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Information card for entry 1503338
Preview
Coordinates | 1503338.cif |
---|---|
Original paper (by DOI) | HTML |
Chemical name | 4,5-dimethyl-3,6-dioxa-1,2-disila-1,1,2,2-tetraphenylcyclohexane |
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Formula | C28 H28 O2 Si2 |
Calculated formula | C28 H28 O2 Si2 |
SMILES | [Si]1([Si](OC(C(O1)C)C)(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1 |
Title of publication | Silane-controlled diastereoselectivity in the tris(pentafluorophenyl)borane-catalyzed reduction of alpha-diketones to silyl-protected 1,2-Diols. |
Authors of publication | Skjel, Miranda K.; Houghton, Adrian Y.; Kirby, Andrea E.; Harrison, Daniel J.; McDonald, Robert; Rosenberg, Lisa |
Journal of publication | Organic letters |
Year of publication | 2010 |
Journal volume | 12 |
Journal issue | 2 |
Pages of publication | 376 - 379 |
a | 9.14 ± 0.002 Å |
b | 10.032 ± 0.003 Å |
c | 15.034 ± 0.004 Å |
α | 111.523 ± 0.004° |
β | 104.962 ± 0.004° |
γ | 95.676 ± 0.004° |
Cell volume | 1209.8 ± 0.6 Å3 |
Cell temperature | 193 ± 2 K |
Ambient diffraction temperature | 193 ± 2 K |
Number of distinct elements | 4 |
Space group number | 2 |
Hermann-Mauguin space group symbol | P -1 |
Hall space group symbol | -P 1 |
Residual factor for all reflections | 0.1016 |
Residual factor for significantly intense reflections | 0.059 |
Weighted residual factors for significantly intense reflections | 0.1507 |
Weighted residual factors for all reflections included in the refinement | 0.1698 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.057 |
Diffraction radiation wavelength | 0.71073 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | Yes |
Has Fobs | No |
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The link is: https://www.crystallography.net/1503338.html
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