Information card for entry 1518666

Structure parameters

• Chemical name: [(dmpe)SbF][OTf]2
• Formula: C8 H16 F7 O6 P2 S2 Sb
• Calculated formula: C8 H16 F7 O6 P2 S2 Sb
• SMILES: [Sb]1([P](CC[P]1(C)C)(C)C)F.S(=O)(=O)([O-])C(F)(F)F.S(=O)(=O)([O-])C(F)(F)F
• Title of publication: Synthesis and reactivity of cyclo-tetra(stibinophosphonium) tetracations: redox and coordination chemistry of phosphine‒antimony complexes
• Authors of publication: Chitnis, Saurabh S.; Robertson, Alasdair P. M.; Burford, Neil; Weigand, Jan J.; Fischer, Roland
• Journal of publication: Chem. Sci.
• Year of publication: 2015
• Journal volume: 6
• Journal issue: 4
• Pages of publication: 2559
• a: 14.5029 ± 0.0006 Å
• b: 8.9034 ± 0.0004 Å
• c: 14.9927 ± 0.0006 Å
• α: 90°
• β: 97.26 ± 0.001°
• γ: 90°
• Cell volume: 1920.41 ± 0.14 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173.15 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0269
• Residual factor for significantly intense reflections: 0.0214
• Weighted residual factors for significantly intense reflections: 0.0473
• Weighted residual factors for all reflections included in the refinement: 0.049
• Goodness-of-fit parameter for all reflections included in the refinement: 1.023
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No