Information card for entry 1549134

Structure parameters

• Formula: C24 H22 Au Cl4 N
• Calculated formula: C24 H22 Au Cl4 N
• SMILES: [Au]1(c2cccc3ccc4ccc[n]1c4c23)(Cl)CCCCc1ccccc1.ClC(Cl)Cl
• Title of publication: Cyclometalated gold(iii) complexes: noticeable differences between (N,C) and (P,C) ligands in migratory insertion.
• Authors of publication: Serra, Jordi; Font, Pau; Sosa Carrizo, E. Daiann; Mallet-Ladeira, Sonia; Massou, Stéphane; Parella, Teodor; Miqueu, Karinne; Amgoune, Abderrahmane; Ribas, Xavi; Bourissou, Didier
• Journal of publication: Chemical science
• Year of publication: 2018
• Journal volume: 9
• Journal issue: 16
• Pages of publication: 3932 - 3940
• a: 7.4651 ± 0.0004 Å
• b: 9.8244 ± 0.0005 Å
• c: 16.963 ± 0.0009 Å
• α: 98.935 ± 0.002°
• β: 91.454 ± 0.002°
• γ: 106.868 ± 0.002°
• Cell volume: 1172.83 ± 0.11 ų
• Cell temperature: 193 ± 2 K
• Ambient diffraction temperature: 193 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0299
• Residual factor for significantly intense reflections: 0.0247
• Weighted residual factors for significantly intense reflections: 0.0561
• Weighted residual factors for all reflections included in the refinement: 0.0583
• Goodness-of-fit parameter for all reflections included in the refinement: 1.093
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No