2_656 ?
Te2 C601 2.149(4) . ?
P11 C101 1.816(3) . ?
P11 C107 1.817(4) . ?
P11 C113 1.825(3) . ?
P12 C113 1.828(3) . ?
P12 C114 1.824(4) . ?
P12 C120 1.820(3) . ?
P21 C201 1.820(3) . ?
P21 C207 1.820(3) . ?
P21 C213 1.810(3) . ?
P22 C213 1.794(3) . ?
P22 C214 1.825(4) . ?
P22 C220 1.816(4) . ?
C101 C102 1.393(5) . ?
C101 C106 1.406(5) . ?
C102 H102 0.9500 . ?
C102 C103 1.388(5) . ?
C103 H103 0.9500 . ?
C103 C104 1.385(6) . ?
C104 H104 0.9500 . ?
C104 C105 1.384(6) . ?
C105 H105 0.9500 . ?
C105 C106 1.390(5) . ?
C106 H106 0.9500 . ?
C107 C108 1.394(5) . ?
C107 C112 1.403(5) . ?
C108 H108 0.9500 . ?
C108 C109 1.386(5) . ?
C109 H109 0.9500 . ?
C109 C110 1.383(6) . ?
C110 H110 0.9500 . ?
C110 C111 1.390(6) . ?
C111 H111 0.9500 . ?
C111 C112 1.391(5) . ?
C112 H112 0.9500 . ?
C113 H11A 0.9900 . ?
C113 H11B 0.9900 . ?
C114 C115 1.398(5) . ?
C114 C119 1.405(5) . ?
C115 H115 0.9500 . ?
C115 C116 1.393(5) . ?
C116 H116 0.9500 . ?
C116 C117 1.390(6) . ?
C117 H117 0.9500 . ?
C117 C118 1.382(6) . ?
C118 H118 0.9500 . ?
C118 C119 1.391(5) . ?
C119 H119 0.9500 . ?
C120 C121 1.398(5) . ?
C120 C125 1.389(5) . ?
C121 H121 0.9500 . ?
C121 C122 1.391(5) . ?
C122 H122 0.9500 . ?
C122 C123 1.386(6) . ?
C123 H123 0.9500 . ?
C123 C124 1.376(6) . ?
C124 H124 0.9500 . ?
C124 C125 1.394(5) . ?
C125 H125 0.9500 . ?
C201 C202 1.396(5) . ?
C201 C206 1.385(5) . ?
C202 H202 0.9500 . ?
C202 C203 1.391(6) . ?
C203 H203 0.9500 . ?
C203 C204 1.373(6) . ?
C204 H204 0.9500 . ?
C204 C205 1.375(6) . ?
C205 H205 0.9500 . ?
C205 C206 1.400(5) . ?
C206 H206 0.9500 . ?
C207 C208 1.406(5) . ?
C207 C212 1.388(5) . ?
C208 H208 0.9500 . ?
C208 C209 1.385(5) . ?
C209 H209 0.9500 . ?
C209 C210 1.388(6) . ?
C210 H210 0.9500 . ?
C210 C211 1.378(6) . ?
C211 H211 0.9500 . ?
C211 C212 1.393(5) . ?
C212 H212 0.9500 . ?
C213 H213 1.0000 . ?
C214 C215 1.401(5) . ?
C214 C219 1.393(5) . ?
C215 H215 0.9500 . ?
C215 C216 1.386(5) . ?
C216 H216 0.9500 . ?
C216 C217 1.381(6) . ?
C217 H217 0.9500 . ?
C217 C218 1.391(6) . ?
C218 H218 0.9500 . ?
C218 C219 1.391(5) . ?
C219 H219 0.9500 . ?
C220 C221 1.400(5) . ?
C220 C225 1.392(5) . ?
C221 H221 0.9500 . ?
C221 C222 1.390(6) . ?
C222 H222 0.9500 . ?
C222 C223 1.386(7) . ?
C223 H223 0.9500 . ?
C223 C224 1.377(7) . ?
C224 H224 0.9500 . ?
C224 C225 1.392(6) . ?
C225 H225 0.9500 . ?
C501 C502 1.384(5) . ?
C501 C506 1.400(5) . ?
C502 H502 0.9500 . ?
C502 C503 1.386(6) . ?
C503 H503 0.9500 . ?
C503 C504 1.384(7) . ?
C504 H504 0.9500 . ?
C504 C505 1.384(6) . ?
C505 H505 0.9500 . ?
C505 C506 1.393(6) . ?
C506 H506 0.9500 . ?
C601 C602 1.384(5) . ?
C601 C606 1.394(6) . ?
C602 H602 0.9500 . ?
C602 C603 1.393(6) . ?
C603 H603 0.9500 . ?
C603 C604 1.375(7) . ?
C604 H604 0.9500 . ?
C604 C605 1.376(7) . ?
C605 H605 0.9500 . ?
C605 C606 1.384(6) . ?
C606 H606 0.9500 . ?
Cl11 C1 1.767(4) . ?
Cl12 C1 1.757(4) . ?
Cl13 C1 1.762(4) . ?
C1 H1 1.0000 . ?
Cl21 C2 1.753(4) . ?
Cl22 C2 1.761(5) . ?
Cl23 C2 1.761(5) . ?
C2 H2 1.0000 . ?
Cl31 C3 1.765(5) . ?
Cl32 C3 1.763(5) . ?
Cl33 C3 1.756(5) . ?
C3 H3 1.0000 . ?
Cl41 C4 1.758(5) . ?
Cl42 C4 1.774(6) . ?
Cl43 C4 1.745(5) . ?
C4 H4 1.0000 . ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion_publ_flag
Au1 P11 C101 C102 1.7(3) . . . . ?
Au1 P11 C101 C106 -179.7(2) . . . . ?
Au1 P11 C107 C108 18.5(3) . . . . ?
Au1 P11 C107 C112 -162.1(3) . . . . ?
Au1 P11 C113 P12 42.1(2) . . . . ?
Au1 P21 C201 C202 92.2(3) . . . . ?
Au1 P21 C201 C206 -90.4(3) . . . . ?
Au1 P21 C207 C208 -40.0(5) . . . . ?
Au1 P21 C207 C212 141.0(2) . . . . ?
Au1 P21 C213 P22 113.6(2) . . . . ?
Au2 P12 C113 P11 -65.4(2) . . . . ?
Au2 P12 C114 C115 -152.8(3) . . . . ?
Au2 P12 C114 C119 27.1(3) . . . . ?
Au2 P12 C120 C121 -146.6(2) . . . . ?
Au2 P12 C120 C125 33.4(3) . . . . ?
Au3 P21 C201 C202 166.8(3) . . . . ?
Au3 P21 C201 C206 -15.7(3) . . . . ?
Au3 P21 C207 C208 -158.0(3) . . . . ?
Au3 P21 C207 C212 23.0(3) . . . . ?
Au3 P21 C213 Au1 -47.28(14) . . . . ?
Au3 P21 C213 P22 66.35(18) . . . . ?
Au4 P22 C213 Au1 57.64(16) . . . . ?
Au4 P22 C213 P21 -52.0(2) . . . . ?
Au4 P22 C214 C215 15.0(3) . . . . ?
Au4 P22 C214 C219 -164.0(3) . . . . ?
Au4 P22 C220 C221 36.0(3) . . . . ?
Au4 P22 C220 C225 -146.7(3) . . . . ?
Te1 C501 C502 C503 -175.6(3) . . . . ?
Te1 C501 C506 C505 175.5(3) . . . . ?
Te2 C601 C602 C603 -178.7(4) . . . . ?
Te2 C601 C606 C605 179.7(4) . . . . ?
P11 C101 C102 C103 178.7(3) . . . . ?
P11 C101 C106 C105 -178.1(3) . . . . ?
P11 C107 C108 C109 179.5(3) . . . . ?
P11 C107 C112 C111 180.0(3) . . . . ?
P12 C114 C115 C116 179.8(3) . . . . ?
P12 C114 C119 C118 -179.2(3) . . . . ?
P12 C120 C121 C122 178.0(3) . . . . ?
P12 C120 C125 C124 -179.9(3) . . . . ?
P21 C201 C202 C203 178.6(3) . . . . ?
P21 C201 C206 C205 -178.1(3) . . . . ?
P21 C207 C208 C209 179.3(3) . . . . ?
P21 C207 C212 C211 -178.9(3) . . . . ?
P22 C214 C215 C216 -178.9(3) . . . . ?
P22 C214 C219 C218 179.2(3) . . . . ?
P22 C220 C221 C222 177.5(3) . . . . ?
P22 C220 C225 C224 -177.7(3) . . . . ?
C101 P11 C107 C108 -102.6(3) . . . . ?
C101 P11 C107 C112 76.9(3) . . . . ?
C101 P11 C113 P12 165.31(19) . . . . ?
C101 C102 C103 C104 -0.3(6) . . . . ?
C102 C101 C106 C105 0.6(5) . . . . ?
C102 C103 C104 C105 0.1(6) . . . . ?
C103 C104 C105 C106 0.5(6) . . . . ?
C104 C105 C106 C101 -0.8(6) . . . . ?
C106 C101 C102 C103 0.0(5) . . . . ?
C107 P11 C101 C102 121.6(3) . . . . ?
C107 P11 C101 C106 -59.8(3) . . . . ?
C107 P11 C113 P12 -83.5(2) . . . . ?
C107 C108 C109 C110 0.3(7) . . . . ?
C108 C107 C112 C111 -0.6(5) . . . . ?
C108 C109 C110 C111 -0.2(7) . . . . ?
C109 C110 C111 C112 -0.3(7) . . . . ?
C110 C111 C112 C107 0.7(6) . . . . ?
C112 C107 C108 C109 0.1(6) . . . . ?
C113 P11 C101 C102 -126.8(3) . . . . ?
C113 P11 C101 C106 51.9(3) . . . . ?
C113 P11 C107 C108 149.8(3) . . . . ?
C113 P11 C107 C112 -30.8(3) . . . . ?
C113 P12 C114 C115 -29.5(3) . . . . ?
C113 P12 C114 C119 150.4(3) . . . . ?
C113 P12 C120 C121 82.5(3) . . . . ?
C113 P12 C120 C125 -97.5(3) . . . . ?
C114 P12 C113 P11 177.28(18) . . . . ?
C114 P12 C120 C121 -26.6(3) . . . . ?
C114 P12 C120 C125 153.5(3) . . . . ?
C114 C115 C116 C117 -0.6(6) . . . . ?
C115 C114 C119 C118 0.8(5) . . . . ?
C115 C116 C117 C118 0.8(6) . . . . ?
C116 C117 C118 C119 -0.2(6) . . . . ?
C117 C118 C119 C114 -0.6(6) . . . . ?
C119 C114 C115 C116 -0.1(5) . . . . ?
C120 P12 C113 P11 67.2(2) . . . . ?
C120 P12 C114 C115 79.7(3) . . . . ?
C120 P12 C114 C119 -100.4(3) . . . . ?
C120 C121 C122 C123 1.8(5) . . . . ?
C121 C120 C125 C124 0.1(6) . . . . ?
C121 C122 C123 C124 0.3(6) . . . . ?
C122 C123 C124 C125 -2.2(7) . . . . ?
C123 C124 C125 C120 2.0(7) . . . . ?
C125 C120 C121 C122 -2.0(5) . . . . ?
C201 P21 C207 C208 76.5(3) . . . . ?
C201 P21 C207 C212 -102.5(3) . . . . ?
C201 P21 C213 Au1 73.24(17) . . . . ?
C201 P21 C213 P22 -173.14(18) . . . . ?
C201 C202 C203 C204 -1.0(7) . . . . ?
C202 C201 C206 C205 -0.6(6) . . . . ?
C202 C203 C204 C205 0.5(7) . . . . ?
C203 C204 C205 C206 0.0(6) . . . . ?
C204 C205 C206 C201 0.1(6) . . . . ?
C206 C201 C202 C203 1.1(6) . . . . ?
C207 P21 C201 C202 -65.8(3) . . . . ?
C207 P21 C201 C206 111.6(3) . . . . ?
C207 P21 C213 Au1 -176.35(14) . . . . ?
C207 P21 C213 P22 -62.7(2) . . . . ?
C207 C208 C209 C210 0.1(6) . . . . ?
C208 C207 C212 C211 2.1(5) . . . . ?
C208 C209 C210 C211 1.1(6) . . . . ?
C209 C210 C211 C212 -0.8(6) . . . . ?
C210 C211 C212 C207 -0.9(5) . . . . ?
C212 C207 C208 C209 -1.7(5) . . . . ?
C213 P21 C201 C202 50.5(3) . . . . ?
C213 P21 C201 C206 -132.0(3) . . . . ?
C213 P21 C207 C208 -33.9(3) . . . . ?
C213 P21 C207 C212 147.1(3) . . . . ?
C213 P22 C214 C215 -114.2(3) . . . . ?
C213 P22 C214 C219 66.8(3) . . . . ?
C213 P22 C220 C221 158.0(3) . . . . ?
C213 P22 C220 C225 -24.6(3) . . . . ?
C214 P22 C213 Au1 -172.52(15) . . . . ?
C214 P22 C213 P21 77.8(2) . . . . ?
C214 P22 C220 C221 -85.5(3) . . . . ?
C214 P22 C220 C225 91.8(3) . . . . ?
C214 C215 C216 C217 -0.4(6) . . . . ?
C215 C214 C219 C218 0.3(6) . . . . ?
C215 C216 C217 C218 0.4(6) . . . . ?
C216 C217 C218 C219 -0.1(6) . . . . ?
C217 C218 C219 C214 -0.3(6) . . . . ?
C219 C214 C215 C216 0.0(6) . . . . ?
C220 P22 C213 Au1 -61.76(19) . . . . ?
C220 P22 C213 P21 -171.41(18) . . . . ?
C220 P22 C214 C215 132.8(3) . . . . ?
C220 P22 C214 C219 -46.2(3) . . . . ?
C220 C221 C222 C223 1.0(6) . . . . ?
C221 C220 C225 C224 -0.4(6) . . . . ?
C221 C222 C223 C224 -1.7(7) . . . . ?
C222 C223 C224 C225 1.3(7) . . . . ?
C223 C224 C225 C220 -0.3(6) . . . . ?
C225 C220 C221 C222 0.1(6) . . . . ?
C501 C502 C503 C504 -0.3(6) . . . . ?
C502 C501 C506 C505 -1.9(5) . . . . ?
C502 C503 C504 C505 -0.9(6) . . . . ?
C503 C504 C505 C506 0.8(6) . . . . ?
C504 C505 C506 C501 0.6(6) . . . . ?
C506 C501 C502 C503 1.7(5) . . . . ?
C601 C602 C603 C604 -1.0(8) . . . . ?
C602 C601 C606 C605 -2.3(7) . . . . ?
C602 C603 C604 C605 -2.5(8) . . . . ?
C603 C604 C605 C606 3.6(8) . . . . ?
C604 C605 C606 C601 -1.1(8) . . . . ?
C606 C601 C602 C603 3.4(7) . . . . ?
