Information card for entry 1100410

Structure parameters

• Formula: C25 H25 Co3 Cr O7 P2
• Calculated formula: C25 H25 Co3 Cr O7 P2
• Title of publication: Metal π-complexes of benzene derivatives XLVIII. Dimethylphosphano derivatives of bis(benzene) chromium as monodentate and chelating ligands at μ-ethylidyne-nona(carbonyl)-tri(cobalt). Synthesis via ETC-autocatalysis, crystal structure determination and redox behavior of [(Me~2~P-η^6^-C~6~H~5~)(η^6^-C~6~H~6~)Cr[(μ-MeC)Co~3~(CO)~8~], [(Me~2~P-η^6^-C~6~H~5~)~2~Cr][(μ-MeC) Co~3~(CO)~8~]~2~ and [(Me~2~P-η^6^-C~6~H~5~)~2~Cr][μ,-MeC)Co~3~(CO)~7~]
• Authors of publication: Elschenbioich, Christoph; Isenburg, Thomas; Behrendt, Andreas; Frenzen, Gerlinde; Harms, Klaus
• Journal of publication: Journal of Organometallic Chemistry
• Year of publication: 1995
• Journal volume: 501
• Journal issue: 1-2
• Pages of publication: 129 - 144
• a: 10.474 ± 0.002 Å
• b: 10.68 ± 0.001 Å
• c: 14.424 ± 0.002 Å
• α: 90.36 ± 0.01°
• β: 110.34 ± 0.01°
• γ: 113.32 ± 0.01°
• Cell volume: 1369.77 ų
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No