Information card for entry 1100735

Structure parameters

• Formula: Cl3 Eu H82 K5 O155.5 P4 W34
• Calculated formula: Cl3 Eu K5 O155.5 P4 W34
• SMILES: [W]1234(=O)O[Eu]56789(O[W]%10%11%12(=O)[O]%13[W]%14%15(=O)(O[W]%16%17%18(=O)[O]%19[W](=O)(O3)(O[W]3%20%21(=O)[O]%22[W]%23(=O)(O%20)(O[W]%20%24(=O)([O]%25[W]%26(=O)(O[W]%27%28(=O)(O6)[O]6[W](=O)(O%27)(O3)(O[W]3%27(=O)([O]%29([W](=O)(O%23)(O%24)(O3)O[W]%29(=O)(O%28)(O%26)O%27)P%22%25=6)O%21)O2)(O%20)O%11)O%14)O%17)(O%16)O[W]23(=O)([O]6([W](=O)(O%18)(O%15)(O2)O[W]6(=O)(O5)(O%12)O3)P%13%19=[O]1)O4)O%10)O[W]123(=O)[O]4[W]56(=O)(O2)O[W]2%10%11(=O)[O]%12[W]%13(=O)(O1)(O[W]1%14(=O)(O9)[O]9[W]%15%16(=O)(O[W]%17%18(=O)(O7)[O]=P74[O]4[W]%19%20(=O)(O5)O[W]5%21(=O)([O]%22[W](=O)(O[W]4(=O)(O%19)(O%17)O[W]4%17(=O)([O]%197[W](=O)(O8)(O3)(O[W]%19(=O)(O6)(O%20)O%17)O4)O%18)(O5)(O%15)O[W]34(=O)([O]5([W](=O)(O%14)(O%13)(O[W]5(=O)(O%11)(O%21)O4)O3)P=%129%22)O%16)O%10)O1)O2.[K+].[K+].[K+].[K+].[K+].[Cl-].[Cl-].[Cl-].O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O
• Title of publication: Influence of Steric and Electronic Properties of the Defect Site, Lanthanide Ionic Radii, and Solution Conditions on the Composition of Lanthanide(III) α1-P2W17O6110-Polyoxometalates
• Authors of publication: Cheng Zhang; Robertha C. Howell; Qun-Hui Luo; Heidi L. Fieselmann; Louis J. Todaro; Lynn C. Francesconi
• Journal of publication: Inorganic Chemistry
• Year of publication: 2005
• Journal volume: 44
• Pages of publication: 3569 - 3578
• a: 16.432 ± 0.003 Å
• b: 21.204 ± 0.004 Å
• c: 25.86 ± 0.005 Å
• α: 88.82 ± 0.03°
• β: 82.32 ± 0.03°
• γ: 69.61 ± 0.03°
• Cell volume: 8367 ± 3 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1786
• Residual factor for significantly intense reflections: 0.1125
• Weighted residual factors for significantly intense reflections: 0.2761
• Weighted residual factors for all reflections included in the refinement: 0.3158
• Goodness-of-fit parameter for all reflections included in the refinement: 1.053
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No