Information card for entry 1550310

Structure parameters

• Chemical name: [(H)2Rh(PNMeP)2]
• Formula: C23 H56 F3 N2 O3 P4 Rh S
• Calculated formula: C23 H56 F3 N2 O3 P4 Rh S
• Title of publication: Evaluating the impacts of amino acids in the second and outer coordination spheres of Rh-bis(diphosphine) complexes for CO₂ hydrogenation.
• Authors of publication: Walsh, Aaron P.; Laureanti, Joseph A.; Katipamula, Sriram; Chambers, Geoffrey M.; Priyadarshani, Nilusha; Lense, Sheri; Bays, J. Timothy; Linehan, John C.; Shaw, Wendy J.
• Journal of publication: Faraday discussions
• Year of publication: 2019
• Journal volume: 215
• Journal issue: 0
• Pages of publication: 123 - 140
• a: 10.1497 ± 0.0004 Å
• b: 11.3546 ± 0.0004 Å
• c: 29.0077 ± 0.0011 Å
• α: 90°
• β: 95.69 ± 0.002°
• γ: 90°
• Cell volume: 3326.5 ± 0.2 ų
• Cell temperature: 140 ± 2 K
• Ambient diffraction temperature: 140 ± 2 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0434
• Residual factor for significantly intense reflections: 0.0299
• Weighted residual factors for significantly intense reflections: 0.065
• Weighted residual factors for all reflections included in the refinement: 0.0705
• Goodness-of-fit parameter for all reflections included in the refinement: 1.026
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No