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1554391 CIFC52 H70 Mg2 N4P c c n17.7085; 33.2898; 17.0054
90; 90; 90
10024.9Li, Jia; Luo, Man; Sheng, Xingchao; Hua, Haiming; Yao, Weiwei; Pullarkat, Sumod A.; Xu, Li; Ma, Mengtao
Unsymmetrical β-diketiminate magnesium(i) complexes: syntheses and application in catalytic hydroboration of alkyne, nitrile and carbonyl compounds
Organic Chemistry Frontiers, 2018, 5, 3538
1554392 CIFC30 H21 Cl N2 O2P -18.5511; 10.4286; 14.3935
88.875; 87.601; 68.209
1190.78Xu, Hui; Chen, Kuan; Liu, Hong-Wei; Wang, Guan-Wu
Solvent-free N-iodosuccinimide-promoted synthesis of spiroimidazolines from alkenes and amidines under ball-milling conditions
Organic Chemistry Frontiers, 2018, 5, 2864
1554393 CIFC22 H24 Cl3 F6 N4 P RuP 1 21/n 18.1716; 30.1115; 10.9853
90; 95.159; 90
2692.1Wu, Qiang; Pan, Le; Du, Guangming; Zhang, Chi; Wang, Dawei
Preparation of pyridyltriazole ruthenium complexes as effective catalysts for the selective alkylation and one-pot C‒H hydroxylation of 2-oxindole with alcohols and mechanism exploration
Organic Chemistry Frontiers, 2018, 5, 2668
1554394 CIFC17 H13 F2 N O2P b c a8.3324; 18.0049; 18.9382
90; 90; 90
2841.2Ma, Xingxing; Deng, Shuilin; Song, Qiuling
Halodifluoroacetates as formylation reagents for various amines via unprecedented quadruple cleavage
Organic Chemistry Frontiers, 2018, 5, 3505
1554395 CIFC14 H17 N OP -16.32; 11.047; 16.999
90.548; 95.825; 90.542
1180.6Liu, Yang; Cerveri, Alessandro; De Nisi, Assunta; Monari, Magda; Nieto Faza, Olalla; Lopez, Carlos Silva; Bandini, Marco
Nickel catalyzed regio- and stereoselective arylation and methylation of allenamides via coupling reactions. An experimental and computational study
Organic Chemistry Frontiers, 2018, 5, 3231
1554396 CIFC12 H26 Cl2 N2 Ni O7P -16.9966; 12.0579; 12.9998
63.724; 88.61; 86.344
981.4Liu, Yang; Cerveri, Alessandro; De Nisi, Assunta; Monari, Magda; Nieto Faza, Olalla; Lopez, Carlos Silva; Bandini, Marco
Nickel catalyzed regio- and stereoselective arylation and methylation of allenamides via coupling reactions. An experimental and computational study
Organic Chemistry Frontiers, 2018, 5, 3231
1554397 CIFC22 H25 N O6P 1 21/c 110.9821; 9.771; 21.137
90; 119.629; 90
1971.56Boichenko, Maksim A.; Ivanova, Olga A.; Andreev, Ivan A.; Chagarovskiy, Alexey O.; Levina, Irina I.; Rybakov, Victor B.; Skvortsov, Dmitriy A.; Trushkov, Igor V.
Convenient approach to polyoxygenated dibenzo[c,e]pyrrolo[1,2-a]azepines from donor–acceptor cyclopropanes
Organic Chemistry Frontiers, 2018, 5, 2829
1554398 CIFC23 H29 N O7P 1 c 17.0556; 15.3824; 10.7866
90; 108.471; 90
1110.38Boichenko, Maksim A.; Ivanova, Olga A.; Andreev, Ivan A.; Chagarovskiy, Alexey O.; Levina, Irina I.; Rybakov, Victor B.; Skvortsov, Dmitriy A.; Trushkov, Igor V.
Convenient approach to polyoxygenated dibenzo[c,e]pyrrolo[1,2-a]azepines from donor–acceptor cyclopropanes
Organic Chemistry Frontiers, 2018, 5, 2829
1554399 CIFC22 H25 N O6P 1 21/c 115.7969; 8.7827; 14.6012
90; 103.801; 90
1967.28Boichenko, Maksim A.; Ivanova, Olga A.; Andreev, Ivan A.; Chagarovskiy, Alexey O.; Levina, Irina I.; Rybakov, Victor B.; Skvortsov, Dmitriy A.; Trushkov, Igor V.
Convenient approach to polyoxygenated dibenzo[c,e]pyrrolo[1,2-a]azepines from donor–acceptor cyclopropanes
Organic Chemistry Frontiers, 2018, 5, 2829
1554400 CIFC43 H26 N2 O2P -19.516; 11.551; 13.616
91.24; 106.05; 99.94
1412.9Kupietz, Kamil; Białek, Michał J.; Białońska, Agata; Szyszko, Bartosz; Latos-Grażyński, Lechosław
Aromaticity control via modifications of a macrocyclic frame: 5,6-dimethoxyphenanthriporphyrin and 5,6-dioxophenanthriporphyrin
Organic Chemistry Frontiers, 2018, 5, 3068
1554401 CIFC61 H45 B F4 N2 O2P 1 21/n 114.154; 17.553; 19.832
90; 106.78; 90
4717.4Kupietz, Kamil; Białek, Michał J.; Białońska, Agata; Szyszko, Bartosz; Latos-Grażyński, Lechosław
Aromaticity control via modifications of a macrocyclic frame: 5,6-dimethoxyphenanthriporphyrin and 5,6-dioxophenanthriporphyrin
Organic Chemistry Frontiers, 2018, 5, 3068
1554402 CIFC86 H54 B8 F22 N4 O7P -18.09; 12.074; 24.254
82.58; 89.11; 70.85
2218.3Kupietz, Kamil; Białek, Michał J.; Białońska, Agata; Szyszko, Bartosz; Latos-Grażyński, Lechosław
Aromaticity control via modifications of a macrocyclic frame: 5,6-dimethoxyphenanthriporphyrin and 5,6-dioxophenanthriporphyrin
Organic Chemistry Frontiers, 2018, 5, 3068
1554404 CIFC29 H37 N O7P 1 21 112.2892; 11.6999; 19.3795
90; 103.521; 90
2709.2Fan, Yaqin; Wang, Yi; Fu, Peng; Chairoungdua, Arthit; Piyachaturawat, Pawinee; Zhu, Weiming
Secopaxilline A, an indole-diterpenoid derivative from an aciduric Penicillium fungus, its identification and semisynthesis
Organic Chemistry Frontiers, 2018, 5, 2835
1554405 CIFC28 H24 O5P 1 21/n 19.5523; 9.8572; 23.9209
90; 99.141; 90
2223.76Zhao, Yinsong; Zheng, Qinze; Yu, Chuangui; Liu, Zheng; Wang, Deping; You, Jingsong; Gao, Ge
Rh(iii)-Catalyzed regioselective C–H [4 + 2] C-annulation of vinyl enaminones with alkynes to form polysubstituted salicylaldehydes
Organic Chemistry Frontiers, 2018, 5, 2875
1554406 CIFC30 H31 Br N2 O3P 1 21 113.248; 7.6262; 27.213
90; 97.298; 90
2727.1Yuan, Yang; Zheng, Zhan-Jiang; Ye, Fei; Ma, Jun-Han; Xu, Zheng; Bai, Xing-Feng; Li, Li; Xu, Li-Wen
Highly efficient desymmetrization of cyclopropenes to azabicyclo[3.1.0]hexanes with five continuous stereogenic centers by copper-catalyzed [3 + 2] cycloadditions
Organic Chemistry Frontiers, 2018, 5, 2759
1554407 CIFC23 H28 O6P 1 21 17.3005; 12.1224; 11.9121
90; 105.259; 90
1017.05Zhang, Xun; Li, Zhongle; Yong, Huaya; Xie, Zhixiang
Biomimetic syntheses of C23 terpenoids: structural revision of salyunnanin A and confirmation of hassanane
Organic Chemistry Frontiers, 2018, 5, 3469
1554408 CIFC14 H10 Br N O4P b c a7.5983; 16.424; 20.8458
90; 90; 90
2601.44Maezono, Shizuka Mei Bautista; Kim, Sung Hong; Lee, Yong Rok
Copper-catalyzed [3 + 2 + 1] annulation for functionalized pyridines as potent and dynamic UV absorbers
Organic Chemistry Frontiers, 2018, 5, 3368
1554409 CIFC18 H18 O2P 1 21/n 19.0575; 12.288; 12.993
90; 94.793; 90
1441Yang, Binmiao; Zhai, Xuejie; Feng, Shubo; Shao, Zhihui
Dearomatization of naphthols using oxy-allyl cations: efficient construction of α-all-carbon quaternary center-containing 2-(2-oxocycloalkyl)cycloalkyl diketones
Organic Chemistry Frontiers, 2018, 5, 2794
1554410 CIFC44 H42 Cl N5 O8P -117.135; 17.343; 20.802
106.696; 98.131; 118.106
4934.7Yang, Wen-Juan; Sun, Qiu; Sun, Jing; Yan, Chao-Guo
Domino aza/oxa-hetero-Diels–Alder reaction for construction of novel spiro[pyrido[3′,2′:5,6]pyrano[2,3-d]pyrimidine-7,5′-pyrimidine]
Organic Chemistry Frontiers, 2018, 5, 2754
1554411 CIFC42 H38 Cl N5 O6P -112.086; 12.455; 17.13
96.558; 109.996; 107.812
2236.9Yang, Wen-Juan; Sun, Qiu; Sun, Jing; Yan, Chao-Guo
Domino aza/oxa-hetero-Diels–Alder reaction for construction of novel spiro[pyrido[3′,2′:5,6]pyrano[2,3-d]pyrimidine-7,5′-pyrimidine]
Organic Chemistry Frontiers, 2018, 5, 2754
1554412 CIFC28 H22P -19.7638; 10.0633; 10.6246
100.341; 103.17; 95.285
990.28Chuskit, Deachen; Chaudhary, Renu; Venugopalan, Paloth; König, Burkhard; Natarajan, Palani
Oxidative homodimerization of substituted olefins by DDQ visible light photocatalysis
Organic Chemistry Frontiers, 2018, 5, 3553
1554413 CIFC18 H25 N O7 SP 1 21/c 110; 14.827; 13.344
90; 101.939; 90
1935.7Lei, Meng; Li, Yanjun; Cao, Shi; Hou, Xinyi; Gong, Lei
Alkylation–peroxidation of α-carbonyl imines or ketones catalyzed by a copper salt via radical-mediated Csp3–H functionalization
Organic Chemistry Frontiers, 2018, 5, 3083
1554414 CIFC19 H24 F3 N O2P -112.1127; 13.1333; 13.1505
76.939; 79.228; 63.194
1810.2Long, Hao; Song, Jinshuai; Xu, Hai-Chao
Electrochemical synthesis of 7-membered carbocycles through cascade 5-exo-trig/7-endo-trig radical cyclization
Organic Chemistry Frontiers, 2018, 5, 3129
1554415 CIFC30 H29 N3 O4 SP 1 21 18.6306; 10.9636; 14.5139
90; 90.644; 90
1373.25Huang, Qiuhong; Cheng, Yuyu; Yuan, Huijun; Chang, Xiaoyong; Li, Pengfei; Li, Wenjun
Organocatalytic enantioselective Mannich-type addition of 5H-thiazol-4-ones to isatin-derived imines: access to 3-substituted 3-amino-2-oxindoles featured by vicinal sulfur-containing tetrasubstituted stereocenters
Organic Chemistry Frontiers, 2018, 5, 3226
1554416 CIFC24 H22 N4 O4P 1 21/c 118.2546; 9.1982; 13.3199
90; 108.231; 90
2124.27Qiu, Shaobing; Guo, Chunlei; Wang, Mingkang; Sun, Zhenglong; Li, Hui; Qian, Xuhong; Yang, Youjun
Mild dealkylative N-nitrosation of N,N-dialkylaniline derivatives for convenient preparation of photo-triggered and photo-calibrated NO donors
Organic Chemistry Frontiers, 2018, 5, 3206
1554417 CIFC12 H12 N2 O3P 1 21/c 111.2278; 13.7389; 7.4364
90; 107.173; 90
1095.98Qiu, Shaobing; Guo, Chunlei; Wang, Mingkang; Sun, Zhenglong; Li, Hui; Qian, Xuhong; Yang, Youjun
Mild dealkylative N-nitrosation of N,N-dialkylaniline derivatives for convenient preparation of photo-triggered and photo-calibrated NO donors
Organic Chemistry Frontiers, 2018, 5, 3206
1554418 CIFC24 H20 N4 O5P 1 21/c 113.145; 14.0218; 12.9264
90; 114.416; 90
2169.47Qiu, Shaobing; Guo, Chunlei; Wang, Mingkang; Sun, Zhenglong; Li, Hui; Qian, Xuhong; Yang, Youjun
Mild dealkylative N-nitrosation of N,N-dialkylaniline derivatives for convenient preparation of photo-triggered and photo-calibrated NO donors
Organic Chemistry Frontiers, 2018, 5, 3206
1554421 CIFC24 H19 Cl N2 OP 1 21/c 15.628; 19.385; 17.569
90; 91.36; 90
1916.2Tong, Mengchao; Zhang, Yong; Qin, Cong; Fu, Yiwei; Liu, Yonghai; Li, Hao; Wang, Wei
Alkenylazaarenes as dipolarophiles in 1,3-dipolar cycloaddition of nitrones: regioselectivity-switchable and highly diastereoselective synthesis of multisubstituted isoxazolidines
Organic Chemistry Frontiers, 2018, 5, 2945
1554422 CIFC24 H19 Cl N2 OP -15.7976; 9.4263; 17.097
87.715; 87.737; 86.465
931.2Tong, Mengchao; Zhang, Yong; Qin, Cong; Fu, Yiwei; Liu, Yonghai; Li, Hao; Wang, Wei
Alkenylazaarenes as dipolarophiles in 1,3-dipolar cycloaddition of nitrones: regioselectivity-switchable and highly diastereoselective synthesis of multisubstituted isoxazolidines
Organic Chemistry Frontiers, 2018, 5, 2945
1554423 CIFC17 H0.25 N OP 21 21 216.229; 13.6065; 14.6177
90; 90; 90
1238.92Xu, Xin-Ming; Lei, Chuan-Hu; Tong, Shuo; Zhu, Jieping; Wang, Mei-Xiang
Lewis acid catalyst-steered divergent synthesis of functionalized vicinal amino alcohols and pyrroles from tertiary enamides
Organic Chemistry Frontiers, 2018, 5, 3138
1554424 CIFC27 H25 F N2 O5 SP 1 21 113.42; 5.3749; 17.821
90; 105.381; 90
1239.4Cao, Zhong-Yan; Wang, Wenmin; Liao, Kui; Wang, Xiaoming; Zhou, Jian; Ma, Jing
Catalytic enantioselective synthesis of cyclopropanes featuring vicinal all-carbon quaternary stereocenters with a CH2F group; study of the influence of C–F⋯H–N interactions on reactivity
Organic Chemistry Frontiers, 2018, 5, 2960
1554425 CIFC18 H16 Br F O2P 16.6841; 8.7074; 14.4482
87.391; 81.591; 78.532
815.14Cao, Zhong-Yan; Wang, Wenmin; Liao, Kui; Wang, Xiaoming; Zhou, Jian; Ma, Jing
Catalytic enantioselective synthesis of cyclopropanes featuring vicinal all-carbon quaternary stereocenters with a CH2F group; study of the influence of C–F⋯H–N interactions on reactivity
Organic Chemistry Frontiers, 2018, 5, 2960
1554426 CIFC14 H13 N O3P 1 21 110.0137; 10.3706; 11.987
90; 109.801; 90
1171.23Kim, Simon J.; Batey, Robert A.
Enantioselective isoquinuclidine synthesis via sequential Diels–Alder/visible-light photoredox C–C bond cleavage: a formal synthesis of the indole alkaloid catharanthine
Organic Chemistry Frontiers, 2018, 5, 2934
1554427 CIFC42 H50 O2 Si2P -17.6019; 7.7795; 17.7908
94.036; 92.577; 114.867
948.98Ozdemir, Resul; Park, Sangyun; Deneme, İbrahim; Park, Yonghan; Zorlu, Yunus; Alidagi, Husniye Ardic; Harmandar, Kevser; Kim, Choongik; Usta, Hakan
Triisopropylsilylethynyl-substituted indenofluorenes: carbonyl versus dicyanovinylene functionalization in one-dimensional molecular crystals and solution-processed n-channel OFETs
Organic Chemistry Frontiers, 2018, 5, 2912
1554428 CIFC48 H50 N4 Si2C 1 2/c 139.755; 10.0294; 11.4351
90; 102.874; 90
4444.8Ozdemir, Resul; Park, Sangyun; Deneme, İbrahim; Park, Yonghan; Zorlu, Yunus; Alidagi, Husniye Ardic; Harmandar, Kevser; Kim, Choongik; Usta, Hakan
Triisopropylsilylethynyl-substituted indenofluorenes: carbonyl versus dicyanovinylene functionalization in one-dimensional molecular crystals and solution-processed n-channel OFETs
Organic Chemistry Frontiers, 2018, 5, 2912
1554429 CIFC33 H35 N O6P 1 21/n 117.45405; 8.11896; 19.929
90; 91.5647; 90
2823.06Yi, Xiao; Tang, Hongxia; Chen, Jing; Xu, Xiuling; Ma, Yongmin
Facile one-pot synthesis of a 3-azabicyclo[3.3.1]nonane scaffold by a tandem Mannich reaction
Organic Chemistry Frontiers, 2018, 5, 3003
1554430 CIFC30 H26 Cl3 N O3P 1 21/c 111.083; 21.629; 12.241
90; 116.92; 90
2616Yi, Xiao; Tang, Hongxia; Chen, Jing; Xu, Xiuling; Ma, Yongmin
Facile one-pot synthesis of a 3-azabicyclo[3.3.1]nonane scaffold by a tandem Mannich reaction
Organic Chemistry Frontiers, 2018, 5, 3003
1554431 CIFC36 H37 O4 P SP 1 21/c 18.7333; 32.515; 11.3552
90; 92.555; 90
3221.3Chen, Yao-Zhong; Liu, Teng; Zhu, Jie; Zhang, Hui; Wu, Lei
Transition-metal-free radical cleavage of a hydrazonyl N–S bond: tosyl radical-initiated cascade C(sp3)–OAr cleavage, sulfonyl rearrangement and atropisomeric cyclopropanation
Organic Chemistry Frontiers, 2018, 5, 3567
1554432 CIFC45 H41 O4 P SP -110.244; 13.1272; 15.4443
85.216; 77.319; 69.981
1903.71Chen, Yao-Zhong; Liu, Teng; Zhu, Jie; Zhang, Hui; Wu, Lei
Transition-metal-free radical cleavage of a hydrazonyl N–S bond: tosyl radical-initiated cascade C(sp3)–OAr cleavage, sulfonyl rearrangement and atropisomeric cyclopropanation
Organic Chemistry Frontiers, 2018, 5, 3567
1554433 CIFC40 H39 O3 P SP 1 21/c 110.9576; 24.0001; 13.0509
90; 94.036; 90
3423.7Chen, Yao-Zhong; Liu, Teng; Zhu, Jie; Zhang, Hui; Wu, Lei
Transition-metal-free radical cleavage of a hydrazonyl N–S bond: tosyl radical-initiated cascade C(sp3)–OAr cleavage, sulfonyl rearrangement and atropisomeric cyclopropanation
Organic Chemistry Frontiers, 2018, 5, 3567
1554434 CIFC37 H35 O3 P SP 1 21/c 112.3705; 13.8788; 19.1238
90; 106.702; 90
3144.8Chen, Yao-Zhong; Liu, Teng; Zhu, Jie; Zhang, Hui; Wu, Lei
Transition-metal-free radical cleavage of a hydrazonyl N–S bond: tosyl radical-initiated cascade C(sp3)–OAr cleavage, sulfonyl rearrangement and atropisomeric cyclopropanation
Organic Chemistry Frontiers, 2018, 5, 3567
1554435 CIFC22 H24 N2P 1 21/c 122.09; 8.574; 9.447
90; 101.6; 90
1752.7Liu, Siyuan; Zhang, Wenzhu; Qu, Jingping; Wang, Baomin
Engaging 2-methyl indolenines in a tandem condensation/1,5-hydride transfer/cyclization process: construction of a novel indolenine–tetrahydroquinoline assembly
Organic Chemistry Frontiers, 2018, 5, 3008
1554436 CIFC21 H21 Br N O7 P SP 21 21 218.8385; 14.3341; 17.8495
90; 90; 90
2261.4Sun, Jun; Mou, Chengli; Liu, Changyi; Huang, Ruoyan; Zhang, Shupeng; Zheng, Pengcheng; Chi, Yonggui Robin
Enantioselective access to multi-cyclic α-amino phosphonates via carbene-catalyzed cycloaddition reactions between enals and six-membered cyclic imines
Organic Chemistry Frontiers, 2018, 5, 2992
1554441 CIFC28 H29 Co P SP 1 21/n 19.0319; 18.9034; 14.4632
90; 96.64; 90
2452.8Liu, Xiangyu; Wu, Chengjuan; Zhang, Jing; Shi, Yihan; Zhang, Shengnan; Geng, Yan; Tung, Chen-Ho; Wang, Wenguang
Cobalt-catalyzed radical cyclization of isocyanides forming phenanthridine derivatives
Organic Chemistry Frontiers, 2018, 5, 2997
1554442 CIFC22 H18 N O2P 1 21/n 112.766; 7.3952; 18.2702
90; 103.067; 90
1680.17Liu, Xiangyu; Wu, Chengjuan; Zhang, Jing; Shi, Yihan; Zhang, Shengnan; Geng, Yan; Tung, Chen-Ho; Wang, Wenguang
Cobalt-catalyzed radical cyclization of isocyanides forming phenanthridine derivatives
Organic Chemistry Frontiers, 2018, 5, 2997
1554443 CIFC30 H23 N O2P -17.3192; 11.4476; 14.2878
109.541; 103.435; 90.85
1091.7Liu, Xiangyu; Wu, Chengjuan; Zhang, Jing; Shi, Yihan; Zhang, Shengnan; Geng, Yan; Tung, Chen-Ho; Wang, Wenguang
Cobalt-catalyzed radical cyclization of isocyanides forming phenanthridine derivatives
Organic Chemistry Frontiers, 2018, 5, 2997
1554444 CIFC26 H21 N O2P -17.4718; 10.17; 13.6849
80.313; 76.092; 74.405
966.3Liu, Xiangyu; Wu, Chengjuan; Zhang, Jing; Shi, Yihan; Zhang, Shengnan; Geng, Yan; Tung, Chen-Ho; Wang, Wenguang
Cobalt-catalyzed radical cyclization of isocyanides forming phenanthridine derivatives
Organic Chemistry Frontiers, 2018, 5, 2997
1554445 CIFC28 H29 Br Co P SP n a 2116.6717; 10.051; 14.516
90; 90; 90
2432.4Liu, Xiangyu; Wu, Chengjuan; Zhang, Jing; Shi, Yihan; Zhang, Shengnan; Geng, Yan; Tung, Chen-Ho; Wang, Wenguang
Cobalt-catalyzed radical cyclization of isocyanides forming phenanthridine derivatives
Organic Chemistry Frontiers, 2018, 5, 2997
1554448 CIFC28 H33 Br O3I 1 2 126.357; 7.5712; 24.9141
90; 92.458; 90
4967.1Liu, Lin; Song, Huayue; Chen, Peng; Yuan, Ziyun; Feng, Shangbiao; Zhang, Weiwei; Fang, Bowen; Xie, Xingang; She, Xuegong
Total synthesis of (−)-8-epi-chromazonarol enabled by a unique N2H4·H2O promoted intramolecular oxa-Michael cyclization reaction
Organic Chemistry Frontiers, 2018, 5, 3013
1554451 CIFC26 H23 N O2 SC 1 c 112.1152; 14.1577; 24.768
90; 93.519; 90
4240.3Zhang, Jia-hao; Wei, Yin; Shi, Min
Gold-catalyzed ring enlargement and cycloisomerization of alkynylamide tethered alkylidenecyclopropanes
Organic Chemistry Frontiers, 2018, 5, 2980

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