Enantiopure 2-substituted glyceraldehyde derivatives by aza-Claisen rearrangement or C-alkylation of enamines.
Authors of publication
Bridgwood, Katy L.; Tzschucke, C. Christoph; O'Brien, Matthew; Wittrock, Sven; Goodman, Jonathan M.; Davies, John E.; Logan, Angus W. J.; Hüttl, Matthias R M; Ley, Steven V.
Journal of publication
Organic letters
Year of publication
2008
Journal volume
10
Journal issue
20
Pages of publication
4537 - 4540
a
22.3552 ± 0.0004 Å
b
6.7979 ± 0.0002 Å
c
11.9364 ± 0.0003 Å
α
90°
β
117.424 ± 0.002°
γ
90°
Cell volume
1610.11 ± 0.07 Å3
Cell temperature
180 ± 2 K
Ambient diffraction temperature
180 ± 2 K
Number of distinct elements
3
Space group number
5
Hermann-Mauguin space group symbol
C 1 2 1
Hall space group symbol
C 2y
Residual factor for all reflections
0.0578
Residual factor for significantly intense reflections
0.0438
Weighted residual factors for significantly intense reflections
0.0954
Weighted residual factors for all reflections included in the refinement
0.1034
Goodness-of-fit parameter for all reflections included in the refinement
