Information card for entry 1519069

Structure parameters

• Formula: C35 H28 Cl N2 O P2 Rh
• Calculated formula: C35 Cl N2 O P2 Rh
• SMILES: [Rh](Cl)([P](c1ccccc1)(c1cnccc1)c1ccccc1)([P](c1ccccc1)(c1cnccc1)c1ccccc1)C#[O]
• Title of publication: Reactions of 3-Pyridyldiphenylphosphine with Rh2(CO)4Cl2 and Co2(CO)8. Crystallographic and Catalytic Studies of Rh(CO)Cl(3-PyPPh2)2.
• Authors of publication: Laitinen, Riitta H.; Soininen, Jaakko; Suomalainen, Pekka; Pakkanen, Tapani A.; Ahlgren, Markku; Pursiainen, Jouni
• Journal of publication: Acta Chemica Scandinavica
• Year of publication: 1999
• Journal volume: 53
• Pages of publication: 335 - 339
• a: 11.677 ± 0.003 Å
• b: 23.536 ± 0.007 Å
• c: 12.215 ± 0.003 Å
• α: 90°
• β: 112.13 ± 0.02°
• γ: 90°
• Cell volume: 3109.7 ± 1.5 ų
• Ambient diffraction temperature: 293 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for significantly intense reflections: 0.0405
• Weighted residual factors for significantly intense reflections: 0.0898
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71069 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No