Information card for entry 1514412

Structure parameters

• Formula: C25 H23 P Si
• Calculated formula: C25 H23 P Si
• Title of publication: A metal‒amide dependent, catalytic C‒H functionalisation of triphenylphosphonium methylide
• Authors of publication: Nako, Adi E.; White, Andrew J. P.; Crimmin, Mark R.
• Journal of publication: Chemical Science
• Year of publication: 2013
• Journal volume: 4
• Journal issue: 2
• Pages of publication: 691
• a: 11.2823 ± 0.0003 Å
• b: 16.8988 ± 0.0004 Å
• c: 22.9869 ± 0.0006 Å
• α: 81.236 ± 0.002°
• β: 79.739 ± 0.002°
• γ: 81.615 ± 0.002°
• Cell volume: 4230.32 ± 0.19 ų
• Cell temperature: 173 K
• Ambient diffraction temperature: 173 K
• Number of distinct elements: 4
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0824
• Residual factor for significantly intense reflections: 0.0539
• Weighted residual factors for significantly intense reflections: 0.1272
• Weighted residual factors for all reflections included in the refinement: 0.139
• Goodness-of-fit parameter for all reflections included in the refinement: 1.037
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No