Information card for entry 1548587

Structure parameters

• Formula: C25 H17 Au Cl F4 N2 O P
• Calculated formula: C25 H17 Au Cl F4 N2 O P
• SMILES: [Au](Cl)[P](c1ccccc1)(c1ccccc1)c1ccc(c(c1F)/N=N\c1c(cc(cc1F)OC)F)F
• Title of publication: Bimetallic gold(i) complexes of photoswitchable phosphines: synthesis and uses in cooperative catalysis
• Authors of publication: Arif, T.; Cazorla, C.; Bogliotti, N.; Saleh, N.; Blanchard, F.; Gandon, V.; Métivier, R.; Xie, J.; Voituriez, A.; Marinetti, A.
• Journal of publication: Catalysis Science & Technology
• Year of publication: 2018
• Journal volume: 8
• Journal issue: 3
• Pages of publication: 710
• a: 16.0034 ± 0.0005 Å
• b: 8.3754 ± 0.0002 Å
• c: 19.2521 ± 0.0005 Å
• α: 90°
• β: 111.188 ± 0.003°
• γ: 90°
• Cell volume: 2406.01 ± 0.12 ų
• Cell temperature: 200 K
• Ambient diffraction temperature: 200 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0389
• Residual factor for significantly intense reflections: 0.0258
• Weighted residual factors for significantly intense reflections: 0.0566
• Weighted residual factors for all reflections included in the refinement: 0.0598
• Goodness-of-fit parameter for all reflections included in the refinement: 1.058
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No