Information card for entry 1545774

Structure parameters

• Formula: C30 H37 Au F6 O P Sb
• Calculated formula: C30 H37 Au F6 O P Sb
• SMILES: [Au]12([P](c3c4c1cccc4ccc3)(C(C)C)C(C)C)[c]1(ccc(cc1)OC)[C@H]1[C@@H]2[C@@H]2CC[C@H]1C2.[Sb](F)(F)(F)(F)([F-])F.[Au]12([P](c3c4c1cccc4ccc3)(C(C)C)C(C)C)[c]1(ccc(cc1)OC)[C@@H]1[C@H]2[C@H]2CC[C@@H]1C2.[Sb](F)(F)(F)(F)([F-])F
• Title of publication: Gold(III)-arene complexes by insertion of olefins into gold-aryl bonds
• Authors of publication: Rekhroukh, Feriel; Blons, Charlie; Estevez, Laura; Ladeira, Sonia; Miqueu, Karinne; Amgoune, Abderrahmane; Bourissou, Didier
• Journal of publication: Chem. Sci.
• Year of publication: 2017
• a: 12.9887 ± 0.0007 Å
• b: 15.9169 ± 0.0009 Å
• c: 15.3964 ± 0.0007 Å
• α: 90°
• β: 106.699 ± 0.0018°
• γ: 90°
• Cell volume: 3048.8 ± 0.3 ų
• Cell temperature: 193 ± 2 K
• Ambient diffraction temperature: 193 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.022
• Residual factor for significantly intense reflections: 0.0191
• Weighted residual factors for significantly intense reflections: 0.045
• Weighted residual factors for all reflections included in the refinement: 0.0463
• Goodness-of-fit parameter for all reflections included in the refinement: 1.026
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No