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Information card for entry 1549758
Preview
Coordinates | 1549758.cif |
---|---|
Original paper (by DOI) | HTML |
Formula | C50 H58 Ag Al2 Br2 Cl4 F55 O6 Si2 |
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Calculated formula | C50 H58 Ag Al2 Br2 Cl4 F55 O6 Si2 |
SMILES | O(C(C(F)(F)F)(C(F)(F)F)C(F)(F)F)[Al](OC(C(F)(F)F)(C(F)(F)F)C(F)(F)F)(OC(C(F)(F)F)(C(F)(F)F)C(F)(F)F)[F][Al](OC(C(F)(F)F)(C(F)(F)F)C(F)(F)F)(OC(C(F)(F)F)(C(F)(F)F)C(F)(F)F)OC(C(F)(F)F)(C(F)(F)F)C(F)(F)F.[Ag]([Cl]CCl)([Cl]CCl)([Br][Si](C(C)(C)C)(C(C)(C)C)C(C)(C)C)[Br][Si](C(C)(C)C)(C(C)(C)C)C(C)(C)C |
Title of publication | Facile and systematic access to the least-coordinating WCA [(R<sup>F</sup>O)<sub>3</sub>Al-F-Al(OR<sup>F</sup>)<sub>3</sub>]<sup>-</sup> and its more Lewis-basic brother [F-Al(OR<sup>F</sup>)<sub>3</sub>]<sup>-</sup> (R<sup>F</sup> = C(CF<sub>3</sub>)<sub>3</sub>). |
Authors of publication | Martens, Arthur; Weis, Philippe; Krummer, Michael Christian; Kreuzer, Marvin; Meierhöfer, Andreas; Meier, Stefan C.; Bohnenberger, Jan; Scherer, Harald; Riddlestone, Ian; Krossing, Ingo |
Journal of publication | Chemical science |
Year of publication | 2018 |
Journal volume | 9 |
Journal issue | 35 |
Pages of publication | 7058 - 7068 |
a | 15.476 ± 0.0018 Å |
b | 16.615 ± 0.002 Å |
c | 18.2967 ± 0.0019 Å |
α | 89.488 ± 0.004° |
β | 67.742 ± 0.004° |
γ | 70.537 ± 0.004° |
Cell volume | 4068.1 ± 0.8 Å3 |
Cell temperature | 100 ± 2 K |
Ambient diffraction temperature | 100 ± 2 K |
Number of distinct elements | 9 |
Space group number | 2 |
Hermann-Mauguin space group symbol | P -1 |
Hall space group symbol | -P 1 |
Residual factor for all reflections | 0.0327 |
Residual factor for significantly intense reflections | 0.0272 |
Weighted residual factors for significantly intense reflections | 0.0665 |
Weighted residual factors for all reflections included in the refinement | 0.0693 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.029 |
Diffraction radiation wavelength | 0.71073 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
For the version history of this entry, please navigate to main COD server.
The link is: https://www.crystallography.net/1549758.html
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