Information card for entry 1506543

Structure parameters

• Chemical name: P,P-diphenyl-N-(1-dimethylphenylsilyl-3-methylmethylene)-phosphinic amide
• Formula: C28 H30 N O P Si
• Calculated formula: C28 H30 N O P Si
• SMILES: [Si](C(NP(=O)(c1ccccc1)c1ccccc1)c1cc(ccc1)C)(C)(C)c1ccccc1
• Title of publication: Stereoselective synthesis of alpha-silylamines by the direct addition of silyl anions to activated imines.
• Authors of publication: Ballweg, David M.; Miller, Rebecca C.; Gray, Danielle L.; Scheidt, Karl A.
• Journal of publication: Organic letters
• Year of publication: 2005
• Journal volume: 7
• Journal issue: 7
• Pages of publication: 1403 - 1406
• a: 9.7494 ± 0.0008 Å
• b: 12.3191 ± 0.0011 Å
• c: 12.4391 ± 0.0011 Å
• α: 101.789 ± 0.001°
• β: 111.839 ± 0.001°
• γ: 107.544 ± 0.001°
• Cell volume: 1234.86 ± 0.19 ų
• Cell temperature: 153 ± 2 K
• Ambient diffraction temperature: 153 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0744
• Residual factor for significantly intense reflections: 0.0492
• Weighted residual factors for significantly intense reflections: 0.118
• Weighted residual factors for all reflections included in the refinement: 0.1308
• Goodness-of-fit parameter for all reflections included in the refinement: 1.001
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No