Information card for entry 1505971

Structure parameters

• Formula: C20 H35 N O2 Si2
• Calculated formula: C20 H35 N O2 Si2
• SMILES: [Si](O[C@H]1NC(=O)[C@H]([C@@]1([Si](C)(C)c1ccccc1)C)C)(C)(C)C(C)(C)C.[Si](O[C@@H]1NC(=O)[C@@H]([C@]1([Si](C)(C)c1ccccc1)C)C)(C)(C)C(C)(C)C
• Title of publication: Stereoselective synthesis of highly substituted gamma-lactams by the [3+2] annulation of alpha-siloxy allylic silanes with chlorosulfonyl isocyanate.
• Authors of publication: Romero, Antonio; Woerpel, K. A.
• Journal of publication: Organic letters
• Year of publication: 2006
• Journal volume: 8
• Journal issue: 10
• Pages of publication: 2127 - 2130
• a: 6.9889 ± 0.001 Å
• b: 12.7368 ± 0.0019 Å
• c: 14.102 ± 0.002 Å
• α: 114.04 ± 0.002°
• β: 99.928 ± 0.003°
• γ: 93.764 ± 0.002°
• Cell volume: 1116.3 ± 0.3 ų
• Cell temperature: 163 ± 2 K
• Ambient diffraction temperature: 163 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0407
• Residual factor for significantly intense reflections: 0.0328
• Weighted residual factors for significantly intense reflections: 0.0815
• Weighted residual factors for all reflections included in the refinement: 0.0892
• Goodness-of-fit parameter for all reflections included in the refinement: 1.066
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No