Information card for entry 1513602

Structure parameters

• Formula: C38 H65 Cl N2 O3 Rh Si
• Calculated formula: C38.04 H57.517 Cl N2 O3 Rh Si
• SMILES: [Rh]123(Cl)([CH]4=[CH]1CC[CH]2=[CH]3CC4)=C1N(C=CN1c1c(C(C)C)cccc1C(C)C)CCC[Si](OC(C)C)(OC(C)C)OC(C)C.CCCCCC
• Title of publication: Heterogeneous catalysts based on supported Rh‒NHC complexes: synthesis of high molecular weight poly(silyl ether)s by catalytic hydrosilylation
• Authors of publication: Lázaro, Guillermo; Fernández-Alvarez, Francisco J.; Iglesias, Manuel; Horna, Cristina; Vispe, Eugenio; Sancho, Rodrigo; Lahoz, Fernando J.; Iglesias, Marta; Pérez-Torrente, Jesús J.; Oro, Luis A.
• Journal of publication: Catalysis Science & Technology
• Year of publication: 2014
• Journal volume: 4
• Journal issue: 1
• Pages of publication: 62
• a: 10.2529 ± 0.0012 Å
• b: 12.602 ± 0.0015 Å
• c: 16.39 ± 0.002 Å
• α: 73.082 ± 0.002°
• β: 87.303 ± 0.002°
• γ: 89.419 ± 0.002°
• Cell volume: 2023.8 ± 0.4 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0772
• Residual factor for significantly intense reflections: 0.0545
• Weighted residual factors for significantly intense reflections: 0.1325
• Weighted residual factors for all reflections included in the refinement: 0.146
• Goodness-of-fit parameter for all reflections included in the refinement: 1.008
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No