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1553819 CIFC25 H26 F3 N O5P 1 21/n 114.9433; 9.3141; 17.6377
90; 102.36; 90
2397.98Tang, Yang; Yu, Qiong; Ma, Shengming
Efficient trifluoromethylation via the cyclopropanation of allenes and subsequent C–C bond cleavage
Organic Chemistry Frontiers, 2017, 4, 1762
1553820 CIFC21 H24 F3 N O4P 1 21/c 115.6855; 9.6366; 13.4345
90; 96.4; 90
2018.03Tang, Yang; Yu, Qiong; Ma, Shengming
Efficient trifluoromethylation via the cyclopropanation of allenes and subsequent C–C bond cleavage
Organic Chemistry Frontiers, 2017, 4, 1762
1553821 CIFC19 H21 F3 O5P -18.577; 11.253; 11.3999
83.261; 69.715; 68.411
959.58Tang, Yang; Yu, Qiong; Ma, Shengming
Efficient trifluoromethylation via the cyclopropanation of allenes and subsequent C–C bond cleavage
Organic Chemistry Frontiers, 2017, 4, 1762
1553822 CIFC19 H15 N3 O4P c a 2116.2553; 8.3116; 24.8996
90; 90; 90
3364.12Krylov, Igor B.; Paveliev, Stanislav A.; Shelimov, Boris N.; Lokshin, Boris V.; Garbuzova, Irina A.; Tafeenko, Viktor A.; Chernyshev, Vladimir V.; Budnikov, Alexander S.; Nikishin, Gennady I.; Terent'ev, Alexander O.
Selective cross-dehydrogenative C–O coupling of N-hydroxy compounds with pyrazolones. Introduction of the diacetyliminoxyl radical into the practice of organic synthesis
Organic Chemistry Frontiers, 2017, 4, 1947
1553823 CIFC24 H21 F2 O3 PC 1 2/c 125.317; 8.8649; 22.042
90; 120.571; 90
4259.3Zhang, Pengbo; Ying, Jianxi; Tang, Guo; Zhao, Yufen
Phosphinodifluoroalkylation of alkynes using P(O)H compounds and ethyl difluoroiodoacetate
Organic Chemistry Frontiers, 2017, 4, 2054
1553824 CIFC26 H28 N2 O5P 1 21/n 17.75; 20.882; 14.5149
90; 93.914; 90
2343.5Yang, Minghua; Zhang, Shusheng; Zhang, Xiang; Wang, Haoyang; Zhang, Fang; Hou, Yuting; Su, Yue; Guo, Yinlong
An unexpected acid-catalyzed decomposition reaction of cilnidipine and pranidipine to the decarboxylative bridged tricyclic products via cascade rearrangements
Organic Chemistry Frontiers, 2017, 4, 2163
1553825 CIFC18 H22 O5I 1 2/a 19.6871; 14.029; 23.8866
90; 90.258; 90
3246.2Sun, Haiyu; Xu, Shiyan; Xing, Zhimin; Liu, Lin; Feng, Shangbiao; Fang, Bowen; Xie, Xingang; She, Xuegong
Rapid construction of complex tetracyclic frameworks via a gold(i)-catalyzed tandem 1,2-acyloxy migration/[3 + 2] cycloaddition/Friedel–Crafts type cyclization reaction of linear enynyl esters
Organic Chemistry Frontiers, 2017, 4, 2109
1553826 CIFC20 H26 O6P 1 21/c 110.2811; 28.3515; 12.9191
90; 103.741; 90
3657.9Sun, Haiyu; Xu, Shiyan; Xing, Zhimin; Liu, Lin; Feng, Shangbiao; Fang, Bowen; Xie, Xingang; She, Xuegong
Rapid construction of complex tetracyclic frameworks via a gold(i)-catalyzed tandem 1,2-acyloxy migration/[3 + 2] cycloaddition/Friedel–Crafts type cyclization reaction of linear enynyl esters
Organic Chemistry Frontiers, 2017, 4, 2109
1553827 CIFC27 H33 N O7 SC 1 2/c 122.151; 9.8005; 26.0531
90; 117.401; 90
5021.3Sun, Haiyu; Xu, Shiyan; Xing, Zhimin; Liu, Lin; Feng, Shangbiao; Fang, Bowen; Xie, Xingang; She, Xuegong
Rapid construction of complex tetracyclic frameworks via a gold(i)-catalyzed tandem 1,2-acyloxy migration/[3 + 2] cycloaddition/Friedel–Crafts type cyclization reaction of linear enynyl esters
Organic Chemistry Frontiers, 2017, 4, 2109
1553828 CIFC18 H22 O6P -18.9279; 10.0249; 10.8557
115.731; 104.925; 90.322
838Sun, Haiyu; Xu, Shiyan; Xing, Zhimin; Liu, Lin; Feng, Shangbiao; Fang, Bowen; Xie, Xingang; She, Xuegong
Rapid construction of complex tetracyclic frameworks via a gold(i)-catalyzed tandem 1,2-acyloxy migration/[3 + 2] cycloaddition/Friedel–Crafts type cyclization reaction of linear enynyl esters
Organic Chemistry Frontiers, 2017, 4, 2109
1553829 CIFC19 H23 O6P 1 21/n 15.9908; 12.2284; 23.731
90; 90; 90
1738.5Sun, Haiyu; Xu, Shiyan; Xing, Zhimin; Liu, Lin; Feng, Shangbiao; Fang, Bowen; Xie, Xingang; She, Xuegong
Rapid construction of complex tetracyclic frameworks via a gold(i)-catalyzed tandem 1,2-acyloxy migration/[3 + 2] cycloaddition/Friedel‒Crafts type cyclization reaction of linear enynyl esters
Organic Chemistry Frontiers, 2017, 4, 2109
1553830 CIFC27 H33 N O7 SC 1 2/c 113.7047; 15.4463; 24.0895
90; 97.806; 90
5052.2Sun, Haiyu; Xu, Shiyan; Xing, Zhimin; Liu, Lin; Feng, Shangbiao; Fang, Bowen; Xie, Xingang; She, Xuegong
Rapid construction of complex tetracyclic frameworks via a gold(i)-catalyzed tandem 1,2-acyloxy migration/[3 + 2] cycloaddition/Friedel–Crafts type cyclization reaction of linear enynyl esters
Organic Chemistry Frontiers, 2017, 4, 2109
1553831 CIFC19 H24 O5P -18.981; 10.331; 10.885
66.11; 71.31; 87.32
870.7Sun, Haiyu; Xu, Shiyan; Xing, Zhimin; Liu, Lin; Feng, Shangbiao; Fang, Bowen; Xie, Xingang; She, Xuegong
Rapid construction of complex tetracyclic frameworks via a gold(i)-catalyzed tandem 1,2-acyloxy migration/[3 + 2] cycloaddition/Friedel‒Crafts type cyclization reaction of linear enynyl esters
Organic Chemistry Frontiers, 2017, 4, 2109
1553832 CIFC25 H29 N O7 SP -19.88; 10.9717; 12.836
85.382; 71.391; 65.05
1193.2Sun, Haiyu; Xu, Shiyan; Xing, Zhimin; Liu, Lin; Feng, Shangbiao; Fang, Bowen; Xie, Xingang; She, Xuegong
Rapid construction of complex tetracyclic frameworks via a gold(i)-catalyzed tandem 1,2-acyloxy migration/[3 + 2] cycloaddition/Friedel–Crafts type cyclization reaction of linear enynyl esters
Organic Chemistry Frontiers, 2017, 4, 2109
1553833 CIFC23 H19 Cl F3 N O5P -17.3052; 10.5757; 14.449
88.853; 83.694; 77.708
1084.1Sun, Yao-Liang; Wei, Yin; Shi, Min
Tunable regiodivergent phosphine-catalyzed [3 + 2] cycloaddition of alkynones and trifluoroacetyl phenylamides
Organic Chemistry Frontiers, 2017, 4, 2392
1553834 CIFC19 H23 Cl F3 N O4P 1 21/n 111.287; 12.727; 14.808
90; 103.68; 90
2066.8Sun, Yao-Liang; Wei, Yin; Shi, Min
Tunable regiodivergent phosphine-catalyzed [3 + 2] cycloaddition of alkynones and trifluoroacetyl phenylamides
Organic Chemistry Frontiers, 2017, 4, 2392
1553835 CIFC21 H17 Cl F3 N O3C 1 2/c 121.872; 7.604; 24.313
90; 110.597; 90
3785.1Sun, Yao-Liang; Wei, Yin; Shi, Min
Tunable regiodivergent phosphine-catalyzed [3 + 2] cycloaddition of alkynones and trifluoroacetyl phenylamides
Organic Chemistry Frontiers, 2017, 4, 2392
1553836 CIFC16 H15 N OP 1 21 16.9086; 9.5831; 19.453
90; 96.737; 90
1279Zhang, Wei; Yu, Wenlong; Yan, Qiangqiang; Liu, Zhanxiang; Zhang, Yuhong
Synthesis of substituted oxazoles via Pd-catalyzed tandem oxidative cyclization
Organic Chemistry Frontiers, 2017, 4, 2428
1553837 CIFC25 H29 N O5 SP 1 21/c 111.7381; 13.2058; 14.4879
90; 98.487; 90
2221.19Lv, Leiyang; Lu, Shenglin; Chen, Yuanjin; Li, Zhiping
Diastereoselective building up polycyclic tetrahydrofurans via tandem annulation of 1,n-enynes with aliphatic acids
Organic Chemistry Frontiers, 2017, 4, 2147
1553838 CIFC29 H25 N O7 SP 21 21 218.0159; 15.545; 21.174
90; 90; 90
2638.4Li, Shoulei; Zhang, Enge; Feng, Junjun; Li, Xin
An enantioselective conjugate addition reaction of 3-substituted benzothiophen-2-ones and 2-phthalimidoacrylates
Organic Chemistry Frontiers, 2017, 4, 2301
1553839 CIFC15 H17 F N2 O2P -19.5214; 9.6784; 9.8861
114.205; 92.568; 116.743
712.04Yang, Zi; Lin, Xing; Wang, Lianhui; Cui, Xiuling
Facile synthesis of 1-aminoindoles via Rh(iii)-catalysed intramolecular three-component annulation
Organic Chemistry Frontiers, 2017, 4, 2179
1553840 CIFC23 H22 Br N O4 SP 1 21/n 110.723; 9.856; 20.94
90; 100.205; 90
2178Wang, Weiyi; He, Qiuqin; Fan, Renhua
PhI(OAc)2-mediated dialkoxylation of 4-aminostyrenes through a dearomatization process under metal-free conditions
Organic Chemistry Frontiers, 2017, 4, 2156
1553841 CIFC17 H21 N O4 SP 1 21/n 113.746; 8.2548; 15.646
90; 104.468; 90
1719.1Wang, Weiyi; He, Qiuqin; Fan, Renhua
PhI(OAc)2-mediated dialkoxylation of 4-aminostyrenes through a dearomatization process under metal-free conditions
Organic Chemistry Frontiers, 2017, 4, 2156
1553842 CIFC40 H48 Cl2 N2 O2 PdP 1 21/n 111.7394; 19.838; 16.5546
90; 94.489; 90
3843.5Chen, Fu-Min; Huang, Fei-Dong; Yao, Xue-Yi; Li, Tian; Liu, Feng-Shou
Direct C‒H heteroarylation by an acenaphthyl-based α-diimine palladium complex: improvement of the reaction efficiency for bi(hetero)aryls under aerobic conditions
Organic Chemistry Frontiers, 2017, 4, 2336
1553843 CIFC16 H15 N O4P 21 21 217.973; 12.9128; 14.3781
90; 90; 90
1480.28Wu, Qiuju; Li, Chengcheng; Wang, Weihong; Wang, Hongling; Pan, Dingwu; Zheng, Pengcheng
NHC-catalyzed enantioselective synthesis of dihydropyran-4-carbonitriles bearing all-carbon quaternary centers
Organic Chemistry Frontiers, 2017, 4, 2323
1553844 CIFC20 H21 N O2P 1 21/n 111.831; 8.4718; 16.4581
90; 90.759; 90
1649.45Wu, Shangze; Huang, Xin; Fu, Chunling; Ma, Shengming
Asymmetric SN2′-type C–H functionalization of arenes with propargylic alcohols
Organic Chemistry Frontiers, 2017, 4, 2002
1553845 CIFC24 H27 N OP -18.316; 10.229; 13.179
69.905; 82.818; 72.23
1002.3Wu, Shangze; Huang, Xin; Fu, Chunling; Ma, Shengming
Asymmetric SN2′-type C–H functionalization of arenes with propargylic alcohols
Organic Chemistry Frontiers, 2017, 4, 2002
1553846 CIFC17 H22 I N O2P 1 21/n 111.781; 12.2621; 12.7517
90; 110.261; 90
1728.1Wu, Shangze; Huang, Xin; Fu, Chunling; Ma, Shengming
Asymmetric SN2′-type C–H functionalization of arenes with propargylic alcohols
Organic Chemistry Frontiers, 2017, 4, 2002
1553847 CIFC8 H6 Br F3 O SP 1 21/c 120.993; 3.9406; 12.147
90; 95.906; 90
999.5Zhang, Yunxiao; Wu, Dongping; Weng, Zhiqiang
Synthesis of 1,2,2-trifluorovinyl sulphides and selenides from trifluorovinylation of organic thiocyanates and selenocyanates
Organic Chemistry Frontiers, 2017, 4, 2226
1553848 CIFC26 H20 Br N O4 SP -19.3385; 11.1134; 11.912
69.983; 88.735; 69.443
1080.8Jin, Hongxing; Li, Erqing; Huang, You
Divergent synthesis of hydropyridine derivatives via nitrogen-containing Lewis base mediated regioselective [4 + 2] cyclizations
Organic Chemistry Frontiers, 2017, 4, 2216
1553849 CIFC26 H20 Br N O4 SC 1 2/c 127.96; 10.908; 16.954
90; 121.023; 90
4431Jin, Hongxing; Li, Erqing; Huang, You
Divergent synthesis of hydropyridine derivatives via nitrogen-containing Lewis base mediated regioselective [4 + 2] cyclizations
Organic Chemistry Frontiers, 2017, 4, 2216
1553850 CIFC18 H16 O4 SP 21 21 219.7797; 10.9021; 14.8619
90; 90; 90
1584.6Zhao, Wei-Wei; Liu, Yan-Kai
Enantio- and diastereoselective synthesis of tetrahydrofuro[2,3-b]furan-2(3H)-one derivatives and related oxygen heterocycles via an asymmetric organocatalytic cascade process
Organic Chemistry Frontiers, 2017, 4, 2358
1553851 CIFC100 H96 Cl6 N6 O10P -19.8074; 13.2321; 17.7176
100.836; 99.601; 93.264
2217.36Zhang, Yuehong; Wang, Chiming; Chen, Xin; Pan, Houhe; Qi, Dongdong; Wang, Kang; Jiang, Jianzhuang
Novel, linear oligoisoindole compounds with a conjugated electronic structure
Organic Chemistry Frontiers, 2017, 4, 2364
1553852 CIFC88 H122 N2 O4 S2P 18.9041; 14.0916; 16.2768
104.121; 91.824; 94.954
1970.23Zhang, Yuehong; Wang, Chiming; Chen, Xin; Pan, Houhe; Qi, Dongdong; Wang, Kang; Jiang, Jianzhuang
Novel, linear oligoisoindole compounds with a conjugated electronic structure
Organic Chemistry Frontiers, 2017, 4, 2364
1553853 CIFC202 H249 Cl14 N9 O15P -118.0089; 19.4187; 29.7417
90.357; 95.539; 107.328
9875.8Zhang, Yuehong; Wang, Chiming; Chen, Xin; Pan, Houhe; Qi, Dongdong; Wang, Kang; Jiang, Jianzhuang
Novel, linear oligoisoindole compounds with a conjugated electronic structure
Organic Chemistry Frontiers, 2017, 4, 2364
1553854 CIFC132 H154 Cl12 N6 O8P 1 21/c 19.9153; 27.367; 23.7531
90; 93.29; 90
6434.8Zhang, Yuehong; Wang, Chiming; Chen, Xin; Pan, Houhe; Qi, Dongdong; Wang, Kang; Jiang, Jianzhuang
Novel, linear oligoisoindole compounds with a conjugated electronic structure
Organic Chemistry Frontiers, 2017, 4, 2364
1553855 CIFC18 H16 Cl N O4 SP 21 21 215.1621; 16.3247; 20.251
90; 90; 90
1706.5Deng, Hua; He, Fu-Sheng; Li, Cong-Shan; Yang, Wu-Lin; Deng, Wei-Ping
Enantioselective construction of tricyclic pyrrolidine-fused benzo[b]thiophene 1,1-dioxide derivatives via copper(i)-catalyzed asymmetric 1,3-dipolar cycloaddition
Organic Chemistry Frontiers, 2017, 4, 2343
1553866 CIFC31 H36 N2 O4P -18.4885; 10.6796; 16.8127
74.369; 82.265; 75.011
1414.37Wu, Jia-Le; Wang, Jing-Yi; Wu, Ping; Mei, Guang-Jian; Shi, Feng
Catalytic asymmetric C2-nucleophilic substitutions of C3-substituted indoles with ortho-hydroxybenzyl alcohols
Organic Chemistry Frontiers, 2017, 4, 2465
1553867 CIFC23 H20 N O2P 6118.5578; 18.5578; 9.8682
90; 90; 120
2943.2Wu, Jia-Le; Wang, Jing-Yi; Wu, Ping; Mei, Guang-Jian; Shi, Feng
Catalytic asymmetric C2-nucleophilic substitutions of C3-substituted indoles with ortho-hydroxybenzyl alcohols
Organic Chemistry Frontiers, 2017, 4, 2465
1553868 CIFC17 H22 N2 O2P 1 21/n 16.0777; 22.245; 11.8606
90; 96.163; 90
1594.3Liu, Xueke; Qian, Ping; Wang, Yi; Pan, Yi
Metal-free sequential decarbonylative annulation of N-cyanamides for the construction of 2,3-dihydropyrrolo[2,1-b]quinazolin-9(1H)-ones
Organic Chemistry Frontiers, 2017, 4, 2370
1553869 CIFC20 H22 N2 OC 1 2/c 121.107; 7.3437; 21.914
90; 101.993; 90
3322.6Liu, Xueke; Qian, Ping; Wang, Yi; Pan, Yi
Metal-free sequential decarbonylative annulation of N-cyanamides for the construction of 2,3-dihydropyrrolo[2,1-b]quinazolin-9(1H)-ones
Organic Chemistry Frontiers, 2017, 4, 2370
1553870 CIFC31 H38 O9P 1 21 17.9044; 11.5678; 15.8146
90; 98.267; 90
1431.01Luo, Jun; Huang, Wan-Sha; Hu, Sheng-Mou; Zhang, Pan-Pan; Zhou, Xu-Wei; Wang, Xiao-Bing; Yang, Ming-Hua; Luo, Jian-Guang; Wang, Chen; Liu, Chang; Yao, He-Quan; Zhang, Can; Sun, Hong-Bin; Chen, Yi-Jun; Kong, Ling-Yi
Rearranged limonoids with unique 6/5/6/5 tetracarbocyclic skeletons from Toona ciliata and biomimetic structure divergence
Organic Chemistry Frontiers, 2017, 4, 2417
1553871 CIFC31 H38 O9P 21 21 2114.6815; 17.2043; 23.1115
90; 90; 90
5837.62Luo, Jun; Huang, Wan-Sha; Hu, Sheng-Mou; Zhang, Pan-Pan; Zhou, Xu-Wei; Wang, Xiao-Bing; Yang, Ming-Hua; Luo, Jian-Guang; Wang, Chen; Liu, Chang; Yao, He-Quan; Zhang, Can; Sun, Hong-Bin; Chen, Yi-Jun; Kong, Ling-Yi
Rearranged limonoids with unique 6/5/6/5 tetracarbocyclic skeletons from Toona ciliata and biomimetic structure divergence
Organic Chemistry Frontiers, 2017, 4, 2417
1553875 CIFC25 H24 Br2 N2 O3 SP -18.4549; 13.872; 14.009
117.552; 101.368; 92.964
1408.7Jiang, Bo; Shi, Min
Rhodium(ii)-catalyzed intermolecular [3 + 2] annulation of N-vinyl indoles with N-tosyl-1,2,3-triazoles via an aza-vinyl Rh carbene
Organic Chemistry Frontiers, 2017, 4, 2459
1553876 CIFC44 H45 Br2 N3 O6 S2P 1 21/c 113.823; 11.5473; 30.267
90; 98.559; 90
4777.4Jiang, Bo; Shi, Min
Rhodium(ii)-catalyzed intermolecular [3 + 2] annulation of N-vinyl indoles with N-tosyl-1,2,3-triazoles via an aza-vinyl Rh carbene
Organic Chemistry Frontiers, 2017, 4, 2459
1553877 CIFC43 H38 Br N3 O4 S2P -111.936; 13.1209; 13.8558
89.702; 84.883; 66.69
1983.8Jiang, Bo; Shi, Min
Rhodium(ii)-catalyzed intermolecular [3 + 2] annulation of N-vinyl indoles with N-tosyl-1,2,3-triazoles via an aza-vinyl Rh carbene
Organic Chemistry Frontiers, 2017, 4, 2459
1553878 CIFC31 H26 N2 O2 SP -110.688; 10.745; 11.245
103.535; 94.412; 96.045
1241.6Jiang, Bo; Shi, Min
Rhodium(ii)-catalyzed intermolecular [3 + 2] annulation of N-vinyl indoles with N-tosyl-1,2,3-triazoles via an aza-vinyl Rh carbene
Organic Chemistry Frontiers, 2017, 4, 2459
1553879 CIFC25 H21 Br N2 O2 SC 1 2/c 124.816; 10.401; 16.9512
90; 96.192; 90
4349.8Jiang, Bo; Shi, Min
Rhodium(ii)-catalyzed intermolecular [3 + 2] annulation of N-vinyl indoles with N-tosyl-1,2,3-triazoles via an aza-vinyl Rh carbene
Organic Chemistry Frontiers, 2017, 4, 2459
1553881 CIFC72 H112 Cl2 N28 O26C 1 2/c 124.1839; 31.5567; 12.6112
90; 104.99; 90
9296.9Xiao, Zhi-You; Lin, Rui-Lian; Tao, Zhu; Liu, Qing-Yun; Liu, Jing-Xin; Xiao, Xin
Multiple noncovalent interaction constructed polymeric supramolecular crystals: recognition of butyl viologen by para-dicyclohexanocucurbit[6]uril and α,α′,δ,δ′-tetramethylcucurbit[6]uril
Organic Chemistry Frontiers, 2017, 4, 2422
1553882 CIFC108 H176 Cl6 N52 O50 Sr2P -112.8381; 15.6916; 22.2878
92.995; 98.521; 106.862
4227.9Xiao, Zhi-You; Lin, Rui-Lian; Tao, Zhu; Liu, Qing-Yun; Liu, Jing-Xin; Xiao, Xin
Multiple noncovalent interaction constructed polymeric supramolecular crystals: recognition of butyl viologen by para-dicyclohexanocucurbit[6]uril and α,α′,δ,δ′-tetramethylcucurbit[6]uril
Organic Chemistry Frontiers, 2017, 4, 2422

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