Information card for entry 1506911

Structure parameters

• Formula: C37 H45 N O2 Si Sn
• Calculated formula: C37 H45 N O2 Si Sn
• SMILES: [Sn]([C@H](/C=C(/[Si](C)(C)C)OC(=O)N(C(C)C)C(C)C)c1ccccc1)(c1ccccc1)(c1ccccc1)c1ccccc1
• Title of publication: Highly enantioenriched homoenolate reagents by asymmetric gamma-deprotonation of achiral 1-silyl-substituted 1-alkenyl carbamates.
• Authors of publication: Reuber, Jenny; Fröhlich, Roland; Hoppe, Dieter
• Journal of publication: Organic letters
• Year of publication: 2004
• Journal volume: 6
• Journal issue: 5
• Pages of publication: 783 - 786
• a: 9.245 ± 0.001 Å
• b: 11.945 ± 0.001 Å
• c: 32.509 ± 0.001 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 3590 ± 0.5 ų
• Cell temperature: 198 ± 2 K
• Ambient diffraction temperature: 198 ± 2 K
• Number of distinct elements: 6
• Space group number: 19
• Hermann-Mauguin space group symbol: P 21 21 21
• Hall space group symbol: P 2ac 2ab
• Residual factor for all reflections: 0.0682
• Residual factor for significantly intense reflections: 0.0396
• Weighted residual factors for significantly intense reflections: 0.0607
• Weighted residual factors for all reflections included in the refinement: 0.0677
• Goodness-of-fit parameter for all reflections included in the refinement: 1.012
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No