Information card for entry 1554819

Structure parameters

• Formula: C24 H31 Ag F6 N2 P2
• Calculated formula: C24 H31 Ag F6 N2 P2
• Title of publication: [Ag(bpy)(PPhtBu2)(OCF3)]: a stable nucleophilic reagent for chemoselective and stereospecific trifluoromethoxylation of secondary alkyl nosylates
• Authors of publication: Chen, Daoqian; Lu, Long; Shen, Qilong
• Journal of publication: Organic Chemistry Frontiers
• Year of publication: 2019
• Journal volume: 6
• Journal issue: 11
• Pages of publication: 1801
• a: 15.277 ± 0.0004 Å
• b: 8.0788 ± 0.0002 Å
• c: 21.7171 ± 0.0005 Å
• α: 90°
• β: 98.481 ± 0.001°
• γ: 90°
• Cell volume: 2651.01 ± 0.11 ų
• Cell temperature: 170 ± 2 K
• Ambient diffraction temperature: 169.96 K
• Number of distinct elements: 6
• Space group number: 7
• Hermann-Mauguin space group symbol: P 1 c 1
• Hall space group symbol: P -2yc
• Residual factor for all reflections: 0.0435
• Residual factor for significantly intense reflections: 0.0405
• Weighted residual factors for significantly intense reflections: 0.0968
• Weighted residual factors for all reflections included in the refinement: 0.0997
• Goodness-of-fit parameter for all reflections included in the refinement: 1.036
• Diffraction radiation wavelength: 1.34139 Å
• Diffraction radiation type: GaKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No