Information card for entry 1518895

Structure parameters

• Formula: C57.5 H67 Cl O P2 Ru Si
• Calculated formula: C57.5 H52 Cl O P2 Ru Si
• Title of publication: Synthesis of Ruthenium Complexes with a NonspectatorSi,O,P-Chelate Ligand: Interconversion between a Hydrido(η2-silane) Complex and a Silyl Complex Leading to Catalytic Alkene Hydrogenation
• Authors of publication: Komuro, Takashi; Arai, Takafumi; Kikuchi, Kei; Tobita, Hiromi
• Journal of publication: Organometallics
• Year of publication: 2015
• Journal volume: 34
• Journal issue: 7
• Pages of publication: 1211
• a: 10.6569 ± 0.0004 Å
• b: 18.1443 ± 0.0005 Å
• c: 26.9876 ± 0.0008 Å
• α: 90°
• β: 92.5022 ± 0.0009°
• γ: 90°
• Cell volume: 5213.4 ± 0.3 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.1064
• Residual factor for significantly intense reflections: 0.0857
• Weighted residual factors for significantly intense reflections: 0.1915
• Weighted residual factors for all reflections included in the refinement: 0.2047
• Goodness-of-fit parameter for all reflections included in the refinement: 1.246
• Diffraction radiation wavelength: 0.71069 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No