Information card for entry 1537146

Structure parameters

• Chemical name: K Na9 (Mn4 (H2 O)2 (As W9 O34)2) (H2 O)35
• Formula: As2 H74 K Mn4 Na9 O105 W18
• Calculated formula: As2 Mn4 Na9 O105 W18
• SMILES: O=[W]123O[W]45(=O)O[W]6(O1)(=O)O[W]178(=O)[O]9[W]%10(O6)(O[W]6%11(O2)([O]2[W]%12(O3)(O6)(=O)O[W]36(O4)([O]([W](O5)(O3)(=O)(O1)[O]1[Mn]3([O]=6)[O]4[Mn]([O]=%11)([O]=%12)([O]5[Mn]6([O]=%10)[O]=[W]%10%11%12(O[W]%13%14(O[W]%15%16(=O)O[W]%17(O%13)(=O)O[W]%13%184([O]4[W](O%17)(O[W]%17%19(O%15)([O]([W](O%16)(O%17)(=O)(O%11)=[O][Mn]1([O]=%19)([O]86)[OH2])[As]4(=O)[O]%10[W]5(O%14)(O%12)(=O)O%13)=O)(O%18)(=O)=[O]3)=O)=O)=O)[OH2])[As]92=O)=O)=O)(O7)=O.[Na+].O.O.[Na+].O.[Na+].O.O.O.O.O.O.O.O.O.O.O.O.O.O.[Na+].O.O.[Na+].O.O.[Na+].O.[Na+].O.[Na+].O.O.O.O.O.O.O.[Na+].O.O.O.O.O
• Title of publication: Rational synthesis and X-ray structure of (Mn(II)4 (H2 O)2 (As(V) W9 O34)2)(10-) from (As(III)4 W40 O140)(28-), (Mn O4)(-) and Mn(2+)
• Authors of publication: Rosu, C.; Crans, D.C.; Weakley, T.J.R.
• Journal of publication: Polyhedron
• Year of publication: 2002
• Journal volume: 21
• Pages of publication: 959 - 962
• a: 11.6368 Å
• b: 14.2113 Å
• c: 17.6343 Å
• α: 98.876°
• β: 105.682°
• γ: 113.29°
• Cell volume: 2463.89 ų
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No