Information card for entry 1100258

Structure parameters

• Chemical name: (μ~3~-Triphenylphosphanimino)-tris(μ~3~-N-(triphenylphosphino)imino(dimethyl )siloxy)-(dimethoxyethane-O)-tetra-lithium dimethoxyethane solvate
• Formula: C84 H93 Li4 N4 O6 P4 Si3
• Calculated formula: C263 H234 Li10 N10 O17 P10 Si9
• Title of publication: Phosphaniminate von Alkalimetallen: Die Kristallstrukturen von [KNPCy~3~]~4~, [KNPCy~3~]~4~·2OPCy~3~, [CsNPCy~3~]~4~·4OPCy~3~ und [Li~4~(NPPh~3~)(OSiMe~2~NPPh~3~)~3~(DME)]
• Authors of publication: Gröb, Thorsten; Chitsaz, Soheila; Harms, Klaus; Dehnicke, Kurt
• Journal of publication: Zeitschrift fuer Anorganische und Allgemeine Chemie
• Year of publication: 2002
• Journal volume: 628
• Journal issue: 2
• Pages of publication: 473 - 479
• a: 15.835 ± 0.001 Å
• b: 15.835 ± 0.001 Å
• c: 117.553 ± 0.005 Å
• α: 90°
• β: 90°
• γ: 120°
• Cell volume: 25527 ų
• Ambient diffraction temperature: 193 K
• Number of distinct elements: 7
• Space group number: 167
• Hermann-Mauguin space group symbol: R -3 c :H
• Hall space group symbol: -R 3 2"c
• Residual factor for significantly intense reflections: 4.95
• Weighted residual factors for significantly intense reflections: 4.95
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No