Crystallography Open Database

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1100293 CIFC21 H19 N O6 WP -18.886; 10.706; 12.807
109.5; 108.06; 98.94
1045.36Dötz, K. H.; Noack, R.; Harms, K.; Müller, G.
Carbene complexes in intramolecular Diels-Alder reactions
Tetrahedron, 1990, 46, 1235-1252
1100294 CIFC42 H84 Li4 O8 S2 Si4P 1 21/c 111.195; 21.374; 12.619
90; 112.66; 90
2786.42Hollstein, Werner; Harms, Klaus; Marsch, Michael; Boche, Gernot
X-Ray Structure Analysis of the Li~2~-Compound of Bis(trimethylsilyl)metnyl Phenyl Sulfone; Structural Units of an α-Sulfonyl- and a Complex-Stabilizedortho-Sulfonyl-"Carbanion"
Angewandte Chemie, International Edition in English, 1987, 26, 1287-1288
1100295 CIFC21 H19 Cr O5 PP 1 21/c 110.334; 11.834; 16.445
90; 102.33; 90
1964.71Dötz, Karl Heinz; Tiriliomis, Athanassios; Harms, Klaus; Regitz, Manfred; Annen, Ulrich
Annelation of Carbene Ligands by λ^3^-Phosphaalkynes, an Entry to Functionalized Phosphaarenes
Angewandte Chemie, International Edition in English, 1988, 27, 713-714
1100296 CIFC10 H16 Li N OP 1 21/c 111.493; 9.567; 19.636
90; 93.18; 90
2155.72Boche, Gernot; Harms, Klaus; Marsch, Michael
X-ray structure determination of [1-cyano-2,.2-dimtheylcyclopropyllithium·tetrahydrofuran]~∞~: a tetrahedral anionic α-cyano carbon atom
Journal of the American Chemical Society, 1988, 110, 6925-6926
1100297 CIFC24 H24 N2 OP -18.225; 10.598; 12.754
96.3; 105.52; 106.17
1008.23Reetz, M. T.; Drewes, M. W.; Harms, K.; Reif, W.
Stereoselective cyanohydrin-forming reactions of chiral α-amino aldehydes
Tetrahedron Letters, 1988, 29, 3295-3298
1100298 CIFC17 H13 Cr N O6P 1 21/c 19.786; 10.649; 16.435
90; 98.6; 90
1693.45Dötz, Karl Heinz; Erben, Hans-Georg; Staudacher, Wolfgang; Harms, Klaus; Müller, Gerhard; Riede, Jürgen
Reaktionen von Komplexliganden: XXXIV. Tetracarbonyl-Carben-Chelatkomplexe des Chroms, Molybdäns und Wolframs
Journal of Organometallic Chemistry, 1988, 355, 177-191
1100299 CIFC13 H10 Cr O5 SP -17.477; 9.591; 11.09
73.08; 72.89; 77.19
719.08Dötz, Karl Heinz; Erben, Hans-Georg; Staudacher, Wolfgang; Harms, Klaus; Müller, Gerhard; Riede, Jürgen
Reaktionen von Komplexliganden: XXXIV. Tetracarbonyl-Carben-Chelatkomplexe des Chroms, Molybdäns und Wolframs
Journal of Organometallic Chemistry, 1988, 355, 177-191
1100300 CIFC17 H25 Li N4P 1 21/c 114.724; 8.561; 13.267
90; 104.11; 90
1621.88Buchholz, Stefan; Harms, Klaus; Marsch, Michael; Massa, Werner; Boche, Gernot
Model of a Solvent-Shared Ion Pair with N‒H⋯C Hydrogen Bonds between Amine and Carbanion-Crystal Structure of [Fluorenyllithium·2 Ethylenediamine]~∞~
Angewandte Chemie, International Edition in English, 1989, 28, 72-73
1100301 CIFC8 H6 N4P n m a12.941; 9.45; 6.459
90; 90; 90
789.89Buchholz, Stefan; Harms, Klaus; Massa, Werner; Boche, Gernot
Hydrogen Bonds between an NH~4~^⊕^ Ion and a Carbanion—Crystal Structure of Ammonium 1,2,4-Tricyanocyclopentadienide
Angewandte Chemie, International Edition in English, 1989, 28, 73-75
1100302 CIFC19 H22 Cr O5C 1 2/c 122.736; 6.809; 25.373
90; 107.86; 90
3738.69Dötz, Karl Heinz; Erben, Hans-Georg; Harms, Klaus
Aminocarbene annulation by alkynes: a regio- and diastereo-selective route to indanone complexes
Journal of the Chemical Society, Chemical Communications, 1989, 692-693
1100303 CIFC26 H52 Li2 N6P -19.968; 11.966; 14.171
77.24; 73.47; 87.16
1580.24Zarges, Wolfgang; Marsch, Michael; Harms, Klaus; Boche, Gernot
X-Ray Structure Analysis of α-Lithiophenylacetonitrile · Lithium Diisopropyl amide · 2 Tetramethylethylenediamine—a "Quasi-Dianion Complex"
Angewandte Chemie, International Edition in English, 1989, 28, 1392-1394
1100304 CIFC17 H17 Cr N O6C 1 2/c 123.355; 11.187; 15.629
90; 111.66; 90
3795.1Dötz, Karl Heinz; Grotjahn, Douglas; Harms, Klaus
Activated Aminocarbene Complexes of the Fischer Type: Synthesis, Structure, and Annelation Reactions
Angewandte Chemie, International Edition in English, 1989, 28, 1384-1386
1100305 CIFC90 H182 Li24 N12 O6 Si12P -115.574; 15.678; 16.257
74.01; 84.38; 61.32
3344.96Zarges, Wolfgang; Marsch, Michael; Harms, Klaus; Boche, Gernot
[{Li~2~(Me~3~SiCCN)}~12~(Et~2~O)~6~(C~6~H~14~)], Kristallstruktur mit dem Trimethylsilylacetonitril-Dianion
Chemische Berichte, 1989, 122, 1307-1311
1100306 CIFC16 H13 N O6 WP -16.11; 9.353; 14.739
82.96; 83.11; 85.04
827.7Dötz, K. H.; Noack, R.; Harms, K.; Müller, G.
Carbene complexes in intramolecular Diels-Alder reactions
Tetrahedron, 1990, 46, 1235-1252
1100307 CIFC30 H38 N2 O5P -19.617; 11.345; 15.09
97.07; 108.05; 107.29
1452.04Reetz, M. T.; Wünsch, T.; Harms, K.
Stereoselective synthesis of α,γ-diamino-β-hydroxy amino acid esters: A new class of amino acids
Tetrahedron: Asymmetry, 1990, 1, 371-374
1100308 CIFC16 H24 O2P 21/n11.907; 8.094; 14.868
90; 90.03; 90
1432.91Tietze, Lutz-F.; von Kiedrowski, Günter; Harms, Klaus; Clegg, William; Sheldrick, George
Stereocontrolled Intramolecular Diels-Alder Reaction of Heterodienes; Studies on the Synthesis of Cannabinoids
Angewandte Chemie, International Edition in English, 1980, 19, 134-135
1100309 CIFC9 H20 Cl N OP 21 21 217.44; 11.609; 12.295
90; 90; 90
1061.93Harms, K.; Sheldrick, G. M.; Fischer, R.; Tietze, L. F.
[(1RS,2RS,3SR)-3-Hydroxy-2-methylcyclopentyl]trimethylammonium chloride
Acta Crystallographica, Section B: Structural Crystallography and Crystal Chemistry, 1980, 36, 3206-3208
1100310 CIFC22 H28 O2 SeP 1 21 110.298; 9.915; 10.835
90; 114.62; 90
1005.73Clegg, W.; Harms, K.; Sheldrick, G. M.; von Kiedrowski, G.; Tietze, L. F.
(2S,6aR,10aR)-6,6,9-Trimethyl-1-oxo-2-phenylseleno-1,2,3,4,6a,7,8,9,10,10a-decahydro-6H-dibenzo[b,d]pyran
Acta Crystallographica, Section B: Structural Crystallography and Crystal Chemistry, 1980, 36, 3159-3162
1100311 CIFC26 H37 Li N2 O3P 1 21 17.894; 16.227; 9.707
90; 101.01; 90
1220.54Enders, Dieter; Bachstädter, Gerhard; Kremer, Kenneth A. M.; Marsch, Michael; Harms, Klaus; Boche, Gernot
Structure of a Chiral Lithium Azaenolate: Monomeric, Intramolecular Chelated Lithio-2-acetylnaphthalene-SAMP-hydrazone
Angewandte Chemie, International Edition in English, 1988, 27, 1522-1524
1100312 CIFC56 H64 Li2 N2 O2P 21 21 2115.141; 15.338; 20.827
90; 90; 90
4836.71Ahlbrecht, Hubertus; Boche, Gernot; Harms, Klaus; Marsch, Michael; Sommer, Horst
Chirale Homoenolat-Äquivalente, IV. Kristallstruktur einer chiralen 1-Aminoallyllithium-Verbindung: dimeres, intramolekular chelatisiertes (3S)-3-Lithio-1-[(S)-2-(methoxymethyl)pyrrolidino]-1,3-diphenylpropen
Chemische Berichte, 1990, 123, 1853-1858
1100313 CIFC26 H29 N OP -19.425; 9.49; 12.386
94.741; 97.68; 102.49
1064.78Priepke, Henning; Brückner, Reinhard; Harms, Klaus
Asymmetric Induction in the Wittig-Still Rearrangement of Ethers Containing an Allylic Stereocenter – Diastereocontrol by Allylic Nitrogen
Chemische Berichte, 1990, 123, 555-563
1100314 CIFC20 H28 N2 O4P 21 21 219.939; 8.52; 23.674
90; 90; 90
2004.72Priepke, Henning; Brückner, Reinhard; Harms, Klaus
Asymmetric Induction in the Wittig-Still Rearrangement of Ethers Containing an Allylic Stereocenter – Diastereocontrol by Allylic Nitrogen
Chemische Berichte, 1990, 123, 555-563
1100315 CIFC32 H72 Li8 O4P 1 21/n 111.024; 23.659; 16.377
90; 101.83; 90
4180.67Marsch, Michael; Harms, Klaus; Lochmann, Lubomir; Boche, Gernot
[nBuLi · LiOtBu]~4~, Solid-State Structure of an n-Butyllithium‒Lithiumtert-Butoxide Complex
Angewandte Chemie, International Edition in English, 1990, 29, 308-309
1100316 CIFC15 H26 O3 SiP 1 21 17.963; 10.014; 12.011
90; 109.22; 90
904.39Scheuplein, Stefan W.; Kusche, Andreas; Brückner, Reinhard; Harms, Klaus
Asymmetric Induction in the [2,3] Witting Rearrangement by Chiral Substituents in the Allyl Moiety: 1,3-Asymmetric Induction
Chemische Berichte, 1990, 123, 917-925
1100317 CIFC16 H15 Cr N O4P 1 21/c 18.854; 13.399; 25.919
90; 95.38; 90
3061.35Dötz, Karl Heinz; Schäfer, Thomas; Harms, Klaus
Synthesis of Nitrogen Heterocycles by Diastereoselective Intramolecular Aminocarbene Annelation
Angewandte Chemie, International Edition in English, 1990, 29, 176-177
1100318 CIFC54 H64 Li2 O10 S2P -110.147; 10.693; 11.919
86.94; 88.69; 85.89
1287.83Hollstein, Werner; Harms, Klaus; Marsch, Michael; Boche, Gernot
X-Ray Structure Investigation of 2,2-Diphenyl-1-(phenylsulfonyl)cyclopropyllithium-Dimethoxyethane (2/3): A Sulfonyl "Carbanion" Having an α-C Atom with a Tetrahedral Configuration
Angewandte Chemie, International Edition in English, 1988, 27, 846-847
1100319 CIFC12 H16 Cl4 O2 SnP 21 21 219.695; 12.819; 13.696
90; 90; 90
1702.14Reetz, M. T.; Harms, K.; Reif, W.
An X-ray structural analysis of a chiral α-alkoxy-ketone/SnCl~4~ chelate
Tetrahedron Letters, 1988, 29, 5881-5884
1100320 CIFC9 H10 Cl4 O2 SnP 1 21/c 114.876; 13.72; 14.101
90; 99.43; 90
2839.1Reetz, M. T.; Harms, K.; Reif, W.
An X-ray structural analysis of a chiral α-alkoxy-ketone/SnCl~4~ chelate
Tetrahedron Letters, 1988, 29, 5881-5884
1100321 CIFC29 H29 Au O2 P SP 1 21/n 111.75; 14.001; 16.751
90; 107.21; 90
2632.35Kneuper, Heinz-Josef; Harms, Klaus; Boche, Gernot
FunktionalisierteÜbergangsmetallalkyle: Synthese und Kristallstruktur von Ph~3~PAuCHPhSO~2~-t-Bu
Journal of Organometallic Chemistry, 1989, 364, 275-279
1100322 CIFC19 H21 Cr O6 PP 1 21/c 115.462; 6.78; 19.762
90; 101.84; 90
2027.62Dötz, Karl Heinz; Tiriliomis, Athanassios; Harms, Klaus
Synthesis of 1,3-oxaphospholes via chromium mediated cyclization of carbenes, carbon monoxide, and phospha-alkynes
Journal of the Chemical Society, Chemical Communications, 1989, 788-790
1100323 CIFC15 H12 O4 S WP 1 21/c 110.093; 11.836; 13.157
90; 106.72; 90
1505.3Kneuper, Heinz-Josef; Zimmermann, Christoph; Harms, Klaus; Boche, Gernot
Funktionalisierte Übergangsmetallalkyle, II. Synthese, Kristallstruktur und Reaktivität von (η~5~-C~5~H~5~)W(CO)~3~‒CH~2~‒S(O)‒C~6~H~5~, einem α-metallierten Sulfoxid
Chemische Berichte, 1989, 122, 1043-1047
1100324 CIFC53 H71 Co N6 O14P 21 21 2115.595; 18.672; 19.023
90; 90; 90
5539.3Battersby, A. R.; Grgurina, I.; Raithby, P. R.; Egert, E.; Harms, K.; Sheldrick, G. M.
Structure of dicyano-15-norcobyrinic acid heptamethyl ester
Acta Crystallographica, Section C: Crystal Structure Communications, 1989, 45, 1589-1593
1100325 CIFC23 H25 Cr N O7P 1 21/n 111.093; 11.474; 19.574
90; 93.63; 90
2486.4Dötz, Karl Heinz; Grotjahn, Douglas; Harms, Klaus
Reaktionen von komplexliganden XXXVIII. Bisacylierung von aminocarben-komplexen zu 2-azaallenyl-komplexen
Journal of Organometallic Chemistry, 1989, 375, C47-C50
1100326 CIFC17 H31 Li N2 OP 1 21/n 18.682; 15.387; 13.934
90; 103.3; 90
1811.52Zarges, Wolfgang; Marsch, Michael; Harms, Klaus; Boche, Gernot
η^1^-C~6~H~5~CH~2~Li·THF·TMEDA, Kristallstruktur eines Benzyllithium·THF·TMEDA-Komplexes mit einem pyramidalen Benzyl-C-Atom
Chemische Berichte, 1989, 122, 2303-2309
1100327 CIFC25 H30 O4 SiP -18.109; 11.7878; 13.696
109.38; 104.62; 96.65
1166.09Koert, Ulrich; Stein, Matthias; Harms, Klaus
Tetrahydrofuran-podands, stereoselective synthesis of trans-2,5-oligo-tetrahydrofurans
Tetrahedron Letters, 1993, 34, 2299-2302
1100328 CIFC26 H44 Li2 N2 O2P 1 21/n 19.32; 12.832; 11.842
90; 106.47; 90
1358.12Boche, Gernot; Marsch, Michael; Harbach, Jürgen; Harms, Klaus; Ledig, Burkhard; Schubert, Frank; Lohrenz, John C. W.; Ahlbrecht, Hubertus
[α-(Dimethylamino)benzyllithium‒Diethyl Ether]~2~, (S)-α-(Methylpivaloylamino)benzyllithium ‒ (‒)-Sparteine, and [3-Iodo-2-lithio-1-methylindole ‒ 2 Tetrahydrofuran]~2~: Crystal Structure Investigations of α-Lithiated Amines
Chemische Berichte, 1993, 126, 1887-1894
1100329 CIFC28 H44 Li N3 OP 21 21 219.466; 12.907; 21.268
90; 90; 90
2598.47Boche, Gernot; Marsch, Michael; Harbach, Jürgen; Harms, Klaus; Ledig, Burkhard; Schubert, Frank; Lohrenz, John C. W.; Ahlbrecht, Hubertus
[α-(Dimethylamino)benzyllithium–Diethyl Ether]~2~, (S)-α-(Methylpivaloylamino)benzyllithium – (–)-Sparteine, and [3-Iodo-2-lithio-1-methylindole – 2 Tetrahydrofuran]~2~: Crystal Structure Investigations of α-Lithiated Amines
Chemische Berichte, 1993, 126, 1887-1894
1100330 CIFC34 H46 I2 Li2 N2 O4P -19.478; 10.091; 20.268
81.44; 76.61; 69.23
1758.48Boche, Gernot; Marsch, Michael; Harbach, Jürgen; Harms, Klaus; Ledig, Burkhard; Schubert, Frank; Lohrenz, John C. W.; Ahlbrecht, Hubertus
[α-(Dimethylamino)benzyllithium‒Diethyl Ether]~2~, (S)-α-(Methylpivaloylamino)benzyllithium ‒ (‒)-Sparteine, and [3-Iodo-2-lithio-1-methylindole ‒ 2 Tetrahydrofuran]~2~: Crystal Structure Investigations of α-Lithiated Amines
Chemische Berichte, 1993, 126, 1887-1894
1100331 CIFC17 H17 Cr N O6C 1 2/c 123.355; 11.187; 15.629
90; 111.66; 90
3795.1Grotjahn, D. B.; Kroll, F. E. K.; Schaefer, T.; Harms, K.; Doetz, K. H.
Reactions of complex ligands. 45. (Acylamino)carbene complexes: synthesis, structure, and reactivity
Organometallics, 1992, 11, 298-310
1100332 CIFC16 H31 Li N2 SiP 1 21/c 112.955; 9.721; 15.582
90; 102.54; 90
1915.52Zarges, Wolfgang; Marsch, Michael; Harms, Klaus; Frenking, Gernot; Boche, Gernot; Koch, Wolfram
Röntgenstrukturuntersuchung von α-(Trimethylsilyl)benzyllithium·Tetramethylendiamin [C~6~H~5~CH(SiMe~3~)Li·TMEDA] und α-(Phenylthio)-benzyllithium·3 Tetrahydrofuran [C~6~H~5~CH(SPh)Li·(THF)~3~] – zwei zentral-chirale Benzyllithium-Verbindungen
Chemische Berichte, 1991, 124, 543-549
1100333 CIFC25 H35 Li O3 SP 1 21/n 19.106; 9.394; 28.743
90; 93.13; 90
2455.06Zarges, Wolfgang; Marsch, Michael; Harms, Klaus; Frenking, Gernot; Boche, Gernot; Koch, Wolfram
Röntgenstrukturuntersuchung von α-(Trimethylsilyl)benzyllithium·Tetramethylendiamin [C~6~H~5~CH(SiMe~3~)Li·TMEDA] und α-(Phenylthio)-benzyllithium·3 Tetrahydrofuran [C~6~H~5~CH(SPh)Li·(THF)~3~] ‒ zwei zentral-chirale Benzyllithium-Verbindungen
Chemische Berichte, 1991, 124, 543-549
1100334 CIFC12 H22 O2P 1 21/n 16.326; 11.667; 15.709
90; 94.9; 90
1155.17Wolff, J. Jens; Frenking, Gernot; Harms, Klaus
The Conformational Behaviour of 10-Substituted Spiro[4.5]decanes
Chemische Berichte, 1991, 124, 551-561
1100335 CIFC12 H21 Br O2P 1 21/n 16.351; 11.877; 16.86
90; 90.92; 90
1271.6Wolff, J. Jens; Frenking, Gernot; Harms, Klaus
The Conformational Behaviour of 10-Substituted Spiro[4.5]decanes
Chemische Berichte, 1991, 124, 551-561
1100336 CIFC17 H12 Cr N2 O4P -16.329; 7.805; 16.812
77.29; 83.14; 78.75
792.01Dötz, Karl Heinz; Rau, Alexander; Harms, Klaus
Reaktionen von Komplexliganden, IL. Synthese und Struktur fünf- und sechsgliedriger Aminocarben-C,N-Chelatkomplexe des Chroms
Chemische Berichte, 1992, 125, 2137-2142
1100337 CIFC14 H13 Mo N O5P 1 21/c 18.37; 15.438; 12.661
90; 106.43; 90
1569.2Dötz, Karl Heinz; Larbig, Harald; Harms, Klaus
Reaktionen von Komplexliganden, LI. Synthese und Reaktionen stabiler (Carben)tetracarbonyl-Chelatkomplexe des Molybdäns
Chemische Berichte, 1992, 125, 2143-2148
1100338 CIFC25 H26 Cr N2 O4P 1 21/n 110.796; 15.242; 14.732
90; 99.32; 90
2392.19Dötz, Karl Heinz; Rau, Alexander; Harms, Klaus
Reaktionen von komplexliganden: LII. Sechsgliedrige aminocarben-chelatkomplexe: Synthese, alkin/carben-verknüpfung und carbenanellierung
Journal of Organometallic Chemistry, 1992, 439, 263-277
1100339 CIFC25 H35 Li3 N6 O8P 1 21/n 17.815; 14.467; 27.772
90; 92.175; 90
3137.63Hiller, Wolfgang; Frey, Stephanie; Strähle, Joachim; Boche, Gernot; Zarges, Wolfgang; Harms, Klaus; Marsch, Michael; Wollert, René; Dehnicke, Kurt
Die Kristallstrukturen von {Li~3~(12-Krone-4)~2~[HC(CN)~2~]~3~}, {Na(15-Krone-5)-[HC(CN)~2~]} und {Na[N(nBu)~4~][HC(CN)~2~]~2~ · THF}
Chemische Berichte, 1992, 125, 87-92
1100340 CIFC13 H21 N2 Na O5P 1 21 17.345; 14.108; 7.785
90; 95.065; 90
803.56Hiller, Wolfgang; Frey, Stephanie; Strähle, Joachim; Boche, Gernot; Zarges, Wolfgang; Harms, Klaus; Marsch, Michael; Wollert, René; Dehnicke, Kurt
Die Kristallstrukturen von {Li~3~(12-Krone-4)~2~[HC(CN)~2~]~3~}, {Na(15-Krone-5)-[HC(CN)~2~]} und {Na[N(nBu)~4~][HC(CN)~2~]~2~ · THF}
Chemische Berichte, 1992, 125, 87-92
1100341 CIFC26 H46 N5 Na OP 21 21 2113.312; 13.874; 15.717
90; 90; 90
2902.78Hiller, Wolfgang; Frey, Stephanie; Strähle, Joachim; Boche, Gernot; Zarges, Wolfgang; Harms, Klaus; Marsch, Michael; Wollert, René; Dehnicke, Kurt
Die Kristallstrukturen von {Li~3~(12-Krone-4)~2~[HC(CN)~2~]~3~}, {Na(15-Krone-5)-[HC(CN)~2~]} und {Na[N(nBu)~4~][HC(CN)~2~]~2~ · THF}
Chemische Berichte, 1992, 125, 87-92
1100342 CIFC39 H52 B N O9P 110.938; 13.923; 14.477
101.16; 109.52; 104.29
1919.53Reetz, Manfred T.; Niemeyer, Christof M.; Harms, Klaus
Heterotopic Host Molecules for Binding Two Different Guests
Angewandte Chemie, International Edition in English, 1991, 30, 1474-1476

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