Design, preparation, X-ray crystal structure, and reactivity of o-alkoxyphenyliodonium bis(methoxycarbonyl)methanide, a highly soluble carbene precursor.
Authors of publication
Zhu, Chenjie; Yoshimura, Akira; Ji, Lei; Wei, Yunyang; Nemykin, Victor N.; Zhdankin, Viktor V.
Journal of publication
Organic letters
Year of publication
2012
Journal volume
14
Journal issue
12
Pages of publication
3170 - 3173
a
9.3953 ± 0.0005 Å
b
10.2384 ± 0.0005 Å
c
10.6318 ± 0.0007 Å
α
95.355 ± 0.007°
β
92.172 ± 0.007°
γ
109.933 ± 0.008°
Cell volume
954.58 ± 0.11 Å3
Cell temperature
123 K
Ambient diffraction temperature
123 K
Number of distinct elements
4
Space group number
2
Hermann-Mauguin space group symbol
P -1
Hall space group symbol
-P 1
Residual factor for all reflections
0.0603
Residual factor for significantly intense reflections
0.0519
Weighted residual factors for all reflections
0.1062
Weighted residual factors for significantly intense reflections
0.0908
Weighted residual factors for all reflections included in the refinement
0.1062
Goodness-of-fit parameter for all reflections included in the refinement