Information card for entry 1545267

Structure parameters

• Formula: C40.55 H59.95 Cl0.15 Pb Ru Si2
• Calculated formula: C40.55 H59.95 Cl0.15 Pb Ru Si2
• SMILES: [Pb]1([C]2([Ru]345678([C]=2([C]3(=[C]14[Si](C)(C)C(C)(C)C)c1ccccc1)c1ccccc1)[c]1([c]8([c]7([c]6([c]51C)C)C)C)C)[Si](C)(C(C)(C)C)C)C(C)C
• Title of publication: Synthesis and reactivity of a ruthenocene-type complex bearing an aromatic π-ligand with the heaviest group 14 element
• Authors of publication: Nakada, Marisa; Kuwabara, Takuya; Furukawa, Shunsuke; Hada, Masahiko; Minoura, Mao; Saito, Masaichi
• Journal of publication: Chem. Sci.
• Year of publication: 2017
• Journal volume: 8
• Journal issue: 4
• Pages of publication: 3092
• a: 16.7796 ± 0.0015 Å
• b: 11.2019 ± 0.0011 Å
• c: 21.597 ± 0.002 Å
• α: 90°
• β: 98.91 ± 0.001°
• γ: 90°
• Cell volume: 4010.5 ± 0.6 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0289
• Residual factor for significantly intense reflections: 0.023
• Weighted residual factors for significantly intense reflections: 0.0499
• Weighted residual factors for all reflections included in the refinement: 0.0518
• Goodness-of-fit parameter for all reflections included in the refinement: 1.025
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No