Information card for entry 1548531

Structure parameters

• Formula: C19 H46 Cl4 Eu N8 O Zn
• Calculated formula: C19 H46 Cl4 Eu N8 O Zn
• SMILES: [Eu]1234567[N]89CC[NH]1CC[NH]4CC[N]7(CC[NH]5CC[NH]2CC8)CC[NH]6CC[NH]3CC9.[Zn](Cl)(Cl)([Cl-])[Cl-].OC
• Title of publication: First use of a divalent lanthanide for visible-light-promoted photoredox catalysis.
• Authors of publication: Jenks, Tyler C.; Bailey, Matthew D.; Hovey, Jessica L.; Fernando, Shanilke; Basnayake, Gihan; Cross, Michael E.; Li, Wen; Allen, Matthew J.
• Journal of publication: Chemical science
• Year of publication: 2018
• Journal volume: 9
• Journal issue: 5
• Pages of publication: 1273 - 1278
• a: 16.9858 ± 0.001 Å
• b: 18.4496 ± 0.001 Å
• c: 18.8816 ± 0.0011 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 5917.1 ± 0.6 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100.1 K
• Number of distinct elements: 7
• Space group number: 61
• Hermann-Mauguin space group symbol: P b c a
• Hall space group symbol: -P 2ac 2ab
• Residual factor for all reflections: 0.0646
• Residual factor for significantly intense reflections: 0.0289
• Weighted residual factors for significantly intense reflections: 0.0526
• Weighted residual factors for all reflections included in the refinement: 0.0625
• Goodness-of-fit parameter for all reflections included in the refinement: 1.047
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No