Information card for entry 1543010

Structure parameters

• Formula: C14 H29 N O2 Si
• Calculated formula: C14 H29 N O2 Si
• SMILES: C(=O)(C(/C=C/C)O[Si](C(C)C)(C(C)C)C(C)C)N
• Title of publication: Spontaneous Oxygenation of Siloxy-N-silylketenimines to α-Ketoamides.
• Authors of publication: Sasaki, Michiko; Ando, Masafumi; Kawahata, Masatoshi; Yamaguchi, Kentaro; Takeda, Kei
• Journal of publication: Organic letters
• Year of publication: 2016
• Journal volume: 18
• Journal issue: 7
• Pages of publication: 1598 - 1601
• a: 7.852 ± 0.003 Å
• b: 8.477 ± 0.004 Å
• c: 14.445 ± 0.006 Å
• α: 89.89 ± 0.004°
• β: 75.96 ± 0.004°
• γ: 65.051 ± 0.004°
• Cell volume: 840.2 ± 0.6 ų
• Cell temperature: 100 K
• Ambient diffraction temperature: 100 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0357
• Residual factor for significantly intense reflections: 0.0321
• Weighted residual factors for significantly intense reflections: 0.0822
• Weighted residual factors for all reflections included in the refinement: 0.0844
• Goodness-of-fit parameter for all reflections included in the refinement: 1.076
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No