Information card for entry 1556335

Structure parameters

• Formula: C44 H72 Cl2 P4 Rh2
• Calculated formula: C44 H72 Cl2 P4 Rh2
• SMILES: [Rh]12([Cl][Rh]3([Cl]1)[P]1(c4c([P]53[C@@H](CC[C@H]5CC)CC)cccc4)[C@@H](CC[C@H]1CC)CC)[P]1(c3c([P]42[C@@H](CC[C@H]4CC)CC)cccc3)[C@@H](CC[C@H]1CC)CC
• Title of publication: Halide bridged trinuclear rhodium complexes and their inhibiting influence on catalysis
• Authors of publication: Preetz, Angelika; Kohrt, Christina; Meißner, Antje; Wei, Siping; Drexler, Hans-Joachim; Buschmann, Helmut; Heller, Detlef
• Journal of publication: Catal. Sci. Technol.
• Year of publication: 2013
• Journal volume: 3
• Journal issue: 2
• Pages of publication: 462
• a: 14.1975 ± 0.0005 Å
• b: 16.3823 ± 0.0004 Å
• c: 20.5561 ± 0.0005 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 4781.1 ± 0.2 ų
• Cell temperature: 200 ± 2 K
• Ambient diffraction temperature: 200 ± 2 K
• Number of distinct elements: 5
• Space group number: 19
• Hermann-Mauguin space group symbol: P 21 21 21
• Hall space group symbol: P 2ac 2ab
• Residual factor for all reflections: 0.0213
• Residual factor for significantly intense reflections: 0.0184
• Weighted residual factors for significantly intense reflections: 0.0377
• Weighted residual factors for all reflections included in the refinement: 0.0381
• Goodness-of-fit parameter for all reflections included in the refinement: 0.908
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No