Information card for entry 1556497

Structure parameters

• Formula: C134 H144 Mg2 N4 P4
• Calculated formula: C110 H120 Mg2 N4 P4
• SMILES: C12=P(c3ccccc3)(c3ccccc3)N(c3c(cccc3C(C)C)C(C)C)[Mg]2[N](=P(C2=P(c3ccccc3)(c3ccccc3)N(c3c(cccc3C(C)C)C(C)C)[Mg]2[N](=P1(c1ccccc1)c1ccccc1)c1c(cccc1C(C)C)C(C)C)(c1ccccc1)c1ccccc1)c1c(cccc1C(C)C)C(C)C.c1ccccc1.c1ccccc1
• Title of publication: Methanediide Formation via Hydrogen Elimination in Magnesium versus Aluminium Hydride Complexes of a Sterically Demanding Bis(iminophosphoranyl)methanediide
• Authors of publication: Sindlinger, C.P.; Lawrence, S.R.; Cordes, D.B.; Slawin, A.M.Z.; Stasch, A.
• Journal of publication: Inorganics
• Year of publication: 2017
• Journal volume: 5
• Pages of publication: 29
• a: 19.08 ± 0.004 Å
• b: 34.382 ± 0.007 Å
• c: 16.79 ± 0.003 Å
• α: 90°
• β: 90.56 ± 0.03°
• γ: 90°
• Cell volume: 11014 ± 4 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 5
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0495
• Residual factor for significantly intense reflections: 0.0445
• Weighted residual factors for significantly intense reflections: 0.1141
• Weighted residual factors for all reflections included in the refinement: 0.1184
• Goodness-of-fit parameter for all reflections included in the refinement: 1.051
• Diffraction radiation wavelength: 0.7108 Å
• Diffraction radiation type: synchrotron
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No