Information card for entry 1518480

Structure parameters

• Formula: C66 H86 Cl20 F24 O16 Pd4 Sb4
• Calculated formula: C64 H84 Cl16 F24 O16 Pd4 Sb4
• SMILES: [Sb](F)(F)(F)(F)([F-])F.[Sb](F)(F)(F)(F)([F-])F.[Sb](F)(F)(F)(F)([F-])F.[Sb](F)(F)(F)(F)([F-])F.[Pd]1234[O]=C(OC)[C@@H]5[C@H]6[C@H]7[C@H]([Pd]89([O]=C(OC)[C@H]%10[C@@H]%11[C@H]%12[Pd]%13%14([O]=C(OC)[C@@H]%15[C@H]%16[C@H]%17[C@H]([Pd]%18%19([O]=C(OC)[C@@H]%20[C@H]%21[C@H](C[CH]3=[CH2]2)[C@H]4[C@@H]([C@@H]%20C(=[O]%18)OC)C%21)[CH2]=[CH]%19C%17)[C@@H]([C@@H]%15C(=[O]%13)OC)C%16)[CH2]=[CH]%14C[C@H]%12[C@@H](C%11)[C@H]%10C(=[O]8)OC)[CH2]=[CH]9C7)[C@@H]([C@@H]5C(=[O]1)OC)C6.ClC(Cl)C(Cl)Cl.ClC(Cl)C(Cl)Cl.ClC(Cl)C(Cl)Cl.ClC(Cl)C(Cl)Cl.[Sb](F)(F)(F)(F)([F-])F.[Sb](F)(F)(F)(F)([F-])F.[Sb](F)(F)(F)(F)([F-])F.[Sb](F)(F)(F)(F)([F-])F.[Pd]1234[O]=C(OC)[C@H]5[C@@H]6[C@@H]7[C@@H]([Pd]89([O]=C(OC)[C@@H]%10[C@H]%11[C@@H]%12[Pd]%13%14([O]=C(OC)[C@H]%15[C@@H]%16[C@@H]%17[C@@H]([Pd]%18%19([O]=C(OC)[C@H]%20[C@@H]%21[C@@H](C[CH]3=[CH2]2)[C@@H]4[C@H]([C@H]%20C(=[O]%18)OC)C%21)[CH2]=[CH]%19C%17)[C@H]([C@H]%15C(=[O]%13)OC)C%16)[CH2]=[CH]%14C[C@@H]%12[C@H](C%11)[C@@H]%10C(=[O]8)OC)[CH2]=[CH]9C7)[C@H]([C@H]5C(=[O]1)OC)C6.ClC(Cl)C(Cl)Cl.ClC(Cl)C(Cl)Cl.ClC(Cl)C(Cl)Cl.ClC(Cl)C(Cl)Cl
• Title of publication: Bypassing the lack of reactivity of endo-substituted norbornenes with the catalytic rectification‒insertion mechanism
• Authors of publication: Commarieu, Basile; Claverie, Jerome P.
• Journal of publication: Chem. Sci.
• Year of publication: 2015
• Journal volume: 6
• Journal issue: 4
• Pages of publication: 2172
• a: 16.4284 ± 0.0014 Å
• b: 19.3745 ± 0.0017 Å
• c: 21.4447 ± 0.0019 Å
• α: 66.181 ± 0.002°
• β: 88.434 ± 0.002°
• γ: 72.775 ± 0.002°
• Cell volume: 5930.9 ± 0.9 ų
• Cell temperature: 200 ± 2 K
• Ambient diffraction temperature: 200 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0963
• Residual factor for significantly intense reflections: 0.056
• Weighted residual factors for significantly intense reflections: 0.1355
• Weighted residual factors for all reflections included in the refinement: 0.1494
• Goodness-of-fit parameter for all reflections included in the refinement: 1.043
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No