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#$Date: 2016-02-13 20:28:24 +0100 (Sat, 13 Feb 2016) $
#$Revision: 176429 $
#$URL: svn://saulius.grazulis.lt/cod-secondary/cif/1/53/59/1535966.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_1535966
loop_
_publ_author_name
'Jacobsen, H.'
'Blasse, G.'
'Meyer, G.'
'Schipper, W.'
_publ_section_title
;
 Synthesis, structures and luminescence of two new europium(II)
 silicate-chlorides, Eu2SiO3Cl2 and Eu5SiO4Cl6
;
_journal_name_full
'Zeitschrift fuer Anorganische und Allgemeine Chemie'
_journal_page_first              451
_journal_page_last               456
_journal_volume                  620
_journal_year                    1994
_chemical_formula_sum            'Cl6 Eu5 O4 Si'
_chemical_name_systematic        'Eu5 Cl6 (Si O4)'
_space_group_IT_number           15
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_cell_angle_alpha                90
_cell_angle_beta                 103.51
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   9.004
_cell_length_b                   14.017
_cell_length_c                   11.123
_cell_volume                     1364.978
_citation_journal_id_ASTM        ZAACAB
_cod_data_source_file            Jacobsen_ZAACAB_1994_1579.cif
_cod_data_source_block           Cl6Eu5O4Si1
_cod_original_cell_volume        1364.979
_cod_original_formula_sum        'Cl6 Eu5 O4 Si1'
_cod_database_code               1535966
loop_
_symmetry_equiv_pos_as_xyz
x,y,z
-x,y,-z+1/2
-x,-y,-z
x,-y,z-1/2
x+1/2,y+1/2,z
-x+1/2,y+1/2,-z+1/2
-x+1/2,-y+1/2,-z
x+1/2,-y+1/2,z-1/2
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
Eu2 Eu+2 0.34734 0.07956 0.86799 1 0.0
Si1 Si+4 0.5 0.4215 0.25 1 0.0
Cl1 Cl-1 0.5 0.2453 0.75 1 0.0
Eu3 Eu+2 0.05526 0.12908 0.48084 1 0.0
Eu1 Eu+2 0.5 0.19968 0.25 1 0.0
Cl3 Cl-1 0.1758 0.47 0.8607 1 0.0
O2 O-2 0.0821 0.9788 0.3738 1 0.0
O1 O-2 0.6287 0.3512 0.2132 1 0.0
Cl4 Cl-1 0.1295 0.6491 0.0473 1 0.0
Cl2 Cl-1 0.75 0.25 0.5 1 0.0
