Information card for entry 1552520

Structure parameters

• Formula: C23 H55 Mn N2 P4 Si
• Calculated formula: C23 H55 Mn N2 P4 Si
• SMILES: [MnH]12([P](C)(C)CC[P]1(C)C)([P](C)(C)CC[P]2(C)C)[SiH](=C1N(C(=C(N1C)C)C)C)CCCC
• Title of publication: Interconversion and reactivity of manganese silyl, silylene, and silene complexes
• Authors of publication: Price, Jeffrey S.; Emslie, David J. H.
• Journal of publication: Chemical Science
• Year of publication: 2019
• a: 16.4955 ± 0.0004 Å
• b: 9.9175 ± 0.0002 Å
• c: 20.3912 ± 0.0005 Å
• α: 90°
• β: 111.915 ± 0.001°
• γ: 90°
• Cell volume: 3094.82 ± 0.13 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0415
• Residual factor for significantly intense reflections: 0.0322
• Weighted residual factors for significantly intense reflections: 0.0795
• Weighted residual factors for all reflections included in the refinement: 0.0855
• Goodness-of-fit parameter for all reflections included in the refinement: 1.06
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No