Information card for entry 1557326

Structure parameters

• Common name: A-cisbeta-[Co(acac)(ch-PNNP)](C1O4)2
• Formula: C39 H47 Cl2 Co N2 O10 P2
• Calculated formula: C39 Cl2 Co N2 O10 P2
• SMILES: [Co]1234([P](CC[NH]3[C@H]3[C@H]([NH]4CC[P]1(c1ccccc1)c1ccccc1)CCCC3)(c1ccccc1)c1ccccc1)OC(=CC(=[O]2)C)C.Cl(=O)(=O)(=O)[O-].Cl(=O)(=O)(=O)[O-]
• Title of publication: Synthesis and Stereochemistry of Cobalt(III) Complexes with the New Optically Active Phosphine Ligand, N,N'-Bis[2-(diphenylphosphanyl)ethyl]-(1R,2R)-cyclohexane-1,2-diamine (ch-PNNP). Crystal Structure of Lambda-Cisbeta-[Co(acac)(ch-PNNP)](ClO4)2
• Authors of publication: Atoh, Masamichi; Sorensen, Henning Osholm; Andersen, Peter
• Journal of publication: Acta Chemica Scandinavica
• Year of publication: 1997
• Journal volume: 51
• Pages of publication: 1169 - 1177
• a: 12.721 ± 0.004 Å
• b: 17.073 ± 0.003 Å
• c: 18.26 ± 0.03 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 3966 ± 7 ų
• Ambient diffraction temperature: 122 K
• Number of distinct elements: 7
• Space group number: 19
• Hermann-Mauguin space group symbol: P 21 21 21
• Hall space group symbol: P 2ac 2ab
• Residual factor for significantly intense reflections: 0.0612
• Weighted residual factors for significantly intense reflections: 0.1349
• Goodness-of-fit parameter for all reflections included in the refinement: 1.441
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No