Information card for entry 1100579

Structure parameters

• Formula: C38 H83 N3 Na O3 Si6 Sm
• Calculated formula: C38 H83 N3 Na O3 Si6 Sm
• SMILES: C[Si](N([Sm](N([Si](C)(C)C)[Si](C)(C)C)(N([Si](C)(C)C)[Si](C)(C)C)C#Cc1ccccc1)[Si](C)(C)C)(C)C.[O]1(CCCC1)[Na]([O]1CCCC1)[O]1CCCC1
• Title of publication: Amidometallate von Seltenerdelementen. Synthese und Kristallstrukturen von [Na(12-Krone-4)~2~][M{N(SiMe~3~)~2~}~3~(OSiMe~3~)] (M = Sm, Yb), [Na(THF)~3~Sm{N(SiMe~3~)~2~}~3~(C≡C-Ph)], [Na(THF)~6~][Lu~2~(μ-NH~2~)(μ-NSiMe~3~){N(SiMe~3~)~2~}~4~] sowie von [NaN(SiMe~3~)~2~(THF)]~2~. Anwendungen der Seltenerdkomplexe als Polymerisationskatalysatoren
• Authors of publication: Karl, M.; Seybert, G.; Massa, W.; Harms, K.; Agarwal, S.; Maleika, R.; Stelter, W.; Greiner, A.; Neumüller, W.; Heitz, B.; Dehnicke, K.
• Journal of publication: Zeitschrift für anorganische und allgemeine Chemie
• Year of publication: 1999
• Journal volume: 625
• Journal issue: 8
• Pages of publication: 1301 - 1309
• a: 13.4447 ± 0.001 Å
• b: 23.2529 ± 0.0014 Å
• c: 17.3216 ± 0.0014 Å
• α: 90°
• β: 93.549 ± 0.009°
• γ: 90°
• Cell volume: 5404.84 ų
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No