Information card for entry 1518668

Structure parameters

• Chemical name: [(Et3P)4Sb4][OTf]4
• Formula: C29 H61.5 F12 N0.5 O12 P4 S4 Sb4
• Calculated formula: C29 H61.5 F12 N0.5 O12 P4 S4 Sb4
• SMILES: [Sb]1([Sb]([Sb]([Sb]1[P+](CC)(CC)CC)[P+](CC)(CC)CC)[P+](CC)(CC)CC)[P+](CC)(CC)CC.S(=O)(=O)([O-])C(F)(F)F.S(=O)(=O)([O-])C(F)(F)F.S(=O)(=O)([O-])C(F)(F)F.S(=O)(=O)([O-])C(F)(F)F.CC#N
• Title of publication: Synthesis and reactivity of cyclo-tetra(stibinophosphonium) tetracations: redox and coordination chemistry of phosphine‒antimony complexes
• Authors of publication: Chitnis, Saurabh S.; Robertson, Alasdair P. M.; Burford, Neil; Weigand, Jan J.; Fischer, Roland
• Journal of publication: Chem. Sci.
• Year of publication: 2015
• Journal volume: 6
• Journal issue: 4
• Pages of publication: 2559
• a: 23.986 ± 0.016 Å
• b: 21.83 ± 0.014 Å
• c: 22.193 ± 0.015 Å
• α: 90°
• β: 106.57 ± 0.014°
• γ: 90°
• Cell volume: 11138 ± 13 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0626
• Residual factor for significantly intense reflections: 0.056
• Weighted residual factors for significantly intense reflections: 0.1447
• Weighted residual factors for all reflections included in the refinement: 0.1485
• Goodness-of-fit parameter for all reflections included in the refinement: 1.225
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No