Information card for entry 1518522

Structure parameters

• Formula: C108 H73 Au6 F18 Mo12 O42 P7
• Calculated formula: C108 H64.5 Au6 F18 Mo12 O42 P7
• SMILES: [Au]12([Au]([P](c3cc(F)ccc3)(c3cc(F)ccc3)c3cc(F)ccc3)[O]2([Au][P](c2cc(F)ccc2)(c2cc(F)ccc2)c2cc(F)ccc2)[Au]1[P](c1cc(F)ccc1)(c1cc(F)ccc1)c1cc(F)ccc1)[P](c1cc(F)ccc1)(c1cc(F)ccc1)c1cc(F)ccc1.[Au]([P](c1cc(F)ccc1)(c1cc(F)ccc1)c1cc(F)ccc1)O[Au][P](c1cc(F)ccc1)(c1cc(F)ccc1)c1cc(F)ccc1.[Mo]1234(=O)O[Mo]567(=O)O[Mo]89(=O)(O1)O[Mo]1%10%11(=O)O[Mo]%12%13(=O)(O[Mo]%14%15(=O)(O1)O[Mo]1%16%17(=O)O[Mo]%18%19(=O)(O[Mo](=O)(O1)(O5)(O%12)[O]7%13=P15[O]4%19[Mo]4(=O)(O[Mo](=O)(O[Mo](=O)(O4)(O%14)(O%16)[O]5%15%17)(O8)(O%10)[O]19%11)(O3)O%18)O2)O6
• Title of publication: Various Oxygen-Centered Phosphanegold(I) Cluster Cations Formed by Polyoxometalate (POM)-Mediated Clusterization: Effects of POMs and Phosphanes
• Authors of publication: Yoshida, Takuya; Yasuda, Yuta; Nagashima, Eri; Arai, Hidekazu; Matsunaga, Satoshi; Nomiya, Kenji
• Journal of publication: Inorganics
• Year of publication: 2014
• Journal volume: 2
• Journal issue: 4
• Pages of publication: 660
• a: 16.191 ± 0.002 Å
• b: 29.165 ± 0.004 Å
• c: 35.365 ± 0.004 Å
• α: 99.801 ± 0.002°
• β: 99.153 ± 0.002°
• γ: 104.963 ± 0.002°
• Cell volume: 15532 ± 3 ų
• Cell temperature: 100 K
• Ambient diffraction temperature: 100 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1077
• Residual factor for significantly intense reflections: 0.0723
• Weighted residual factors for significantly intense reflections: 0.1625
• Weighted residual factors for all reflections included in the refinement: 0.1753
• Goodness-of-fit parameter for all reflections included in the refinement: 1.027
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No