Information card for entry 1556340

Structure parameters

• Formula: C37 H86 B Cl4 F4 P6 Rh3
• Calculated formula: C37 H86 B Cl4 F4 P6 Rh3
• SMILES: [B](F)(F)(F)[F-].C1C[P@@](C)(C(C)(C)C)[Rh]2([P@]1(C)C(C)(C)C)[Cl]1[Rh]3([Cl]2[Rh]21[P@@](C(C)(C)C)(C)CC[P@]2(C(C)(C)C)C)[P@@](C(C)(C)C)(C)CC[P@]3(C(C)(C)C)C.C(Cl)Cl
• Title of publication: Halide bridged trinuclear rhodium complexes and their inhibiting influence on catalysis
• Authors of publication: Preetz, Angelika; Kohrt, Christina; Meißner, Antje; Wei, Siping; Drexler, Hans-Joachim; Buschmann, Helmut; Heller, Detlef
• Journal of publication: Catal. Sci. Technol.
• Year of publication: 2013
• Journal volume: 3
• Journal issue: 2
• Pages of publication: 462
• a: 9.6676 ± 0.0019 Å
• b: 12.005 ± 0.002 Å
• c: 12.658 ± 0.003 Å
• α: 109.83 ± 0.03°
• β: 94.19 ± 0.03°
• γ: 90.56 ± 0.03°
• Cell volume: 1377.3 ± 0.6 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 7
• Space group number: 1
• Hermann-Mauguin space group symbol: P 1
• Hall space group symbol: P 1
• Residual factor for all reflections: 0.0274
• Residual factor for significantly intense reflections: 0.0236
• Weighted residual factors for significantly intense reflections: 0.0486
• Weighted residual factors for all reflections included in the refinement: 0.049
• Goodness-of-fit parameter for all reflections included in the refinement: 0.991
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No