Information card for entry 1551018

Structure parameters

• Chemical name: μ-Carbonyl-2:3κ^2^<i>C</i>:<i>C</i>-octacarbonyl-1κ^3^<i>C</i>, 2κ<i>C</i>,3κ<i>C</i>,4κ^3^<i>C</i>-bis[1:2μ-(η^6^:η^5^);3:4μ-(η^5^:η^6^)-2-methylindenyl]-1,4-dichromium(0)-2,3-dirhodium(III)}(<i>Rh</i>—<i>Rh</i>)
• Formula: C29 H18 Cr2 O9 Rh2
• Calculated formula: C29 H18 Cr2 O9 Rh2
• SMILES: [c]1234[cH]5[cH]6[cH]7[cH]8[c]91([cH]1[c]%10([cH]2[Rh]2491%10(C#[O])C(=O)[Rh]149%102([c]2%11%12[cH]%13[cH]%14[cH]%15[cH]%16[c]12([cH]4[c]9([cH]%10%11)C)[Cr]%12%13%14%15%16(C#[O])(C#[O])C#[O])C#[O])C)[Cr]35678(C#[O])(C#[O])C#[O]
• Title of publication: μ-Carbonyl-bis(carbonyl{η^5^-[tricarbonyl(η^6^-2-methylindenyl)chromium(0)]rhodium(III)})(<i>Rh</i>—<i>Rh</i>)
• Authors of publication: Werlé, Christophe; Bailly, Corinne; Karmazin, Lydia; Djukic, Jean-Pierre
• Journal of publication: IUCrData
• Year of publication: 2019
• Journal volume: 4
• Journal issue: 5
• Pages of publication: x190573
• a: 11.3335 ± 0.0002 Å
• b: 32.6839 ± 0.0009 Å
• c: 15.9743 ± 0.0004 Å
• α: 90°
• β: 105.876 ± 0.001°
• γ: 90°
• Cell volume: 5691.5 ± 0.2 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.1077
• Residual factor for significantly intense reflections: 0.0565
• Weighted residual factors for significantly intense reflections: 0.0967
• Weighted residual factors for all reflections included in the refinement: 0.1124
• Goodness-of-fit parameter for all reflections included in the refinement: 1.034
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: Yes