Information card for entry 1521286

Structure parameters

• Chemical name: mu-carbido-[(4'-phenyl-2,2':6',2''-terpyridine)silver(I)-dichlorobis(tricyclohexylphosphine)ruthenium(VI)]triflate
• Formula: C61 H83 Ag Cl8 F3 N3 O3 P2 Ru S
• Calculated formula: C61 H83 Ag Cl8 F3 N3 O3 P2 Ru S
• SMILES: Cl[Ru](Cl)(#C[Ag]12[n]3c(c4cc(cc(c5cccc[n]25)[n]14)c1ccccc1)cccc3)([P](C1CCCCC1)(C1CCCCC1)C1CCCCC1)[P](C1CCCCC1)(C1CCCCC1)C1CCCCC1.C(S(=O)(=O)[O-])(F)(F)F.C(Cl)(Cl)Cl.ClC(Cl)Cl
• Title of publication: Carbide complexes as π-acceptor ligands
• Authors of publication: Reinholdt, Anders; Vibenholt, Johan E.; Morsing, Thorbjørn J.; Schau-Magnussen, Magnus; Reeler, Nini E. A.; Bendix, Jesper
• Journal of publication: Chem. Sci.
• Year of publication: 2015
• Journal volume: 6
• Journal issue: 10
• Pages of publication: 5815
• a: 13.297 ± 0.0006 Å
• b: 14.55 ± 0.0013 Å
• c: 18.906 ± 0.0017 Å
• α: 111.639 ± 0.007°
• β: 93.007 ± 0.005°
• γ: 92.517 ± 0.006°
• Cell volume: 3387.4 ± 0.5 ų
• Cell temperature: 123 ± 2 K
• Ambient diffraction temperature: 123 ± 2 K
• Number of distinct elements: 10
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.067
• Residual factor for significantly intense reflections: 0.0521
• Weighted residual factors for significantly intense reflections: 0.1405
• Weighted residual factors for all reflections included in the refinement: 0.1584
• Goodness-of-fit parameter for all reflections included in the refinement: 1.092
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No