Information card for entry 1534350

Structure parameters

• Common name: bissilyloxy aldehyde
• Chemical name: (2R,3R)-2,3-bis(tris(trimethylsilyl)siloxy)-hexanal
• Formula: C24 H64 O3 Si8
• Calculated formula: C24 H64 O3 Si8
• SMILES: [Si]([Si](C)(C)C)([Si](C)(C)C)([Si](C)(C)C)O[C@@H]([C@H](O[Si]([Si](C)(C)C)([Si](C)(C)C)[Si](C)(C)C)C=O)CCC.[Si]([Si](C)(C)C)([Si](C)(C)C)([Si](C)(C)C)O[C@H]([C@@H](O[Si]([Si](C)(C)C)([Si](C)(C)C)[Si](C)(C)C)C=O)CCC
• Title of publication: A highly diastereoselective “super silyl” governed aldol reaction: synthesis of α,β-dioxyaldehydes and 1,2,3-triols
• Authors of publication: Gati, Wafa; Yamamoto, Hisashi
• Journal of publication: Chem. Sci.
• Year of publication: 2016
• Journal volume: 7
• Journal issue: 1
• Pages of publication: 394
• a: 16.614 ± 0.019 Å
• b: 18.221 ± 0.019 Å
• c: 14.051 ± 0.016 Å
• α: 90°
• β: 105.69 ± 0.02°
• γ: 90°
• Cell volume: 4095 ± 8 ų
• Cell temperature: 173 K
• Ambient diffraction temperature: 173 K
• Number of distinct elements: 4
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for significantly intense reflections: 0.2228
• Weighted residual factors for all reflections included in the refinement: 0.531
• Goodness-of-fit parameter for all reflections included in the refinement: 1.285
• Diffraction radiation wavelength: 0.71075 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No