Information card for entry 1514992

Structure parameters

• Common name: {[SiP(iPr)3]Ni-N2}{BArF}
• Formula: C77.75 H75.75 B F24 N2 Ni P3 Si
• Calculated formula: C79.064 H77.064 B F24 N2 Ni P3 Si
• Title of publication: Thermally stable N2 and H2 adducts of cationic nickel(ii)
• Authors of publication: Tsay, Charlene; Peters, Jonas C.
• Journal of publication: Chemical Science
• Year of publication: 2012
• Journal volume: 3
• Journal issue: 4
• Pages of publication: 1313
• a: 47.534 ± 0.004 Å
• b: 13.9003 ± 0.0011 Å
• c: 30.423 ± 0.002 Å
• α: 90°
• β: 128.63 ± 0.001°
• γ: 90°
• Cell volume: 15703 ± 2 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 8
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.068
• Residual factor for significantly intense reflections: 0.0464
• Weighted residual factors for significantly intense reflections: 0.114
• Weighted residual factors for all reflections included in the refinement: 0.1291
• Goodness-of-fit parameter for all reflections included in the refinement: 1.021
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No